钛胶海水提铀动力学研究Ⅱ——吸附机理的推断

海水提铀机理的研究,已逐渐受到重视,然而,至今研究还不是很深入,观点也各有差别.例如,Keen等[1]认为钛胶从海水中吸附铀是阳离子交换过程,即海水中的铀是UO₂2+离子的形式与钛胶进行交换;尾方升等[2]则倾向于阴离子吸着,即铀是以UO₂(CO₃)₃4-的形式被吸附.我们曾于1973年在海洋局系统的一次会议上提出阳离子给合交换的看法,并在后来的两次专业会议上予以补充发展.张正斌[3]认为是阳离子交换或一价阳离子失水络合.最近崔清晨[4]提出可能是UO₂(OH)₃-的络合吸附.根据几年来的工作,我们仍认为,钛胶从海水中的吸铀机理可能是一种阳离子形式的络合交换过程.     

Optimum design of filament-wound multilayer-sandwich submersible pressure hulls

Submersible pressure hulls with fiber-reinforced multilayer-sandwich constructions have been developed in recent years as substitutes for classical metallic ring-stiffened pressure hulls. This study aims to optimize the design of filament-wound multilayer-sandwich submersible pressure hulls, taking into consideration the shell buckling strength constraint, the angle-ply laminated facing failure strength constraint and the low-density isotropic core yielding strength constraint under hydrostatic pressure using the hybrid genetic algorithm (HGA). The thickness of the facing, the thickness of the core layer, the orientation angle of the fibers in the facings and the shear modulus of the core material are taken as design variables. A sensitivity analysis is performed to study the effects of the operational depths and the hull shell geometry parameter, the length-to-diameter ratio (L/D), on the optimal design of filament-wound multilayer-sandwich submersible pressure hulls with graphite/epoxy, glass/epoxy and boron/epoxy composite facings. The results reveal that the optimal weight of various sandwich pressure hulls increases linearly with the operational depth, but it is almost unchanged as the geometry paramter. Furthermore, Graphite/Epoxy is the best choice for the material of the facings in a light-weight design. With reference to wall design, Boron/Epoxy is the best choice for the material of the facing at shallow depths, but Graphite/Epoxy is the best choice at extreme depths. Results of this study provide a valuable reference for designers of underwater vehicles.     

Objective prism survey of qsos in the field centered at 10h40m + 00°00′

QSO objective prism survey was done for the field centered at 10^h40^m + 00°00. For the 348 objects selected, we present in this paper their positions,B _J magnitudes, spectra, and finding charts. Based on the sample containing 163 QSO candidates with higher reliabilities (F 3), the surface density of QSO candidates withB _J 20 is estimated to be about 4.5 per square degree.Work based on UKST plates.     

钾霞石制备体系碱性滤液的利用技术

为处理钾长石水热制备钾霞石所产生的碱性滤液,本文采用水热法,考察了氢氧化铝溶解时间、晶化时间、晶化温度、水碱比对钾霞石产率和白度的影响,并对合成钾霞石物相进行了表征。结果表明,合成钾霞石的最佳条件为,氢氧化铝溶解时间为1.5 h,晶化时间为4 h,晶化温度280℃,水碱比为1.8。XRD结果表明,产物为钾霞石粉体。傅里叶变换红外光谱表明,Al(OH)₃中的Al在水热条件下进入到Si—O骨架中形成了Si—O—Al官能团,从而印证了钾霞石的合成。差热分析结果表明,合成钾霞石具有良好的热稳定性。氮气吸附结果表明,合成钾霞石比表面积为5.18 m²/g,平均孔径为32.98 nm。实现了钾长石水热制备钾霞石所剩碱性滤液的资源化利用,并为钾长石水热制备钾霞石提供了一种母液循环的思路,使水热制备钾霞石工业化成为一种可能。     

随钻测录井地质导向二维分解实时绘图方法

根据随钻测录井实时地质导向和大斜度、水平井评价成图技术需求，针对传统绘图方法存在的弊端，提出了将测录井信息、井眼轨迹和地质模型进行二维分解的实时绘图方法。针对二维分解绘图方法绘图时空复杂度较高的问题，给出了不同事件驱动下的局部实时计算和拷屏重绘算法，控制了对CPU和内存的消耗、提高了绘图效率，消除了实时绘图的闪烁和卡顿现象。应用实例表明，二维分解实时绘图方法能够实现大尺度随钻测录井地质导向图形的流畅、无卡顿实时绘图，可提高大斜度、水平井储层模型评价的刻画精度和时效。     

Improved treatments for evaluating horizontal magnetic components through the 3-D FDM in E -polarization induction problems

To improve the accuracy of the numerical evaluation through the 3-D finite difference method, the surface boundary conditions are added to modify the old program. The author has tested the new program by making calculations for the model constructed by Wanamaker, et al (1984). The comparison between the numerical results obtained from this paper and those by Wannamaker, et al (1984) indicates that a pronounced improvement is realized in the evaluation of the horizontal magnetic components. Moreover, better calculations for the vertical magnetic components are also obtainable by using the new program.     

Soil degradation: a global problem endangering sustainable development

1 Introduction Soil is not only the major natural resource on which human being depends for the production of food, feed, fiber, renewable energy and raw materials, but also plays a key role in maintaining the complex terrestrial ecosystems and climate systems of this planet. Recent rapid increase in the human population is placing a great strain on the worlds soil resources. Only about 11% of the global land surface covered by the soils are being used to raise crops and livestock, in other …     

禾青井动水位对断层蠕动与慢地震过程的响应初析

以湖南禾青井深井水位观测的异常图象为例进行定性分析，发现动水位观测有可能直接反映出断层的滑动或断层的慢地震过程，前者可能为地下水物理参量的观测与研究提供亲折思路，后者则可能对震源物理学的发展和地震预报水平的提高具有特殊的意义。     

甲醛还原Pt/TiO2催化剂用于温和条件下高效催化氧化甲醛（英文）

通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差.