High-P granulites of the Songshugou area (Qinling Orogen,east-central China): Petrography,phase relations,and U/Pb zircon geochronology

High-pressure (HP) granulites provide telling records of mineral reactions at upper mantle to lower crustal levels and key information on the fate of material in subduction systems. The latter especially applies when they abut eclogite and mantle dunite because such rock associations are crucial for understanding the incompletely known processes at the interface of converging plates. A continental arc, active c. 520–395 Ma ago, formed an enigmatic example of such a rock association in the Songshugou area, Qinling Orogen. To unravel the juxtaposition of the distinct rocks, this study combines petrography, phase equilibria modelling, conventional thermobarometry, and zircon U–Th–Pb–Ti–REE analysis. Two mafic HP granulites, which contain the mineral assemblages garnet–clinopyroxene–plagioclase–rutile–mesoperthite–quartz and garnet–clinopyroxene–plagioclase–rutile, experienced peak metamorphic conditions of ≤1.4 GPa, 860°C and ~1.3 GPa, ≥910°C, respectively. During decompression and cooling, at 489 ± 4 Ma, amphibole lamellae unmixed from a clinopyroxene solid solution and orthopyroxene in part replaced garnet. A felsic HP granulite shows equilibration of garnet, perthite, antiperthite, kyanite, quartz, and rutile at 810–860°C, ~1.2 GPa, sillimanite growth during decompression, and upper amphibolite facies cooling at 510 ± 4 Ma. Though the thermobarometric data are just within the methodological errors, the U/Pb zircon ages imply the HP granulites did not evolve coherently. The HP granulites either represent foundered lower arc crust or originated from subduction erosion because their geochemistry is indistinguishable from that of the hanging-wall plate. Published and new pressure–temperature–time–deformation paths converge at ~710°C, ~0.9 GPa, and ≲470 Ma, implying exhumation tectonics juxtaposed the HP granulites with a mélange of eclogite and mantle dunite at lower crustal levels. This study highlights that lower arc crust can comprise material of diverse evolution.     

The ichnology of carbonate drifts

Carbonate drifts have so far not been as intensely investigated as their siliciclastic equivalents, especially from an ichnological perspective. The aim of this work is therefore to provide an overview of the different bioturbation styles in carbonate drifts for ichnologists and sedimentologists working in such deposits. Different types of carbonate drifts from the Maldives were studied to address this objective. The cores recovered during International Ocean Discovery Program Expedition 359 were examined to provide the sedimentological and ichnological data for a detailed analysis of the ichnology of carbonate drifts. The ichnological characteristics of the Maldives drifts are compared to other carbonate drifts in order to discuss similarities and differences, and thus provide an overview of the general characteristics of carbonate drift ichnology. These drifts are located in the Santaren Channel which lines Great Bahama Bank, along the Marion Plateau in Australia, in the Limassol and Larnaca basins in Cyprus and in the Danish Basin in Denmark. The common characteristics of bioturbation in carbonate drifts are: (i) the complete bioturbation of the sediment with bioturbation indexes between four and six; (ii) the occurrence of distinctive trace fossils limited to facies contacts or condensed intervals; (iii) a typical ichnoassemblage consisting of Thalassinoides, Scolicia, Planolites, Zoophycos, Chondrites, Phycosiphon and Palaeophycus; (iv) the contiguous occurrence of ichnogenera from different tiers, with only Zoophycos and Chondrites as deep tiers; and (v) distinct infills of the traces including particulate organic matter, pyrite, silica and celestine. In addition, the main ichnofacies of carbonate drifts is the Zoophycos ichnofacies. Ichnofabrics grade from coarse‐grained and completely bioturbated to ichnofabrics with present to rare trace fossils and preserved sedimentary structures. The type and intensity of the bioturbation is controlled by the amount of organic matter and the oxygenation at the sea floor that is determined by the action of bottom currents and the sea‐level fluctuations affecting the carbonate factory in carbonate platforms bordering the basins where the carbonate drifts form. The study of the bioturbation in core and outcrop provides palaeoenvironmental information about carbonate‐drift deposits that complement the classical sedimentological data.     

