An application of Boussinesq equations to Bragg reflection of irregular waves

A numerical model based on the second-order fully nonlinear Boussinesq equations of Wei et al. [1995. Journal of Waterway, Port, Coastal and Ocean Engineering 121 (5), 251-263] is developed to simulate the Bragg reflection of both regular and irregular surface waves scattered by submerged bars. Particularly for incident regular waves, the computed results are observed to agree very well with the existing experimental data as presented by Davies and Heathershaw [1984. Journal of Fluid Mechanics 144, 419-446] and Kirby and Anton [1990. Proceedings of the 22nd International Conference on Coastal Engineering, ASCE, New York, pp. 757–768). In the case of incident irregular waves, the simulated results reveal that the distribution of Bragg reflection from irregular waves becomes more flat than that of regular waves. Due to lack of experimental data, the numerical results for incident irregular waves are compared with those of the evolution equation of the mild-slope equation [Hsu et al., 2002 Proceedings of the 24th Ocean Engineering Conference in Taiwan, pp. 70–77 (in Chinese)]. In addition, several parameters such as the number of bars, the relative height of bars and the spacing of bars affecting Bragg reflection are also discussed.     

Sequential solvent extraction for the modes of occurrence of selenium in coals of different ranks from the Huaibei Coalfield, China

Forms of selenium in bituminous coal, anthracite, and cokeite (natural coke) from Huaibei Coalfield, Anhui, China, have been determined by sequential solvent extraction. The selenium content in bulk samples is 4.0, 2.4, and 2.0 μg/g in bituminous coal, anthracite, and cokeite, respectively. The six forms of selenium determined by six-step solvent extraction are water-leachable, ion-exchangeable, organic matter-associated, carbonate-associated, silicate-associated, and sulfide-associated. The predominant forms of selenium in bituminous coal are organic matter-associated (39.0%), sulfide-associated (21.1%), and silicate bound (31.8%); these three forms account for 92% of the total. The organic matter bound-selenium decrease dramatically from bituminous coal (39.0%) to anthracite (11.6%) and to cokeite (0%), indicating that organic matter bound selenium is converted to other forms during metamorphism of the coal, most likely sulfide-form. The sulfide-associated form increased remarkably from bituminous coal (21.1%) to anthracite (50.4%) and cokeite (54.5%), indicating the formation of selenium sulfide, possibly in pyrite during the transformation of bituminous coal to anthracite and cokeite. The silicate-associated selenium in bituminous coal (31.8%) is much higher than that in anthracite (16.4%) and cokeite (15.8%), indicating that silicate-associated selenium is partly converted to sulfide during metamorphism.     

大凌河隐伏断裂的确定

大凌河隐伏断裂存在与否一直是一个没有解决的问题,随着经济建设的不断发展,迫切要求对这个问题有一个明确的回答。本文采用地球物理探测方法,并结合跨大凌河的钻孔剖面,认定在大凌河床底部存在有隐伏断裂。     

Performance of Goddard earth observing system GCM column radiation models under heterogeneous cloud conditions

We test the performance of the shortwave (SW) and longwave (LW) Column Radiation Models (CORAMs) of Chou and collaborators with heterogeneous cloud fields from a single-day global dataset produced by NCAR's Community Atmospheric Model (CAM) with a 2-D Cloud Resolving Model (CRM) installed in each column. The original SW version of the CORAM performs quite well compared to reference Independent Column Approximation (ICA) calculations for boundary fluxes (global error 4 W m⁻² for reflected flux), largely due to the success of a combined overlap and cloud scaling parameterization scheme. The absolute magnitude of errors relative to ICA are even smaller (global error 2 W m⁻² for outgoing flux) for the LW CORAM which applies similar overlap. The vertical distribution of heating and cooling within the atmosphere is also simulated quite well with daily averaged zonal errors always less than 0.3 K/day for SW and 0.6 K/day for LW heating (cooling) rates. The SW CORAM's performance improves by introducing a scheme that accounts for cloud inhomogeneity based on the Gamma Weighted Two Stream Approximation (GWTSA).These results suggest that previous studies demonstrating the inaccuracy of plane-parallel models may have unfairly focused on worst case scenarios, and that current radiative transfer algorithms in General Circulation Models (GCMs) may be more capable than previously thought in estimating realistic spatial and temporal averages of radiative fluxes, as long as they are provided with correct mean cloud profiles. However, even if the errors of our particular CORAMs are small, they seem to be systematic, and their impact can be fully assessed only with GCM climate simulations.     

