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91.
92.
Eloïse Gaillou Aurlien Delaunay Benjamin Rondeau Martine Bouhnik-le-Coz Emmanuel Fritsch Guy Cornen Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113
Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si4+ by Al3+ and Fe3+. The induced charge imbalance is compensated chiefly by Ca2+, Mg2+, Mn2+, Ba2+, K+, and Na+. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence. 相似文献
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Emmanuel Jacquet Marine Paulhiac‐Pison Olivier Alard Anton T. Kearsley Matthieu Gounelle 《Meteoritics & planetary science》2013,48(10):1981-1999
We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior (“interior grains”), chondrule surficial shells (“margin grains”), and the matrix (“isolated grains”). Save for a few anomalous grains, Ni‐normalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least‐melted, fine‐grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high‐temperature isolation of refractory platinum‐group‐element (PGE)‐rich condensates before mixing with lower temperature PGE‐depleted condensates. The rounded shape of the Ni‐rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1–100 K h?1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni‐poorer, amoeboid margin grains, often included in the pyroxene‐rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high‐temperature event, of which the chondrule margin records a late “quenching phase,” in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule‐forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated. 相似文献
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本文首先简要介绍了我国地震地下流体观测台网的现状,然后针对其存在的主要问题提出了调整与优化的建议: ① 调整布局,重点加强我国中西部地区(105°E以西)的监测; ② 扩大规模,观测井(泉)数要达到1000个左右; ③ 全面提高观测井质量,淘汰不符合规范要求的观测井(泉),改造不完全符合规范要求的观测井,新建一批完全符合规范的观测井; ④ 优化观测项目的组合,大力发展观测井(泉)水流量观测,强化以H2、 He、 CO2等为主测项的断层带土壤气观测,建立断层带土壤气观测网; ⑤ 优化现有的观测模式,开展平面上的台阵式观测与垂向的多层次立体化观测; ⑥ 完善与提升现有数字化观测技术水平. 相似文献
98.
Concentration of 7 Heavy Metals in Sediments and Mangrove Root Samples from Mai Po, Hong Kong 总被引:7,自引:0,他引:7
R. G. Ong Che 《Marine pollution bulletin》1999,39(1-12):269-279
Concentration of 7 heavy metals, Zn, Fe, Cu, Cr, Cd, Pb and Ni in mudflat sediments, mangrove root sediments and root tissues of Acanthus ilicifolius, Aegicerus corniculatum and Kandelia candel from the Mai Po Nature Reserve, Northwest Hong Kong, were measured. Metal concentrations in the upper 0–10 cm of the sediment cores from the mudflat were 4–25% higher than those found in the bottom 21–30 cm. Relative Topsoil Enrichment Index approximated 1.0 for all the metals. Mudflat sediment concentrations of Fe, Ni, Cr, Cd and Cu were greater than those found in the mangrove sediments. Except for Fe, concentrations of the other 6 heavy metals were more elevated in the mangrove root sediments than in the corresponding root samples. Higher concentration factors for Zn, Fe and Cu may indicate bioaccumulation. Mean metal concentrations in both mudflat and mangrove sediments decreased in the order Fe > Zn > Pb > Ni > Cu > Cr > Cd. Mangrove root tissues also showed the same pattern except that Pb > Cu > Ni 相似文献
99.
Che Yong-tai Yu Jin-zi Zhang Shu-liang Fan Xue-fang Guo Jun-jie Zhang Tian-yuan Yang Jin-lan 《地震学报(英文版)》2002,15(2):226-233
A lot of slow fluctuations of water level have been observed in the original recording maps of subsurface fluid in Well Shuozhou,
Shanxi Province. Some typical recording maps of the “precursors” are introduced in the paper and the features of the “precursors”
recorded by the well are analyzed. The results show that 38% strong earthquakes possess this kind of record, which has a fluctuation
period arranging from several to tens of minutes and appear mostly two days before the earthquakes. Moreover, the mechanism,
transmission and responding conditions of well water level are discussed, as well as the scientific meaning and practical
value of the “precursor” of the well water level in earthquake predictions.
Foundation item: State Natural Science Foundation of China (19973011). 相似文献
100.
Groundwater exploitation is an essential aspect of the numerous processes of transforming the urban natural environment for human gains. We use the political ecology of borehole exploitation in Nigeria’s urban environment to understand the micro-and macro-level processes mediating the transformation and changes in urban “groundwater scape”. The fieldwork processes depend on field counting of borehole distribution, in-depth and semi-structured interviews, and a review of secondary literatures. We argue that the social and environmental changes arising from the exploitation of groundwater bespeak the active and continual manifestation of the interplay of combustible interests and power friction among institutional agents within the permissible range of the natural environment. Such dynamic power relations engender a pattern of socio-natural transformation consistent with Swyngedouw’s notion of urban metabolism- “a series of interconnected heterogeneous and dynamic but contested and contestable processes of continuous quantitative and qualitative transformations that re-arranges humans and non-humans in new and often unexpected ways”. 相似文献