气相色谱法测定地下水中六六六结果的不确定度评定

依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。     

阿尔金断裂昌马大坝—宽滩山段全新世活动特征

阿尔金断裂是我国西部著名的巨型走滑断裂带之一,也是全新世活动断裂和发震断裂。该断裂昌马大坝—宽滩山段运动方式为以左行走滑占主导,伴有弱的垂直运动;在距今2.7ka以来发生过明显的新构造活动（和地震）。在沙坪—宽滩山段全新世左行走滑位移速率为0.9～2.2mm/a,明显低于阿尔金断裂东段昌马大坝以西地区4～5mm/a和中西段9～11mm/a的位移速率。阿尔金断裂东段在肃北和昌马大坝出现二次位移速率的锐减,锐减的部分分别转化为海原活动断裂西段（党河南山断裂）和祁连山北缘活动断裂西段的左行走滑和逆冲,且在位移速率数值上相互之间具有非常好的对应性。阿尔金断裂在肃北位移速率减少部分（4.6mm/a）与海原活动断裂西段（党河南山断裂）的位移速率（4～5mm/a）非常接近,同样阿尔金断裂在昌马大坝位移速率减少部分（3.2mm/a）与祁连山北缘活动断裂的位移速率（3.0mm/a）也非常接近。     

云南个旧老厂-卡房花岗岩体成因：锆石U-Pb年代学和岩石地球化学约束

在云南个旧地区发育大量与成矿时空密切相关的侵入岩。个旧东区的老厂-卡房花岗质岩体为一隐伏的花岗岩体,侵入于三叠纪个旧组灰岩和碳酸盐地层中,岩性主要为中细粒黑云母花岗岩,是个旧地区与成矿关系最为密切的花岗岩体之一。岩石的ACNK值大多在1.0以上,属于高钾钙碱性系列岩石;U、Th含量较高,应归属于HHP花岗岩;岩石类型属于S型花岗岩,但经历了高度的分异和演化;n(Rb)/n(Sn)- n(Rb)/n(Ba)与n(CaO)/n(Na2O)-n(Al2O3)/n(TiO2)图解均暗示岩石的源区性质为由粘土岩所派生的岩浆。锆石LA-ICP-MS定年结果表明,老厂-卡房岩体形成于85±0.85Ma,相当于晚白垩世。根据区域地质和花岗岩的地球化学特征,暗示个旧地区燕山晚期处于伸展构造背景。     

松科1井南孔选址、岩心剖面特征与特殊岩性层的分布

松科1井南孔是松辽盆地白垩系科学钻探工程两个钻孔中的一个,位于松辽盆地北部中央坳陷区齐家古龙凹陷敖南鼻状构造的翼部。通过对松科1井南孔嫩二段底部到泉三段顶部连续取心资料的详细描述,建立松科1井南孔岩心剖面,识别出5种常见岩性(泥岩、粉砂质泥岩、泥质粉砂岩、粉砂岩和细砂岩)和8种特殊岩性(白云岩、火山灰、油页岩、灰质泥岩、泥灰岩、重结晶灰岩、介形虫碎屑灰岩和介形虫灰岩)。特殊岩性出现的总层数为172层,总厚度为14.516m,分布在青一段,青二、三段,姚二、三段,嫩一段和嫩二段地层中。对松科1井的精细岩心描述和对特殊岩性的识别是后续研究工作开展的基础。     

Impact of land use covers upon karst processes in a typical Fengcong depression system of Nongla, Guangxi, China

The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land, fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly affected by soil CO₂ in tilled land and shrub.     

Dissolved trace elements and heavy metals in the Danjiangkou Reservoir,China

Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project, were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results would help develop water resource management and conservation strategy for the interbasin water transfer project.     

Sulfide-driven arsenic mobilization from arsenopyrite and black shale pyrite

We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As−1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O₂), hypoxic (2% O₂, 98% N₂), and anoxic (5% H₂, 95% N₂) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (−1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.     

Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

渤海湾盆地新生界生油岩系底界面温度分布

依据渤海湾盆地2000余口测温井的地温梯度数据、地层岩性描述、分层数据以及钻井资料,计算了该盆地各生油岩系底界面的温度。统计结果表明:渤海湾盆地沙河街组大部分凹陷区地层底界面温度介于90℃至150℃,目前仍具有大量生油的温度条件,而在隆起或一些凸起地区,该地层组段温度普遍小于90℃,未能达到生油的温度指标。东营组和孔店组地层也仍具有一定的生油温度条件。研究还表明:地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷区地层界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。     

塔里木盆地西部吐木休克断裂带的主要特征和构造演化

塔里木盆地西部的吐木休克断裂带是中央隆起(前身是晋宁期碰撞造山带)的次级单元巴楚断隆与北部坳陷的次级单元阿瓦提凹陷之间的分界。本文以大量的地质和地球物理证据,证明它是一条内部结构复杂且切穿地壳的深断裂。结合区域构造演化恢复了断裂发育史,指出它经历过三期重大的冲断活动,分别发生在加里东期、海西期和新近纪。新近纪的冲断与巴楚断隆的南界断裂带有相同的构造样式,可分为两幕:中新世的冲断受制于南天山前陆冲断带的向南扩展,更新世的冲断主要受制于西昆仑前陆冲断带的向北扩展。吐木休克断裂带的东西走向段和北西走向段的构造特征尚有若干差异,前者在加里东期活动较强,反映了构造的继承性;北西走向段则是加里东期出现的新生构造,在海西期进一步发展,更新世时因被卷入西昆仑的前陆冲断作用,表现出强烈而复杂的变形。