Plasticity‐fibre model for steel triangular plate energy dissipating devices

Properly fabricated triangular‐plate added damping and stiffness (TADAS) devices can sustain a large number of yield reversals without strength degradation, thereby dissipating a significant amount of earthquake‐induced energy. A pronounced isotropic‐hardening effect is recognized in the force‐deformation relationships of the TADAS devices made from two grades of low yield strength steel. The proposed plasticity‐fibre model employing two surfaces (a yield surface and a bounding surface) in plasticity theory accurately predicts the experimental responses of the TADAS devices. This model is also implemented into a computer program DRAIN2D+ to investigate a frame response with the TADAS devices. Substructure pseudo‐dynamic tests and analytical studies of a two‐storey steel frame constructed with the low yield strength steel, LYP‐100 or LYP‐235 grade, TADAS devices confirm that the dynamic structural response can only be predicted if the proposed plasticity‐fibre model is used for LYP‐100 steel TADAS device. Copyright © 2002 John Wiley & Sons, Ltd.     

Fisher判别分析中投影空间的优化问题

本文对Fisher意义下的判别分析中泛函值 λ=C~T·B·C/C~T·W·C与判别效果(指 错判个数)之间的非同一性进行了讨论,指出在m个变量构成的m维空间中,由广义特征问题 (B-λW)C=0的特征向量所决定的投影空间不一定是判别效果最优的空间,即,泛函λ取 极值与判别效果取极值不是等价问题。 本文构造了一个与Fisher判别效果相一致,但又无解析形式的泛函: I=I(C_1,C_2,…,C_r)它建立在线性函数集合之上,I取极值与判别效果取极值是等价的。 文章提出了可采用最优化方法根据泛函λ值取极值的解求得泛函I值取极值的解,从而 解决了Fisher判别分析中投影空间的优化问题。实例计算表明,在优化的投影空间中进行 Bayes准则判别其效果要优于由广义特征问题(B-λW)C=0所决定的投影空间中所进行 的判别。     

Determining elastic constants of transversely isotropic rocks using Brazilian test and iterative procedure

The elastic constants of rocks are the basic parameters for rock mechanics, and play a very important role in engineering design. There are many laboratory methods to determine the elastic constants of transversely isotropic rocks, and the Brazilian test is a popular method. This paper presented a method combination of the Brazilian test, back calculation, and iterative procedure to evaluate the five independent elastic constants of transversely isotropic rocks in laboratory. The strain data at the centre of discs were obtained using Brazilian test. The stresses at the centre of discs were computed using numerical programs. By using back calculation, the temporary elastic constants were computed after the stresses and stains were substituted into elastic mechanics equations. After iterative procedure, the convergent values of the elastic constants can be obtained. One numerical example and three experimental cases were proposed to show the applicability of this method. The convergent values of the five independent elastic constants can be obtained in no more than 10 iterative cycles. The results coming from numerical analysis method exhibited satisfactory outcome in accordance with those of generalized reduced gradient method. The merits of this method include convenient specimen preparation of the Brazilian test, simple iterative procedure, and readily available commercially numerical programs, so that this method can be easily popularized in research and engineering analysis. Copyright © 2007 John Wiley & Sons, Ltd.     

