Post-breakup basaltic magmatism along the East Greenland Tertiary rifted margin

Mafic and ultramafic intrusions in East Greenland adjacent to the offshore Greenland–Iceland ridge were emplaced 5–9 My after continental breakup at 55 Ma [1]. Rare earth element (REE) concentrations determined by secondary ion mass spectrometry are reported for cumulus clinopyroxene from these intrusions, and the data are used to estimate REE abundance in equilibrium melts using available partitioning data. Estimated equilibrium melts from intrusions have strongly fractionated REE patterns with Nd/Dy(N) in the range 2 to 5.6 and Yb/Dy(N) 0.55 to 0.92, similar to values for coeval basalts. These melts have markedly higher Nd/Dy(N) than earlier breakup related flood basalts. The moderately low Yb/Dy(N) for the post-breakup volcanism is indicative of residual garnet in the source, while their high Nd/Dy(N) ratios can best be explained by aggregating low degree melts from a light-REE-enriched garnet- and spinel-bearing mantle source. We also report He, Sr, and Nd isotopic data for the intrusions. The highest ³He/⁴He ratios (>10 R/R_a) are found in the samples whose REE data reflect the largest proportion of melts from a garnet-bearing source, and having Sr and Nd isotopic compositions identical with the radiogenic Sr and unradiogenic Nd isotope end of the Iceland compositional field. There is no indication of a MORB-type mantle in the source of the intrusions. We postulate that post-breakup volcanism along the East Greenland coastline reflects the increasing proximity of the mantle plume to the East Greenland continental margin. The low degree of melting at high mean pressure inferred for the parental melts for the intrusions may reflect re-thickening of the lithosphere, which in turn was caused by the vigorous volcanism during breakup, with accompanying depletion of upper mantle and underplating of the crust at the continental margin.     

Potassium isotopic composition of Australasian tektites

Abstract— We have analyzed the potassium isotopic composition of four tektites from the Australasian strewn field, spanning a wide diversity of thermal histories, inferred from textures and volatile element contents. Our results indicate no isotopic differences between tektites and terrestrial crustal rocks, placing stringent limits of ≤2% loss of potassium during the brief duration of high temperature heating experienced by these samples. This confirms that the chemical composition of tektites is entirely a reflection of source rock composition and has not been modified by the tektiteforming process for elements less volatile than potassium. Losses of more volatile components, e.g., the halogens and water, are not precluded by the present data. Coupling a radiative cooling temperature‐time path with potassium vapor pressure data indicates that tektite melt drops are not likely to develop bulk elemental fractionation during the brief heating episodes of tektites for peak temperatures <2273 K. The extent of K isotopic fractionation is independent of droplet size but dependent on peak heating temperature. The exact peak temperature depends on the choice of vapor pressure data used for K, which need to be better constrained.     

The Cuban Tektite Revisited

Abstract— A tektite, probably found in Cuba, was previously classified as belonging to the North American tektite strewn field on the basis of chemistry, age, isotopic, and petrographic characteristics. New major element analyses and trace element analyses show that the sample falls within the range of other North American tektites, and is close to the bediasite compositions. There are, however, some differences to normal georgiaites and bediasites. In a Na₂O/K₂O diagram the sample plots between the two distinct fields formed by georgiaites and bediasites. The rare earth elements and some lithophile trace elements are slightly enriched compared to bediasites, and much higher than in georgiaites. The discovery of tektite fragments from locations at Barbados and a DSDP site off the coast of New Jersey makes it likely that the North American strewn field is larger than previously thought, in agreement with microtektite distributions. Thus it is possible that the “Cuban” tektite really originated from Cuba.     

Flow nets from finite element data

Finite element solutions for steady-state flow of fluids through porous media do not include an explicit develpoment of the flow net, and many engineers find this lack frustrating. To solve for the stream function, the analyst can use essentially the same finite element routines as he used for the potential, but the matrix corresponding to the hydraulic conductivity is not the inverse of the conductivity. Contouring the potential and the stream function is done element by element; certain anomalous situations are described in an appendix.     

Uncertainty and learning: implications for the trade-off between short-lived and long-lived greenhouse gases

The economic benefits of a multi-gas approach to climate change mitigation are clear. However, there is still a debate on how to make the trade-off between different greenhouse gases (GHGs). The trade-off debate has mainly centered on the use of Global Warming Potentials (GWPs), governing the trade-off under the Kyoto Protocol, with results showing that the cost-effective valuation of short-lived GHGs, like methane (CH₄), should be lower than its current GWP value if the ultimate aim is to stabilize the anthropogenic temperature change. However, contrary to this, there have also been proposals that early mitigation mainly should be targeted on short-lived GHGs. In this paper we analyze the cost-effective trade-off between a short-lived GHG, CH₄, and a long-lived GHG, carbon dioxide (CO₂), when a temperature target is to be met, taking into consideration the current uncertainty of the climate sensitivity as well as the likelihood that this will be reduced in the future. The analysis is carried out using an integrated climate and economic model (MiMiC) and the results from this model are explored and explained using a simplified analytical economic model. The main finding is that the introduction of uncertainty and learning about the climate sensitivity increases the near-term cost-effective valuation of CH₄ relative to CO₂. The larger the uncertainty span, the higher the valuation of the short-lived gas. For an uncertainty span of ±1°C around an expected climate sensitivity of 3°C, CH₄ is cost-effectively valued 6.8 times as high as CO₂ in year 2005. This is almost twice as high as the valuation in a deterministic case, but still significantly lower than its GWP₁₀₀ value.