Crystal chemistry, surface morphology and X-ray photoelectron spectroscopy of Fe-rich osumilite from Mt. Arci, Sardinia (Italy)

Microprobe analysis, single crystal X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy, and X-ray absorption spectroscopy were applied on Fe-rich osumilite from the volcanic massif of Mt. Arci, Sardinia, Italy. Osumilite belongs to the space group P6/mcc with unit cell parameters a = 10.1550(6), c = 14.306(1) Å and chemical formula (K_0.729)_C (Na_0.029)_B (Si_10.498 Al_1.502)_T1 (Al_2.706 Fe _0.294 ²⁺ )_T2 (Mg_0.735 Mn_0.091 Fe _1.184 ²⁺ )_AO₃₀. Structure refinement converged at R = 0.0201. Unit cell parameter a is related to octahedral edge length as well as to Fe²⁺ content, unlike the c parameter which does not seem to be affected by chemical composition. The determination of the amount of each element on the mineral surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s and Fe_2p core levels, suggests that Fe presents Fe²⁺ oxidation state and octahedral coordination. Two peaks at 103.1 and 100.6 eV can be related to Si⁴⁺ and Si¹⁺ components, respectively, both in tetrahedral coordination. The binding energy of Al_2p, at 74.5 eV, indicates that Al is mostly present in the distorted T2 site, whereas the Mg peak at 1,305.2 eV suggests that this cation is located at the octahedral site. X-ray absorption at the Fe L_2,3-edges confirms that iron is present in the mineral structure, prevalently in the divalent state and at the A octahedral site.     

Monitoring, prediction, and early warning using ground-based radar interferometry

In order to define adequate prevention measures and to manage landslide emergencies, real-time monitoring is required. This paper presents two different applications of the remote sensing technique: the ground-based synthetic aperture radar interferometry, here proposed as a monitoring and early warning support for slope instability. Data acquisitions carried out through a ground-based synthetic aperture radar interferometer, operating in K_u band, installed in front of the observed slopes, are discussed. Two case studies, based on the use of the same apparatus (formerly developed by the Joint Research Center of the European Commission and by Ellegi-LiSALab srl), are reported: the first one concerns the monitoring of a large landslide, named Ruinon (Valfurva, Italy). The second one deals with the monitoring of the NW unstable slope in the Stromboli island aimed to implementing an early warning system. Acquired interferometric data are processed to provide displacements and velocity maps of the monitored area. The monitoring services ongoing on the Ruinon landslide and on Stromboli demonstrate the capability of this technique to operate in different operative settings (i.e., different phenomena and geological framework) and for different aims (monitoring for prevention, early warning, and emergency assessment). This methodology has also been proved by national and regional authorities of civil protection in order to provide a real-time monitoring for emergency management.     

Provenance of Oligocene synorogenic sediments of the Ligurian Alps (NW Italy): inferences on belt age and cooling history

Mineral chemistry, ⁴⁰Ar/³⁹Ar geochronology on white micas and Apatite Fission Track Thermochronology (AFTT), are applied here to study the provenance of the synorogenic Molare Formation (lowermost unit of the Tertiary Piedmont Basin clastic sequence). The Molare Formation was deposited during transgression onto the Ligurian Alps nappe stack in the Early Oligocene. Depositional facies show that clastic distribution remained transversal, with local sources located just landward from the coastline. Phengite mineral chemistry together with ⁴⁰Ar/³⁹Ar data clearly shows two distinctive source areas, each one mirroring the composition of the basement directly beneath the clastic sequence. Amphibole mineral chemistry allows second order provenance distinctions within each sector, reflecting heterogeneous metamorphic evolution of the bedrock complexes. Integrated ⁴⁰Ar/³⁹Ar dating and AFTT suggest that, following a fast cooling/exhumation episode of the Ligurian Alps during the Oligocene, very little net uplift has since occurred. This is due to a period of general subsidence from the Oligocene–Late Miocene followed by comparable uplift from Late Miocene–Pliocene to the present. In general our data provide an image of the Ligurian Alps during the Oligocene, which is very similar to the present-day one.This revised version was published online in September 2003.     

