Spectral reflectivities of the Galilean satellites and Titan, 0.32 to 0.86 micrometers

A spectrophotometric observational study of the Galilean satellites and Titan was carried out at 0.004-μm (40-Å) resolution over the spectral range 0.32 to 0.86 μm. A standard lunar area was used as a primary spectroscopic standard to establish the relative reflection spectra of the objects by ratioing the sky-corrected satellite spectra to the standard area on the Moon. J1 (Io) is found to have a spectral edge at 0.33 μm that has not been previously reported. The increase in reflectivity from 0.4 to 0.5 μm and the band at 0.56 μm are confirmed. A weak band at 0.56 μm is probable on J2 (Europa) and possible on J3 (Ganymede). J4 (Callisto) shows no spectral features that have not been previously reported. On Titan, no temporal variations in the methane bands greater than 2% were found, indicating that the effective path length in the Titan atmosphere did not change over the 3-month period of this study. A new absorption band of methane at 0.68 μm was found on Titan. We propose an extension of the evaporite model of Fanale et al. (1974, 1977) and the sulfur mixing models of Wamsteker et al. (1974) in which the primary constituent of the surface of J1 is elemental sulfur sublimated onto the surface by photodissociation of hydrogen sulfide outgassing from the interior. The sulfur is continually renewed by sublimation, sputtering, and redeposition. At low temperatures irradiation produces stable S₂, S₃, S₄, S₆, and long chain polymers. Some of these allotropes have an edge at 0.33 μm, a rising reflectance between 0.4 and 0.5 μm a band at 0.56 μm. All of these features are found in the spectrum of J1. We conclude that the lunar ratioing technique used in this study is well suited for determining the relative reflection spectra of solar system objects.     

Correlation of 13C12C and 34S32S secular variations

Statistical evaluation of 3056 δ¹³C measurements in carbonate rocks and fossils shows that they record a 2‰ ¹³C depletion from the late Proterozoic to the early Paleozoic, a 2.5‰ enrichment to the Permian, and a 1.5‰ depletion to the Cenozoic. These variations, not controlled primarily by facies or alteration phenomena, correlate negatively with the δ³⁴S sulfate secular trend, as confirmed by collation of 1083 δ³⁴S measurements. The correlation suggests that the biologically mediated redox fluxes of the C and S cycles have been approximately balanced through this long span of geological time, generally levelling available oxygen. Such a redox system is consistent with the controlling mechanism proposed by Garrels and Perry (1974). Consequently, the sedimentary reservoirs of C_organic as well as S_{bacteriological'}have varied through geological time.     

Gender, science and physical geography in nineteenth-century Britain

Summary This paper considers the gendered construction of science and scientific geography in Britain during the nineteenth century. It explores the general exclusion of women from public, institutionalized science and their location in amateur, domestic pursuits, whilst simultaneously problematizing this binary construction. Finally, the paper speculates on the legacy of the past on the gendering of contemporary physical geography.     

The predictability of near-coastal currents using a baroclinic unstructured grid model

A limited domain, coastal ocean forecast system consisting of an unstructured grid model, a meteorological model, a regional ocean model, and a global tidal database is designed to be globally relocatable. For such a system to be viable, the predictability of coastal currents must be well understood with error sources clearly identified. To this end, the coastal forecast system is applied at the mouth of Chesapeake Bay in response to a Navy exercise. Two-day forecasts are produced for a 10-day period from 4 to 14 June 2010 and compared to real-time observations. Interplay between the temporal frequency of the regional model boundary forcing and the application of external tides to the coastal model impacts the tidal characteristics of the coastal current, even contributing a small phase error. Frequencies of at least 3 h are needed to resolve the tidal signal within the regional model; otherwise, externally applied tides from a database are needed to capture the tidal variability. Spatial resolution of the regional model (3 vs 1 km) does not impact skill of the current prediction. Tidal response of the system indicates excellent representation of the dominant M ₂ tide for water level and currents. Diurnal tides, especially K ₁, are amplified unrealistically with the application of coarse 27-km winds. Higher-resolution winds reduce current forecast error with the exception of wind originating from the SSW, SSE, and E. These winds run shore parallel and are subject to strong interaction with the shoreline that is poorly represented even by the 3-km wind fields. The vertical distribution of currents is also well predicted by the coastal model. Spatial and temporal resolution of the wind forcing including areas close to the shoreline is the most critical component for accurate current forecasts. Additionally, it is demonstrated that wind resolution plays a large role in establishing realistic thermal and density structures in upwelling prone regions.     

