The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields. 相似文献
We find that five sources listed in the new carbon star catalog are not really carbon-rich objects but oxygen-rich stars, because they all have the prominent 10μm silicate features in absorption and the 1612MHz OH maser emission or/and the SiO molecular features. These objects were considered as carbon stars in the catalog based only on their locations in the infrared two-color diagram. Therefore to use the infrared two-color diagram to distinguish carbon-rich stars from oxygenrich stars must be done with caution, because, in general, it has only a statistical meaning. 相似文献
Along with the consumption increase of the petroleum products,more countries have transferred their attentions to the offshore fields,especially the deepwater oil and gas reserves.For deepwater exploitation,the risers must be installed to act as the conduits connecting surface platforms to subsea facilities.In this paper,the typical risers sorted by different classes are introduced,and the correspondent installation methods are presented.By investigating the recent projects performed in the deepwater hot spots,and combining the challenges of HYSY201 for riser installation,a lifting device developed for assisting riser installation is proposed and detailed to satisfy the installation of deepwater risers in the LW3-1 Gas Field of in the South China Sea.Tests on both the functions and performances of such a new system exhibit the satisfaction of meeting all challenging requirements of HYSY201 for application to riser installation in waters up to a depth of in the South China Sea. 相似文献
Many mud volcanoes are distributed along the tectonic sutures in southern Taiwan and can be divided into five zones based on their relative positions in different tectonic domains. Most active mud volcanoes are exhaling methane-dominated gases. Nevertheless, some gases show unusual carbon dioxide-dominated and/or nitrogen-excess compositions. This implies that there are multiple sources for the gas compositions of mud volcanoes in Taiwan.For better understanding the total amount of exhalation gases and its flux, the gas flow and compositions were continuously measured in the interval of two minutes at Chung-lun (CL) bubbling mud pool for a few months. The major compositions of gases exhaling from this site were 75~90% of CO2 and 5~12% of CH4. The amount of gases exhaling from the mud pool can be estimated to be about 1.4 ton/year for CH4 and 28 ton/year for CO2, respectively. The preliminary results of exhaling gas flux from the major vents of representative active mud volcanoes, yielded an estimated total CH4 output of the mud volcanoes in Taiwan of ca. 29 ton/year during quiescent period. 相似文献
Well che89, located in the Chepaizi area in the northwest margin of Junggar basin, acquires high production industrial oil flow, which is an important breakthrough in the exploration of the south foreland slope area of Junggar basin. The Chepaizi area is near two hydrocarbon generation depressions of Sikeshu and Shawan, which have sets of hydrocarbon source rock of Carboniferous to Jurassic as well as Upper Tertiary. Geological and geochemical parameters are proper for the accumulation of mixed source crude oil. Carbon isotope, group composition and biomarkers of crude oil in Upper Tertiary of well Che89 show that the features of crude oil in Upper Tertiary Shawan Formation are between that of Permian and Jurassic, some of them are similar to these two, and some are of difference, they should be the mixed source of Permian and Jurassic. Geochemical analysis and geological study show that sand extract of Lower Tertiary Wulunguhe Formation has the same source as the crude oil and sand extract of Upper Tertiary Shawan Formation, but they are not charged in the same period. Oil/gas of Wulunguhe Formation is charged before Upper Tertiary sedimentation, and suffered serious biodegradation and oxidation and rinsing, which provide a proof in another aspect that the crude oil of Upper Tertiary Shawan Formation of well Che89 is not from hydrocarbon source rock of Lower Tertiary.