Probabilistic assessment of structural operational efficiency in emergency limit conditions: the I.OPà.CLE method

One major issue in the aftermath of a strong earthquake is the emergency management, which cannot be guaranteed if the physical components necessary for the operability of the contingency plan are either damaged, unusable or inaccessible. In order to assess the physical efficiency of the emergency system on which a contingency plan is based, the I.OPà.CLE method (Indices for evaluation of the Operational efficiency of Limit Condition Emergency) has been set up by the Italian Civil Protection Department. It is basically aimed at supporting civil protection decision makers in evaluating emergency systems and establishing strategies and priorities concerning strengthening interventions at national, regional or municipality level. The method must be potentially applied to any of the around 8000 municipalities all over Italy, and then it must refer to a minimum information dataset readily available for any municipality. Therefore, I.OPà.CLE has been specifically tailored for the minimum standard information that is provided by the analysis of Limit Condition for Emergency, as formulated in 2012 by the Italian Civil Protection Department. This analysis defines the standard framework of the physical layout of a municipal seismic emergency plan, relying on a limited number of information. Notwithstanding the numerically extensive target and limited amount of information available, the ambition of I.OPà.CLE is to perform simplified analyses without renouncing to rigor in the methodology. The present paper illustrates the analytic formulation of I.OPà.CLE and its capabilities, as well as two real examples. In the conclusion, future upgrading of the model are discussed, even in relation to the availability of further pieces of information.     

The Intra-Pontide ophiolites in Northern Turkey revisited:From birth to death of a Neotethyan oceanic domain

The Anatolian peninsula is a key location to study the central portion of the Neotethys Ocean(s)and to understand how its western and eastern branches were connected.One of the lesser known branches of the Mesozoic ocean(s)is preserved in the northern ophiolite suture zone exposed in Turkey,namely,the Intra-Pontide suture zone.It is located between the Sakarya terrane and the Eurasian margin(i.e.,Istanbul-Zonguldak terrane)and consists of several metamorphic and non-metamorphic units containing ophiolites produced in supra-subduction settings from the Late Triassic to the Early Cretaceous.Ophiolites preserved in the metamorphic units recorded pervasive deformations and peak metamorphic conditions ranging from blueschist to eclogite facies.In the nonmetamorphic units,the complete oceanic crust sequence is preserved in tectonic units or as olistoliths in sedimentary melanges.Geochemical,structural,metamorphic and geochronological investigations performed on ophiolite-bearing units allowed the formulation of a new geodynamic model of the entire"life"of the IntraPontide oceanic basin(s).The reconstruction starts with the opening of the Intra-Pontide oceanic basins during the Late Triassic between the Sakarya and Istanbul-Zonguldak continental microplates and ends with its closure caused by two different subductions events that occurred during the upper Early Jurassic and Middle Jurassic.The continental collision between the Sakarya continental microplate and the Eurasian margin developed from the upper Early Cretaceous to the Palaeocene.The presented reconstruction is an alternative model to explain the complex and articulate geodynamic evolution that characterizes the southern margin of Eurasia during the Mesozoic era.     

Positive fault inversion triggering 'intrusive diapirism': an analogue modelling perspective

Understanding the formation and the development of salt structures is very important especially because they are of significant economical interest for hydrocarbon trapping and for long-term storage of radioactive waste and energy reserves. Generally, the activity of normal faults developed in extensional regimes is considered the most efficient mechanism for salt diapirs. The results of analogue models reported in this paper suggest a new triggering mechanism for the rise of salt structures during basin inversion. This mechanism relates the localization of ductile diapirs to early normal faults only after their inversion during later shortening. In this case, diapiric growth is related to the strong dip-slip reactivation component along the fault extruding the silicone-simulating salt upward. Some natural cases, in which the timing and the mechanism of diapiric growth is not clear, can be re-interpreted in the light of these analogue model results.     