A Time-Dependent Model of Radiative and Conductive Thermal Energy Transport in Planetary Regoliths with Applications to the Moon and Mercury

Modeling thermal energy transfer in planetary regoliths involves treating four processes: visible radiative transfer, thermal radiative transfer, conductive transfer, and heat storage. We explicitly treat these processes while considering time-dependent problems, and we apply this model to the regoliths of the Moon and Mercury. Fitting the model to observational data allows us to constrain the radiative resistivity and thermal inertia parameters of these regoliths and hence constrain their conductivities, thermal extinction coefficients, and average grain sizes. It is also found that water ice would be stable in the polar subsurfaces of both bodies, even in areas which receive sunlight during the day.     

(Re)politicizing empowerment: Lessons from the South African wine industry

Despite being a poorly defined and vague concept, empowerment is currently of political and theoretical significance and nowhere more so than in South Africa, where it seen as central to post-apartheid transformation. This paper explores the ways in which empowerment has been understood, defined and deployed by post-apartheid governments in the context of a gradual shift from nation-building to neo-liberal governance. It examines the impact of legislation and government policy through a critical examination of empowerment initiatives in the wine industry. Drawing on research conducted in the Western Cape in 2004, the paper analyses how empowerment is interpreted and appropriated both within legislation and specifically within the wine industry. It explores what the wine industry reveals about the disempowering work of neo-liberalism, even as it is couched in the discourses of empowerment. Findings suggest that equating empowerment with economic empowerment threatens to reinforce structures of domination, rather than transforming them, while leaving power relations largely untouched. The case study reveals that until more radical understandings of power and empowerment are acknowledged and incorporated into government policies the failure to address broader issues of social and economic transformation will persist and policies aimed at the empowerment of marginalised individuals and communities will continue to have apparently pre-determined and depoliticised outcomes.     

Intrinsic bioremediation of a petroleum-impacted wetland

Following the 1994 San Jacinto River flood and oil spill in southeast Texas, a petroleum-contaminated wetland was reserved for a long-term research program to evaluate bioremediation as a viable spill response tool. The first phase of this program, presented in this paper, evaluated the intrinsic biodegradation of petroleum in the contaminated wetland. Sediment samples from six test plots were collected 11 times over an 11-month period to assess the temporal and spatial petroleum concentrations. Petroleum concentrations were evaluated using gas chromatography-mass spectrometer analyses of specific target compounds normalized to the conservative biological marker, C(30)17alpha,21beta(H)-hopane. The analyses of specific target compounds were able to characterize that significant petroleum biodegradation had occurred at the site over the one-year period. Total resolved saturate and total resolved aromatic hydrocarbon data indicated the petroleum was degraded more than 95%. In addition, first-order biodegradation rate constants were calculated for the hopane-normalized target compounds and supported expected biodegradation patterns. The rapid degradation rates of the petroleum hydrocarbons are attributed to conditions favorable to biodegradation. Elevated nutrient levels from the flood deposition and the unconsolidated nature of the freshly deposited sediment possibly provided a nutrient rich, oxic environment. Additionally, it is suggested that an active and capable microbial community was present due to prior exposure to petroleum. These factors provided an environment conducive for the rapid bioremediation of the petroleum in the contaminated wetland.