HTP21/c–C2/c phase transition and kinetics of Fe2+–Mg order–disorder of an Fe-poor pigeonite: implications for the cooling history of ureilites

A natural Ca-poor pigeonite (Wo₆En₇₆Fs₁₈) from the ureilite meteorite sample PCA82506-3, free of exsolved augite, was studied by in situ high-temperature single-crystal X-ray diffraction. The sample, monoclinic P2₁/c, was annealed up to 1,093°C to induce a phase transition from P2₁/c to C2/c symmetry. The variation with increasing temperature of the lattice parameters and of the intensity of the b-type reflections (h + k = 2n + 1, present only in the P2₁/c phase) showed a displacive phase transition P2₁/c to C2/c at a transition temperature T _Tr = 944°C, first order in character. The Fe–Mg exchange kinetics was studied by ex situ single-crystal X-ray diffraction in a range of temperatures between the closure temperature of the Fe–Mg exchange reaction and the transition temperature. Isothermal disordering annealing experiments, using the IW buffer, were performed on three crystals at 790, 840 and 865°C. Linear regression of ln k _D versus 1/T yielded the following equation: ln k_\textD = - 3717( ±416)/T(K) + 1.290( ±0.378);    (R² = 0.988) \ln \,k_{\text{D}} = - 3717( \pm 416)/T(K) + 1.290( \pm 0.378);\quad (R^{2} = 0.988) . The closure temperature (T _c) calculated using this equation was ∼740(±30)°C. Analysis of the kinetic data carried out taking into account the e.s.d.'s of the atomic fractions used to define the Fe–Mg degree of order, performed according to Mueller’s model, allowed us to retrieve the disordering rate constants C ₀ K _dis⁺ for all three temperatures yielding the following Arrhenius relation: ln( C₀ K_\textdis ⁺ ) = ln K₀ - Q/(RT) = 20.99( ±3.74) - 26406( ±4165)/T(K);    (R² = 0.988) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = \ln \,K_{0} - Q/(RT) = 20.99( \pm 3.74) - 26406( \pm 4165)/T(K);\quad (R^{2} = 0.988) . An activation energy of 52.5(±4) kcal/mol for the Fe–Mg exchange process was obtained. The above relation was used to calculate the following Arrhenius relation modified as a function of X _Fe (in the range of X _Fe = 0.20–0.50): ln( C₀ K_\textdis ⁺ ) = (21.185 - 1.47X_\textFe ) - \frac(27267 - 4170X_\textFe )T(K) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = (21.185 - 1.47X_{\text{Fe}} ) - {\frac{{(27267 - 4170X_{\text{Fe}} )}}{T(K)}} . The cooling time constant, η = 6 × 10⁻¹ K⁻¹ year⁻¹ calculated on the PCA82506-3 sample, provided a cooling rate of the order of 1°C/min consistent with the extremely fast late cooling history of the ureilite parent body after impact excavation.     

Diatom quantification and their distribution with salinity brines in coastal sediments of Terra Nova Bay (Antarctica)

Benthic diatoms represent an important element of global nutritional productivity; to raise attention on their role, which is often neglected due to analytical difficulties, surface (1 cm top layer) coastal sediments from Gerlache inlet to Penguin Bay at Terra Nova Bay were collected and stored at -20 °C. DNA amplification by real-time PCR, based on diatom-specific oligonucleotide primers designed on small-subunit rRNA (SSU rRNA), was performed in addition to diatom conventional cell counting and spectrophotometric determination of photo-pigments. Moreover, cations and anions were determined in sediments with the aim to identify factors involved in the control of diatom abundance. Diatom distribution was found quite heterogeneous displaying significant differences from site to site. The salinity in sediments ranged from 45.1 at Gerlache inlet to 76.2 at Penguin Bay and it was correlated with cell abundance, biodiversity, amount of pigments and amplified DNA. The dominant species, Fragilariopsis curta, was associated to sediment salinity brines.     

Conjugate Points in the Gravitational n-Body Problem

In an effort to understand the nature of almost periodic orbits in the n-body problem (for all time t) we look first to the more basic question of the oscillatory nature of solutions of this problem (on a half-line, usually taken as R ⁺). Intimately related to this is the notion of a conjugate point(due to A. Wintner) of a solution. Specifically, by rewriting the mass unrestricted general problem of n-bodies in a symmetric form we prove that in the gravitational Newtonian n-body problem with collisionless motions there exists arbitrarily large conjugate points in the case of arbitrary (positive) masses whenever the cube of the reciprocal of at least one of the mutual distances is not integrable at infinity. The implication of this result is that there are possibly many Wintner oscillatorysolutions in these cases (some of which may or may not be almost periodic). As a consequence, we obtain sufficient conditions for all continuable solutions (to infinity) to be either unbounded or to allow for near misses (at infinity). The results also apply to potentials other than Newtonian ones. Our techniques are drawn from results in systems oscillation theory and are applicable to more general situations. Dedicated to the memory of Robert M. (Bob) Kauffman, formerly Professor of the University of Alabama in Birmingham     