Petrological constraints on the tectonic setting of the Kathmandu Nappe in the Langtang–Gosainkund–Helambu regions,Central Nepal Himalaya

The Gosainkund–Helambu region in central Nepal occupies a key area for the development of Himalayan kinematic models, connecting the well‐investigated Langtang area to the north with the Kathmandu Nappe (KN), whose interpretation is still debated, to the south. In order to understand the structural and metamorphic architecture of the Greater Himalayan Sequence (GHS) in this region, a detailed petrological study was performed, focusing on selected metapelite samples from both the Gosainkund–Helambu and Langtang transects. The structurally lowest sample investigated belongs to the Lesser Himalayan Sequence; its metamorphic evolution is characterized by a narrow hairpin P–T path with peak P–T conditions of 595 ± 25 °C, 7.5 ± 1 kbar. All of the other samples here investigated belong to the GHS. Along the Langtang section, two tectono‐metamorphic units have been distinguished within the GHS: the Lower Greater Himalayan Sequence (L‐GHS), characterized by peak P–T conditions at 728 ± 11 °C, 10 ± 0.5 kbar (corresponding to a T/depth ratio of 22 ± 1 °C km^?1), and the structurally higher Upper Greater Himalayan Sequence, with peak metamorphic conditions at 780 ± 20 °C, 7.8 ± 0.8 kbar (corresponding to a T/depth ratio of 31 ± 4 °C km^?1). This confirms the existence of a main tectono‐metamorphic discontinuity within the GHS, as previously suggested by other authors. The results of petrological modelling of the metapelites from the Gosainkund–Helambu section show that this region is entirely comprised within a sub‐horizontal and thin L‐GHS unit: the estimated peak metamorphic conditions of 734 ± 19 °C, 10 ± 0.8 kbar correspond to a uniform T/depth ratio of 23 ± 3 °C km^?1. The metamorphic discontinuity identified along the Langtang transect and dividing the GHS in two tectono‐metamorphic units is located at a structural level too high to be intersected along the Gosainkund–Helambu section. Our results have significant implications for the interpretation of the KN and provide a contribution to the more general discussion of the Himalayan kinematic models. We demonstrate that the structurally lower unit of the KN (known as Sheopuri Gneiss) can be correlated with the L‐GHS unit; this result strongly supports those models that correlate the KN to the Tethyan Sedimentary Sequence and that suggest the merging of the South Tibetan Detachment System and the Main Central Thrust on the northern side of the KN. Moreover we speculate that, in this sector of the Himalayan chain, the most appropriate kinematic model able to explain the observed tectono‐metamorphic architecture of the GHS is the duplexing model, or hybrid models which combine the duplexing model with another end‐member model.     

On the misinterpretation of the North Atlantic Oscillation in CMIP5 models

The representation of the wintertime North Atlantic Oscillation (NAO) and its relationship with atmospheric blocking and the Atlantic jet stream is investigated in a set of CMIP5 models. It is shown that some state-of-the-art climate models are unable to correctly simulate the physical processes connected to the NAO. This is especially true for models with a strongly underestimated frequency of high-latitude blocking over Greenland. In these models the first empirical orthogonal function (EOF1) of the Euro-Atlantic sector can represent at least three different categories of dominant modes of variability associated with different prevalent regions of blocking occurrence and jet stream displacements. It is therefore possible to show that such “biased NAOs” are connected with different dynamical processes with respect to the canonical NAO seen in observations. Since the NAO is a widely used concept in scientific community, the consequent “dynamical misinterpretation” of the NAO that can result when climate models are analyzed may have important implications for the NAO-related studies. This may be especially relevant for the ones involving climate scenarios, since these modeled NAOs may react differently to greenhouse gas forcing.