页岩中气体的超临界等温吸附研究

页岩气等温吸附实验多为临界温度以上的吸附实验,其得到的吸附量为过剩吸附量。为了研究页岩气超临界等温吸附机理,运用重力法,在临界温度以上,分别进行了甲烷和二氧化碳在页岩中的高压等温吸附实验。在分析经典型吸附和超临界吸附区别的基础上,通过修改的超临界等温吸附模型(Langmuir方程和微孔充填(Dubinin Radushkevich,D-R))对实验数据进行了拟合。结果表明:简单的Langmuir方程可近似拟合甲烷吸附实验数据,但精度不高,且无法拟合二氧化碳的吸附数据;将吸附相密度作为可优化参数,修改的微孔充填模型和Langmuir模型能很好地拟合甲烷和二氧化碳的吸附数据,其中修改的微孔充填模型拟合效果最好,且回归得到的超临界甲烷吸附相密度同文献报道的一致,表明吸附气可能以微孔充填的形式存在。     

准噶尔盆地沙湾凹陷二叠系凝析气藏相态识别及成因分析

近年来,我国中西部陆续发现了资源量较大的凝析气藏,准噶尔盆地沙湾凹陷周缘的多个凝析气藏也显示出深层勘探的潜力。针对沙湾凹陷凝析气藏的烃类流体特征和形成机制不清晰的科学问题,笔者等采用原油物性和地球化学分析测试,运用经验统计法来识别油气藏类型,分析油气相态特征及其来源。主要认识如下：① 沙湾凹陷二叠系主要存在带油环凝析气藏,中佳2- H井为典型带油环凝析气藏井,研究区存在风城组为烃源—断层垂向输导—温压控制的原生型和天然气气侵共同作用形成的次生型凝析气藏;② 结合P—V—T相图分析沙湾凹陷二叠系凝析气藏烃类流体C7+占比较小,挥发性油藏地层温度明显低于临界温度,地饱压差较小,黑油油藏地层流体的临界温度与临界凝析温度都较高且临界压力较小;③ 根据新光井区凝析气藏的气油比要高于13000 m3/m3,且新光1井凝析气藏属于无油环凝析气藏可判断新光1井为原生型凝析气藏;中佳2- H井凝析气藏正构烷烃损失率达到90%,且研究区存在混合来源气,证实该凝析气藏曾遭受气侵作用。笔者等提出的凝析气成因可为研究区下一步油气勘探提供参考,同时也可以为准噶尔盆地凝析气成藏的研究和资源评价提供方法支持。     

华北山地多成因壶穴初步研究——对华北山地“冰臼”等“冰川地貌”的讨论

华北山地"距今二、三百万年"的"冰臼"绝大部分位于第四纪河谷内,"距今1～2万年"的"冰川壶穴"位于全新世河谷内,与华北山地地貌演化相矛盾;所谓的"冰川地貌"组合不是真正的地貌组合,而是不同时代、不同成因地貌的混合,因此,华北山地不存在冰臼。所谓的"冰臼"是不同时代、多种成因的壶穴——距今2.50Ma前后的河蚀壶穴,距今10～20ka的雪蚀壶穴,距今10ka以来的溶蚀穴、溶蚀—河蚀壶穴、风化—风蚀壶穴、现代壶穴和水潭。     

建立地震发射台的建议

目前地球上有成千上万个地震台，但它们都是接收地震波的地震台。建议建立一种新型的地震台，这种地震台用人工的方法不断地向外发射地震波，照亮需要研究地区的地下结构，研究特定的科学问题。建立地震发射台的核心问题是选择合适的人工震源，近年来出现的绿色环保震源，以及现代信息处理技术的发展，使得建立照亮10万km2(深至Moho面)地区地下结构的地震发射台已经完全是可能的。     

http://www.sciencedirect.com/science/article/pii/S1674987111000788

This paper presents numerical investigation on the ore-forming fluid migration driven by tectonic deformation and thermally-induced buoyancy force in the Chanziping ore district in South China. A series of numerical scenarios are considered to examine the effect of meteoric water precipitation, the dip angle of the faults, unconformity surface, and thermal input on the ore genesis. Our computations reveal that the downward basinal fluid flow driven by extensional stress mixes with the upward basal fluid driven by the thermal input from depth at the junction of two faults at a temperature of about 200 C, triggering the precipitation of the Chanziping uranium deposit.     