History of scoria-cone eruptions on the eastern shoulder of the Kenya–Tanzania Rift revealed in the 250-ka sediment record of Lake Chala near Mount Kilimanjaro

Reconstructions of the timing and frequency of past eruptions are important to assess the propensity for future volcanic activity, yet in volcanic areas such as the East African Rift only piecemeal eruption histories exist. Understanding the volcanic history of scoria-cone fields, where eruptions are often infrequent and deposits strongly weathered, is particularly challenging. Here we reconstruct a history of volcanism from scoria cones situated along the eastern shoulders of the Kenya–Tanzania Rift, using a sequence of tephra (volcanic ash) layers preserved in the ~250-ka sediment record of Lake Chala near Mount Kilimanjaro. Seven visible and two non-visible (crypto-) tephra layers in the Lake Chala sequence are attributed to activity from the Mt Kilimanjaro (northern Tanzania) and the Chyulu Hills (southern Kenya) volcanic fields, on the basis of their glass chemistry, textural characteristics and known eruption chronology. The Lake Chala record of eruptions from scoria cones in the Chyulu Hills volcanic field confirms geological and historical evidence of its recent activity, and provides first-order age estimates for seven previously unknown eruptions. Long and well-resolved sedimentary records such as that of Lake Chala have significant potential for resolving regional eruption chronologies spanning hundreds of thousands of years.     

Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

Sulfide and platinum mineralization in the Merensky Reef: evidence from hydrous silicates and fluid inclusions

The base metal sulfides of the Merensky Reef are associated with hydrous silicates and intense deuteric hydrous alteration of cumulus and postcumulus silicates. Biotite and phlogopite crystallized in the vicinity of sulfides from a volatile-enriched highly fractionated intercumulus melt. Amphibole, chlorite, and talc are later alteration phases of cumulus pyroxene and intercumulus plagioclase. Biotite is often accompanied by zircon, rutile, and quartz. Accessory quartz hosts a complex suite of H₂O-NaCl-(CaCl₂)-CO₂-CH₄ fluid inclusions which have thus far not been described from the Merensky Reef. The earliest fluid inclusion compositions are NaCl-(H₂O) with less than 10 vol.% water; CO₂ coexisting with a halite daughter crystal and brine; and polyphase inclusions with up to six daughter and accidental phases and high contents of divalent cations. The maximum trapping temperature is around 730° C at 4 to 5 kb pressure. Later inclusion generations are H₂O-NaCl, CO₂-H₂O, and pure CO₂ and CH₄. The presence of Cl-rich fluids during the intercumulus stage of the crystallizing Merensky Reef is directly related to the mode of sulfide precipitation. Prior to sulfide unmixing in a hydrous magma sulfur is likely to be present as H₂S. Sulfur saturation causes reaction of H₂S with oxides of the silicate melt to form a sulfide melt plus water. During reaction the magma is enriched in water until a separate fluid unmixes. It carries all compounds with high fluid/melt partition coefficients, as well as metals capable of forming OH- and Cl-complexes. Precious metals are assumed to have fractionated into the Cl-rich fluid as Cl-complexes rather than being dissolved in the sulfide melt. During the cooling evolution of the fluid the precious elements precipitate around the periphery of sulfide melt droplets. The model proposed explains the distribution pattern of platinum-group minerals in the Merensky Reef better than any orthomagmatic mineralization concept offered so far.     

Geochemistry and shock petrography of the Crow Creek Member,South Dakota,USA: Ejecta from the 74‐Ma Manson impact structure

Abstract— The Crow Creek Member is one of several marl units recognized within the Upper Cretaceous Pierre Shale Formation of eastern South Dakota and northeastern Nebraska, but it is the only unit that contains shock‐metamorphosed minerals. The shocked minerals represent impact ejecta from the 74‐Ma Manson impact structure (MIS). This study was aimed at determining the bulk chemical compositions and analysis of planar deformation features (PDFs) of shocked quartz; for the basal and marly units of the Crow Creek Member. We studied samples from the Gregory 84‐21 core, Iroquois core and Wakonda lime quarry. Contents of siderophile elements are generally high, but due to uncertainties in the determination of Ir and uncertainties in compositional sources for Cr, Co, and Ni, we could not confirm an extraterrestrial component in the Crow Creek Member. We recovered several shocked quartz grains from basal‐unit samples, mainly from the Gregory 84‐21 core, and results of PDF measurements indicate shock pressures of at least 15 GPa. All the samples are composed chiefly of SiO₂ (29–58 wt%), Al₂O₃ (6–14 wt%), and CaO (7–30 wt%). When compared to the composition of North American Shale Composite, the samples are significantly enriched in CaO, P₂O₅, Mn, Sr, Y, U, Cr, and Ni. The contents of rare earth elements (REE), high field strength elements (HFSE), Cr, Co, Sc, and their ratios and chemical weathering trends, reflect both felsic and basic sources for the Crow Creek Member, an inference, which is consistent with the lithological compositions in the environs of the MIS. The high chemical indices of alteration and weathering (CIA' and CIW': 75–99), coupled with the Al₂O₃‐(CaO*+Na₂O)‐K₂O (A‐CN'‐K) ratios, indicate that the Crow Creek Member and source rocks had undergone high degrees of chemical weathering. The expected ejecta thicknesses at the sampled locations (409 to 219 km from Manson) were calculated to range from about 1.9 to 12.2 cm (for the present‐day crater radius of Manson), or 0.4 to 2.4 cm (for the estimated transient cavity radius). The trend agrees with the observed thicknesses of the basal unit of the Crow Creek Member, but the actually observed thicknesses are larger than the calculated ones, indicating that not all of the basal unit comprises impact ejecta.     