Isotopic and element exchange during serpentinization and metasomatism at the Atlantis Massif (MAR 30°N): Insights from B and Sr isotope data

The Lost City hydrothermal system at the southern Atlantis Massif (Mid-Atlantic Ridge, 30°N) provides a natural laboratory for studying serpentinization processes, the temporal evolution of ultramafic-hosted hydrothermal systems, and alteration conditions during formation and emplacement of an oceanic core complex. Here we present B, O, and Sr isotope data to investigate fluid/rock interaction and mass transfer during detachment faulting and exhumation of lithospheric sequences within the Atlantis Massif. Our data indicate that extensive serpentinization was a seawater-dominated process that occurred predominately at temperatures of 150-250 °C and at high integrated W/R ratios that led to a marked boron enrichment (34-91 ppm). Boron removal from seawater during serpentinization is positively correlated with changes in δ¹¹B (11-16‰) but shows no correlation with O-isotope composition. Modeling indicates that B concentrations and isotope values of the serpentinites are controlled by transient temperature-pH conditions. In contrast to prior studies, we conclude that low-temperature marine weathering processes are insignificant for boron geochemistry of the Atlantis Massif serpentinites. Talc- and amphibole-rich fault rocks formed within a zone of detachment faulting at temperatures of approximately 270-350 °C and at low W/R ratios. Talc formation in ultramafic domains in the massif was subsequent to an early stage of serpentinization and was controlled by the access of Si-rich fluids derived through seawater-gabbro interactions. Replacement of serpentine by talc resulted in boron loss and significant lowering of δ¹¹B values (9-10‰), which we model as the product of progressive extraction of boron. Our study provides new constraints on the boron geochemical cycle at oceanic spreading ridges and suggests that serpentinization associated with ultramafic-hosted hydrothermal systems may have important implications for the behavior of boron in subduction zone settings.     

Strain rates in the Alpine Mediterranean region: insights from advanced techniques of data processing

Strain rates and Euler poles for various subregions of the Alpine Mediterranean region were calculated by using global navigation satellite system data from permanent stations. The main scope of the study is to compare and analyze strain rate maps that were calculated using different approaches. This area presents a complex tectonic setting due to the interaction of the Eurasian and Nubian plates. The horizontal velocity gradient tensor was computed starting from a new set of site velocities determined by using continuous long-series geodetic data, state-of-the-art antenna calibrations and recomputed precise orbits. Geodesy provides velocities for a sparsely distributed, discrete number of sites, while deformation has a spatially continuous distribution. For this reason, the interpolation method and the geometric approach to the problem play a fundamental role in the estimation of the strain rate field. In the present study, principal deformation axes and principal angle were estimated by applying two different approaches: the Delaunay triangulation and a grid solution. Both methods produce results with broad coherence, providing new information about the deformation throughout the entire study area. Moreover, an evaluation and analysis of Euler poles related to the different velocity patterns, give complementary information to reconstruct the active deformation in the Mediterranean area.     

Time-dependent ground movements induced by shield tunneling in soft clay: a parametric study

In this work, the effects of coupled hydromechanical (consolidation) processes associated with shield tunneling excavation in soft clays are investigated with particular attention to the prediction of ground movements at the ground surface. A series of 2d FE analyses have been carried out in parametric form in order to investigate the effects of tunnel excavation velocity relative to the soil consolidation rate and the hydraulic boundary conditions at the tunnel boundary. The shield advancement process has been simulated with a simplified procedure incorporating both volume loss and ovalization of the tunnel section. In order to investigate the relative importance of soil consolidation during the excavation process, different characteristic times for the tunnel face advancement and for the consolidation process around the tunnel have been considered, for the two limiting conditions of fully permeable liner and impervious liner. The potential damage induced by the tunnel excavation on existing structures, based on computed ground surface distortions and horizontal deformations, has been found to vary significantly with time during the consolidation process. The results of the simulations allowed to obtain useful information on the minimum tunnel face advancement speed for which the assumption of fully undrained conditions for the soil during the excavations is acceptable, as well as on the speed range for which solving the fully coupled hydromechanical problem is necessary.     

Correction to: Rip current hazard assessment on a sandy beach in Liguria,NW Mediterranean

Natural Hazards - The article was published showing the first two author names in the wrong order.