Marine hazards in coastal areas and human action against them—A case study of the Changjiang River estuaries and Qiantang River

China's eastern coastal area marine hazards (storm surge, erosion and deposition by tidal currents and seawater intrusion) and the history, present situation, experiences and problems of inhabitants in their fight against marine hazards are discussed in this paper, which also suggests counter-measures against, and scientific and rational management of, coastal area marine hazards in order to protect the coastal and estuarine ecosystems.     

运用AMMI模型分析水稻区域试验 (I).参试组合的产量稳定性评价

运用 AMMI模型对 1 996年全国籼型杂交稻区域试验中稻两系组资料进行分析 ,结果表明 :组合稳定性评价很重要 ,基因型与环境的互作达极显著水平 ,互作效应 (平方和 )几乎为基因型效应 (平方和 )的 2倍 ,AMMI模型的前三个主成分共解释了 80 .4 1 %的交互作用信息 ,为线性回归模型的 3 .1倍。安湘 S/ 871 3、两优 T63表现出较高产且稳产 ,培矮 64 S/山青 1 1、培矮 64 S/ 2 4 1 0、培矮 63 S/ R3 1 8表现较稳产而不高产 ,两优 79、培矮 64 S/ JR1 0 68既不高产也不稳产。     

青藏高原地面加热场与四川主汛期降水及伏旱关系

分析了高原地面加热场强度距平指数与四川盆地伏旱及主汛期降水的联系。结果表明,高原前期加热强度同四川盆汛期降水和伏旱程度密切相关。把这些关系引入汛期降水预测模型对提高短期气候预测能力有一定积极意义。     

自动建模客观分型方法在非汛期人工增雨中的应用

根据安徽省人工影响天气业务系统需要,利用NCEP 500 hPa高度场和风场格点资料及安徽省81站10年非汛期逐日降水资料,在客观分析天气形势基础上,结合预报员实践经验给出的不同系统影响安徽省时的关键区,计算机自动建模,形成逐日天气型日历,实现环流分型客观化。此方法识别条件实用,模型物理意义明确,自动化程度高,自动生成的逐日天气型日历,为安徽省非汛期人工增雨作业指挥系统提供了很好的天气预报参考依据。     

利用催化动力学原理测定化探样中微量碘的含量

在HAc-NaAc形成的中性缓冲溶液体系中,利用碘的催化动力学原理,使N-N-四甲基-4-4-二氨基二苯甲烷与氯胺T的氧化反应,生成蓝色络合物来测定地探样中微量碘的含量。通过实验,最佳试剂加入量为8%的HAc溶液5mL,8%的Na2CO3溶液3mL,0.1%的N-N-四甲基-4-4-二氨基二苯甲烷溶液5mL所组成的溶液体系中,在加入0.1%的氯胺T1mL显色后,其测定结果准确度、精密度高,检出限低,测定化探样中微量碘时该方法可以推广应用。     

Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).     

Effect of nano-hematite morphology on photocatalytic activity

Nano-hematites, i.e., hematites with nanoparticle-, nanorod-, and nanotube-like morphologies, were synthesized via the hydrothermal method by controlling the reaction time, temperature, and reactant concentration. The nano-hematites of different crystal shapes all exhibited band gaps within the visible-light region (1.56–2.1 eV). Further, they showed weak ferromagnetic behavior, and their coercive magnetic field was larger than that of the bulk hematite. Moreover, all the nano-hematites also exhibited high photocatalytic activities during the degradation of methylene blue under visible-light irradiation. The experimental data fitted the Langmuir–Hinshelwood kinetics model very well. The nanorods had the highest photocatalytic rate constant per unit surface area, possibly owing to a higher aspect ratios; this lowers the electron–hole recombination rate. These results suggest that the crystal morphology of hematites has a significant effect on their physical and photocatalytic properties. Therefore, controlling the morphology of the materials is essential for obtaining well-tailored photocatalysts.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。     

数字地震观测中由台风产生的震颤信号分析

本文的工作源于我们在以宽频数字地震计和倾斜、重力仪开展对"慢地震"、"前驱波"等信号连续观测和分析的过程中,观测到不少异常的波动信号.在探讨这些异常信号的产生原因的研究中,发现其中一部分由热带气旋(台风)产生.