Development of Cu and Zn Isotope MC-ICP-MS Measurements: Application to Suspended Particulate Matter and Sediments from the Scheldt Estuary

The present study evaluates several critical issues related to precision and accuracy of Cu and Zn isotopic measurements with application to estuarine particulate materials. Calibration of reference materials (such as the IRMM 3702 Zn) against the JMC Zn and NIST Cu reference materials were performed in wet and/or dry plasma modes (Aridus I and DSN‐100) on a Nu Plasma MC‐ICP‐MS. Different mass bias correction methods were compared. More than 100 analyses of certified reference materials suggested that the sample‐calibrator bracketing correction and the empirical external normalisation methods provide the most reliable corrections, with long term external precisions of 0.06 and 0.07‰ (2SD), respectively. Investigation of the effect of variable analyte to spike concentration ratios on Zn and Cu isotopic determinations indicated that the accuracy of Cu measurements in dry plasma is very sensitive to the relative Cu and Zn concentrations, with deviations of δ⁶⁵Cu from ?0.4‰ (Cu/Zn = 4) to +0.4‰ (Cu/Zn = 0.2). A quantitative assessment (with instrumental mass bias corrections) of spectral and non‐spectral interferences (Ti, Cr, Co, Fe, Ca, Mg, Na) was performed. Titanium and Cr were the most severe interfering constituents, contributing to inaccuracies of ?5.1‰ and +0.60‰ on δ^68/64Zn, respectively (for 500 μg l^?1 Cu and Zn standard solutions spiked with 1000 μg l^?1 of Ti or Cr). Preliminary isotopic results were obtained on contrasting sediment matrices from the Scheldt estuary. Significant isotopic fractionation of zinc (from 0.21‰ to 1.13‰ for δ⁶⁶Zn) and copper (from ?0.38‰ to 0.23‰ for δ⁶⁵Cu), suggest a control by physical mixing of continental and marine water masses, characterized by distinct Cu and Zn isotopic signatures. These results provide a stepping‐stone to further evaluate the use of Cu and Zn isotopes as biogeochemical tracers in estuarine environments.     

Two modes of climatic control in the Holocene stalagmite record from the Japan Sea side of the Japanese islands

The Holocene stalagmite FG01 collected at the Fukugaguchi Cave in Itoigawa, central Japan provides a unique high‐resolution record of the East Asian winter monsoon. Because of the climate conditions on the Japan Sea side of the Japanese islands, the volume of precipitation during the winter is strongly reflected in the stalagmite δ¹⁸O signal. Examination of the carbon isotopes and the Mg/Ca ratio of FG01 provided additional information on the Holocene climate in Itoigawa, which is characterized by two different modes separated at 6.4 ka. Dripwater composition and the correlation between the δ¹³C and Mg/Ca data of FG01 indicate the importance of prior calcite precipitation (PCP), a process that selectively eliminated ¹²C and calcium ions from infiltrating water from CO₂ degassing and calcite precipitation. In an earlier period (10.0–6.4 ka), an increase in soil pCO₂ associated with warming and wetting climate trends was a critical factor that enhanced PCP, and resulted in an increasing trend in the Mg/Ca and δ¹³C data and a negative correlation between the δ¹³C and δ¹⁸O profiles. A distinct peak in the δ¹³C age profile at 6.8 ka could be a response to an increase of approximately 10% in C4 plants in the recharge area. At 6.4 ka, the climate mode changed to another, and correlation between δ¹⁸O and δ¹³C became positive. In addition, a millennial‐scale variation in δ¹⁸O and pulsed changes in δ¹³C and Mg/Ca became distinct. Assuming that δ¹⁸O and PCP were controlled by moisture in the later period, the volume of precipitation was high during 6.0–5.2, 4.4–4.0, and 3.0–2.0 ka. In contrast, the driest interval in Itoigawa was during 0.2–0.4 ka, and broadly corresponds to the Little Ice Age.