用地震危险性分析方法预测山东地区震害

依据地震危险性分析的思路，提出一种场地震害预测的方法。依此方法，给出山东地区５０ａ超越概率为１０％的震害预测略图     

Study of red tide prediction model for the Changjiang Estuary

ＩＮＴＲＯＤＵＣＴＩＯＮＡｑｕｉｃｕｌｔｕｒｅａｒｅａｒｅｄｔｉｄｅｓｉｇｎａｌｓｏｃｅａｎｐｏｌｌｕｔｉｏｎａｎｄｄｉｓａｓｔｅｒ.Ａｌｔｈｏｕｇｈｅｎｖｉｒｏｎｍｅｎｔｓｃｉｅｎｔｉｓｔｓｈａｖｅｃｏｎｄｕｃｔｅｄｍａｎｙｉｎ ｄｅｐｔｈｒｅｓｅａｒｃｈｅｓｏｎｔｈｅｃａｕｓｅａｎｄｆｏｒｍａｔｉｏｎｍｅｃｈａｎｉｓｍｏｆｒｅｄｔｉｄｅ ,ｍａｎｙｏｆｉｔｓａｓｐｅｃｔｓａｒｅｓｔｉｌｌｕｎｋｎｏｗｎｂｅｃａｕｓｅｒｅｄｔｉｄｅｉｓａｃｏｍｐｌｅｘｐｈｅｎｏｍｅｎｏｎａｎｄｔｈｅｅｃｏｌｏｇｉｃ…     

南极普里兹湾及其邻近海域水团研究

普里兹湾及其邻近海域是中国南大洋调查研究的传统优势海域与重点区域。围绕夏季表层水、冬季水、陆架水、绕极深层水、南极底层水、普里兹湾底层水、冰架水等研究海区主要水团的特征和分布,总结了前人在南极普里兹湾及其邻近海域基于调查资料开展的水团研究中所取得的成果。研究表明,前人在对陆架水的示性指标界定上,将陆架水是否区分为高盐陆架水和低盐陆架水存在较大争议,在高盐陆架水和普里兹湾底层水的定义上存在重叠;目前尚没有证据表明绕极深层水向南可以伸展到普里兹湾的陆架区域,也没有发现在普里兹湾附近海域生成南极底层水的直接证据。     

A bio-optical inversion model to retrieve absorption contributions and phytoplankton size structure from total minus water spectral absorption using genetic algorithm

We propose a bio-optical inversion model that retrieves the absorption contributions of phytoplankton and colored detrital matter(CDM),as well as the phytoplankton size classes(PSCs),from total minus water absorption spectra.The model is based on three-component separation of phytoplankton size structure and a genetic algorithm.The model performance was tested on two independent datasets(the NASA bio-Optical Marine Algorithm Dataset(NOMAD) and the northern South China Sea(NSCS) dataset).The relationships between the estimated and measured values were strongly linear,especially for aCDM(412),and the Root Mean Square Error(RMSE) of the CDM exponential slope(SCDM) was relatively low.Next,the inversion model was directly applied to in-situ total minus water absorption spectra determined by an underwater meter during a cruise in September 2008,to retrieve the phytoplankton size structure in the seawater.By comparing the measured and retrieved chlorophyll a concentrations,we demonstrated that total and size-specific chlorophyll a concentrations could be retrieved by the model with relatively high accuracy.Finally,we applied the bio-optical inversion model to investigate changes in phytoplankton size structure induced by an anti-cyclonic eddy in the NSCS.     

Spheroidal weathering of granite porphyry with well‐developed columnar joints by oxidation,iron precipitation,and rindlet exfoliation

Spheroidal weathering, one of the important rock weathering styles, has been attributed to chemical weathering by the water from joint surfaces, and mechanical aspects of the weathering have not been well addressed. We made an investigation on spheroidal weathering of Miocene granite porphyry with well‐developed columnar joints and found that this spheroidal weathering proceeds through chemical processes and accompanying mechanical processes. The investigation of the textures, physical properties, mineralogy, and chemistry of the porphyry revealed the presence of a brown band on the surface margins of corestones, representing the oxidation of pyrite and chlorite, and the precipitation of iron hydroxides, and the consequent generation of micro‐cracks within the band. During weathering, oxidation progresses inwards from joints that surround the rindlets, including both high‐angle columnar and low‐angle planar joints, and causes rounding of the unweathered interior portion of the rock. Microscopic observations of the brown band embedded with fluorescent resin show that pores are first filled with iron hydroxides, and that micro‐cracks then form parallel to the oxidation front in the outer portion of the brown band. Iron hydroxide precipitation increases the P‐wave velocity in the brown band, while micro‐crack formation decreases the tensile strength of the rock. Where the brown band has thickened to ~6 cm, the micro‐cracks are connected to one another to create continuous cracks, which separate the rindlets from the corestone. Micro‐crack formation parallel to the corestone surface may be attributed to compressive stresses generated by small amounts of volumetric expansion due to the precipitation of iron hydroxides in the brown band. Earth surface is under oxidizing environments so that precipitation of iron hydroxides commonly occurs; the spheroidal weathering in this paper is a typical example of the combination of chemical and mechanical processes under such environments. Copyright © 2016 John Wiley & Sons, Ltd.