甲醛还原Pt/TiO2催化剂用于温和条件下高效催化氧化甲醛（英文）

通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差.     

论滑坡学

滑坡学可分为理论滑坡学和应用滑坡学．前者的分支有：滑坡发生学、滑坡运动学、滑坡组构学、滑坡形态学、滑坡断代－周期学、滑坡分类学、滑坡分布学、滑坡制图学、滑坡编目学和滑坡数据库系统等．应用滑坡学含滑坡研究方法论、技术手段和滑坡防御工程等．     

Softs of Fildes Peninsula, King George Island, the maritime Antarctic: Part I. Formation processes and pedogenetic particularities

Based on the data obtained from tens of the investigated soil profiles scattered over the Fildes Peninsula, King George Island, the maritime Antarctic, the soil-forming processes were discussed. It was concluded that on the weathering crusts resulted from various physical courses, the strong freeze-thaw action within regolith, significant organic matter accumulation, evident leaching and illuviation, as well as initial argillification dominated the formation and development of the soils on the Fildes Peninsula. Furthermore, this study indicated that the juvenility of genesis, poor profile-expression, variation in column thickness, etc. characterized the pedogenetic features of the soils of the Fildes Peninsula.     

Seasonal change of ice algal and phytoplankton assemblages in the Nella Fjord near Zhongshan Station, East Antarctica

The ice algal and phytoplankton assemblages were studied from Nella Fjord near Zhongshan Station, East Antarctica from April 12 to December 30, 1992. Algal blooms occurred about 3 cm thick on the bottom of sea ice in late April and mid November to early December respectively, and a phytoplankton bloom appeared in the underlying surface water in mid December following the spring ice algal bloom. The biomass in ice bottom was 1 to 3 orders of magnitude higher than that of surface water. Amphiprora kjellmanii, Berkeleya sp., Navicula glaciei, Nitzschia barkelyi, N. cylindrus /N. curta, N. lecointei and Nitzschia sp. were common in the sea ice temporarily or throughout the study period. The biomass in a certain ice segment was decreased gradually and the dominant species were usually succeeded as the season went on. Nitzschia sublineata and Dactyliosolen antarctica were two seasonal dominant species only observed in underlying water column. The assemblages between bottom of ice and underlying surface water were different except when spring ice algae bloomed. The evidence shows that the ice algal blooms occurred mainly by in situ growth of ice algae, and the phytoplankton bloom was mostly caused by the release of ice algae.     

Effects of climate change on annual streamflow using climate elasticity in Poyang Lake Basin, China

Hydrological processes depend directly on climate conditions [e.g., precipitation, potential evapotranspiration (PE)] based on the water balance. This paper examines streamflow datasets at four hydrological stations and meteorological observations at 79 weather stations to reveal the streamflow changes and underlying drivers in four typical watersheds (Meigang, Saitang, Gaosha, and Xiashan) within Poyang Lake Basin from 1961 to 2000. Most of the less than 90th percentile of daily streamflow in each watershed increases significantly at different rates. As an important indicator of the seasonal changes in the streamflow, CT (the timing of the mass center of the streamflow) in each watershed shows a negligible change. The annual streamflow in each watershed increases at different rates, with a statistically significant trend (at the 5 % level) of 9.87 and 7.72 mm year^?1, respectively, in Meigang and Gaosha watersheds. Given the existence of interactions between precipitation and PE, the original climate elasticity of streamflow can not reflect the relationship of streamflow with precipitation and PE effectively. We modify this method and find the modified climate elasticity to be more accurate and reasonable using the correlation analysis. The analyses from the modified climate elasticity in the four watersheds show that a 10 % increase (decrease) in precipitation will increase (decrease) the annual streamflow by 14.1–16.3 %, while a 10 % increase (decrease) in PE will decrease (increase) the annual streamflow by ?10.2 to ?2.1 %. In addition, the modified climate elasticity is applied to estimate the contribution of annual precipitation and PE to the increasing annual streamflow in each watershed over the past 40 years. Our result suggests that the percentage attribution of the increasing precipitation is more than 59 % and the decreasing in PE is less than 41 %, indicating that the increasing precipitation is the major driving factor for the annual streamflow increase for each watershed.     

一次冷涡过程降水的微物理机制分析

该文分析了一次冷涡天气过程中云微物理量的分布特征、降水粒子的增长机制及云下雨滴的蒸发效应。主要结果为：云系由低层暖性Sc云和冷性主体As云组成。As云底高2 km,云顶高大于5 km,云中存在比较大的过冷水区,–11.2 ℃时的过冷水含量0.21 g·m-3,但过冷水的含量分布极不均匀,大于0.05 g·m-3的过冷水区连续分布的宽度87%小于2.4 km,不利于云中冰晶的连续凇附增长;同时云下雨滴的蒸发效应大,直径小于1.0 mm的雨滴难以落到地面,因此本次过程只产生弱的降水。     

三峡库区经济发展评价

当前三峡库区经济发展存在主要产业经济效益低，国有产业亏损大，产业规模小，城镇经济中心作用弱等突出问题．库区开发必需是持久战和持续发展相结合，将库区基础设施建设放在重要地位，搞好资金、行业、所有制之间的优化组合，大力发展第三产业；要准备用几十年的艰苦奋斗，才能赶上全国平均水平．     

Precursor times of abnormal <Emphasis Type="Italic">b</Emphasis>-values prior to mainshocks

Seismic observations exhibit the presence of abnormal b-values prior to numerous earthquakes. The time interval from the appearance of abnormal b-values to the occurrence of mainshock is called the precursor time. There are two kinds of precursor times in use: the first one denoted by T is the time interval from the moment when the b-value starts to increase from the normal one to the abnormal one to the occurrence time of the forthcoming mainshock, and the second one denoted by T _p is the time interval from the moment when the abnormal b-value reaches the peak one to the occurrence time of the forthcoming mainshock. Let T* be the waiting time from the moment when the abnormal b-value returned to the normal one to the occurrence time of the forthcoming mainshock. The precursor time, T (usually in days), has been found to be related to the magnitude, M, of the mainshock expected in a linear form as log(T)?=?q?+?rM where q and r are the coefficient and slope, respectively. In this study, the values of T, T _p , and T* of 45 earthquakes with 3?≤?M?≤?9 occurred in various tectonic regions are compiled from or measured from the temporal variations in b-values given in numerous source materials. The relationships of T and T _p , respectively, versus M are inferred from compiled data. The difference between the values of T and T _p decreases with increasing M. In addition, the plots of T*/T versus M, T* versus T, and T* versus T-T* will be made and related equations between two quantities will be inferred from given data.     

The influence of horizontally non-uniform heating upon the development of strong convective mesoscale disturbances

It is shown by observational data and synoptic analysis that the development of strong convective echo is influenced by the horizontally non-uniform heating, such as the one caused by lake-land distribution. In this paper, a simple linear cell-convection model is established using an appropriate heating field, and the instability of heating convection is theoretically studied. It is found that the heating convection development will be unstable if the heating-caused temperature gradientdT ₀/dy is greater than the critical value (dT ₀/dy) _c which is approximately 0.64°C/10 km, and that the development of convective band has a preferred width of 12.5 km. It will take 25 min for the initial disturbance to increase intensity by 10 times. All these results are in rather good agreement with the squall line process in the lake-land region of Jiangsu Province on June 8, 1979.