Valuing the non-CO2 climate impacts of aviation

The non-CO₂ climate impact of aviation (NO_x and contrails) is assessed and emissions weighting factors (EWFs) i.e., the factor by which aviation CO₂ emissions should be multiplied to get the CO₂-equivalent emissions for annual fleet average conditions are estimated. The EWFs are estimated using two economic metrics. One is based on the relative damage cost between non-CO₂ forcers and CO₂. The other is based on the cost-effective valuation between the non-CO₂ forcers and CO₂ given an upper ceiling on the global annual average surface temperature (set at 2?K above pre-industrial levels). We also estimate EWFs using three physical metrics, Global Warming Potential (GWP), Global Temperature change Potential (GTP) and Sustained GTP (SGTP) and compare our results with the economics based metrics. Given best estimates on the forcing contributions from CO₂, contrails and NO_x from aviation and by using a discount rate of 3%/year, the RDC based metric gives an EWF equal to 1.4 (slightly higher than EWFs based on GWP and SGTP using a 100?year time horizon). EWF using the cost-effective approach depends on the time that remains before stabilization occurs. It is roughly equal to unity until a few years before the temperature reaches its ceiling, and approximately 2 when stabilization has taken place. EWFs based on GTP resemble those based on CETO when the time left to when stabilization occurs is sufficiently large. Once stabilization has occurred CETO values resemble RDC based values. If aviation-induced cirrus clouds are included, uncertainties increase and the EWFs for GWP, SGTP and RDC based metrics end up in the range 1.3–2.9, while EWFs for GTP and CETO remain close to unity in the near term.     

Settling-velocity distributions and sorting processes on a longitudinal dune: A case study

The processes acting on a longitudinal dune are inferred from the response in the area size-sorting characteristics of the sediment of the active layer. The sediment size distributions are determined by settling and are best described by a log-hyperbolic model which provides the most information on size-sorting processes. Size-sorting characteristics are markedly different across the low round-crested part of the dune from cross-sections of the high more sharp-crested part. This results in changes in textural parameters along the lee-side consistent with changes in the lee-side separation vortex. This is the first time that the effect of wind speed up on the lee-side is observed to be reflected in the sediment; it can only be detected with the very sensitive log-hyperbolic parameters.     

Explorations into the formal structure of drainage basins

Every basin of higher than first order is drained by a channel network composed of two subnetworks. Their basins are separated by a drainage divide line, called the basin divider, which is the primary organizing feature of the main basin. Each basin of magnitude n contains n – 1 subnetworks of higher order, and is therefore organized by a set of n – 1 dividers. The dividers and the basin boundary are interconnected in a graph called the divider network of the basin; in graph-theoretic terms this network forms a tree and has the same magnitude and link numbers as the channel network draining the basin. While the subbasins and subnetworks of a drainage basin form a nesting hierarchy, the corresponding dividers do not; indeed, any two dividers share at most one node in common, and whether they do so is independent of whether the corresponding subbasins are nesting or disjoint. However, the dividers of nesting basins are linked by recursive relationships which permit the derivation of a set of algebraic equations; these equations relate the dividers of a basin to other basin components; for example, their combined length is equal to half the length of all first-order basin boundaries minus the length of the main basin boundary. The second part of the paper explores the dependence of the divider length on other basin parameters. The expected length, as predicted by the assumption of topological randomness, is clearly rejected by the data. An alternative approach (regression) is based on the observed magnitudes of the subbasins separated by each divider, and is reasonably successful in estimating divider length. The last section introduces the concept of the standardized basin defined by a boundary length of unity; the estimated lengths of the basin divider and the basin boundary permit an approximate reconstruction of the idealized basin shape and the location of the divider in it.     

Development of a High Magnification Enlarger

Visual interpretation forms the basis for many operational applications of remote sensing. Suitable enlargement of remotely sensed data by optical projection is a basic requirement for visual interpretation. High Magnification Enlarger (HME) is a versatile interpretation aid developed for achieving wide-ranging scale transfer and variable-magnification display from a standard 24 cm format transparency. It operates on the principle of optical projection and is configured as a vertical column mounted unit. Low-distortion, high-quality enlarging lenses coupled with accuracy of alignment ensure accurate reproduction of the scale and the finer details from the input image transparency. Maximum user convenience is achieved by motorization of various controls.