Co-simulated Size Number: An Elegant Novel Algorithm for Identification of Multivariate Geochemical Anomalies

Natural Resources Research - Identification of geochemical anomalies is of particular importance for tracing the footprints of anomalies. This can be implemented by advanced techniques of...     

Trace element geochemistry of CR chondrite metal

We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior (“interior grains”), chondrule surficial shells (“margin grains”), and the matrix (“isolated grains”). Save for a few anomalous grains, Ni‐normalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least‐melted, fine‐grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high‐temperature isolation of refractory platinum‐group‐element (PGE)‐rich condensates before mixing with lower temperature PGE‐depleted condensates. The rounded shape of the Ni‐rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1–100 K h^?1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni‐poorer, amoeboid margin grains, often included in the pyroxene‐rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high‐temperature event, of which the chondrule margin records a late “quenching phase,” in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule‐forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated.     

Turbulent kinetic energy budget in a gravel-bed channel flow

The present experimental investigation focuses on the characteristics of near bed turbulence in a fully rough, uniform open-channel flow over a gravel-type bed. Due to bed topography small scale heterogeneity, the flow is not uniform locally in the near bed region and a double averaging methodology is applied over a length scale much larger than the gravel size. The double-averaged Turbulent Kinetic Energy (TKE) budget derived in the context of the present flow over a gravel bed differs from the TKE budget written for flow over a vegetation canopy. The non-constant shape of the roughness function measured in our gravel bed leads to an additional bed-induced production term which is null for vertical roughness elements, such as simplified vegetation elements. The experimental estimation of the terms of the TKE budget reveals that the maximum turbulent activity takes place away from the reference plane, near the roughness crests. However, within the interface sublayer the work of the bed induced velocity fluctuations against the Reynolds stress is of the same magnitude as the main turbulence production term. Consequently, the characteristics of the TKE budget have similarities with uniform flows over canopies and strongly differ from uniform flows over smooth and transitionally rough flows over sedimentlike beds.     

The Economic Contributions of Agricultural Tourism in Michigan

Family farms have long generated income from agricultural tourism including U‐picks, wagon rides, corn mazes and petting zoos, but contemporary agricultural tourism reflects much greater sophistication in terms of product variety, services, activities, and marketing. In Michigan, farm operators have moved beyond classic products and activities and the traditional consumer base. New sources of revenue derive from classes on beer, cider, mead and wine making, yarn spinning, perfume/soap‐making, farm markets, fishing, educational classes, school tours and hospitality including weddings and on‐farm restaurants. This case study of Michigan agricultural tourism reports results from a systematic survey of 154 agritourism operations conducted throughout the state during summer and fall of 2013 with a focus on the economic benefits of the fast‐changing sector. This study summarizes tax revenues, sales and employment trends for the farm operations participating in the survey but also quantitatively assesses the contribution of agricultural tourism to Michigan's economy through an extrapolation of the sample to estimate state‐wide totals. Results from OLS multivariate regression analysis intended to identify relationships between employment, advertising and scale to gross sales per day are also reported. These analyses show the importance of agricultural tourism to rural and peri‐urban places in Michigan and throughout the nation, while raising concerns about a growing division between large and small operators and what this growing gap may mean for the future of the sector.     

3D Mineral Prospectivity Mapping with Random Forests: A Case Study of Tongling,Anhui, China

Natural Resources Research - In the past few decades, a variety of data-driven predictive modeling techniques has led to a dramatic advancement in mineral prospectivity mapping (MPM). The random...     

Deep-water sediment transport patterns and basin floor topography in early rift basins: Plio-Pleistocene syn-rift of the Corinth Rift,Greece

Our current understanding on sedimentary deep-water environments is mainly built of information obtained from tectonic settings such as passive margins and foreland basins. More observations from extensional settings are particularly needed in order to better constrain the role of active tectonics in controlling sediment pathways, depositional style and stratigraphic stacking patterns. This study focuses on the evolution of a Plio-Pleistocene deep-water sedimentary system (Rethi-Dendro Formation) and its relation to structural activity in the Amphithea fault block in the Corinth Rift, Greece. The Corinth Rift is an active extensional basin in the early stages of rift evolution, providing perfect opportunities for the study of early deep-water syn-rift deposits that are usually eroded from the rift shoulders due to erosion in mature basins like the Red Sea, North Sea and the Atlantic rifted margin. The depocentre is located at the exit of a structurally controlled sediment fairway, approximately 15 km from its main sediment source and 12 km basinwards from the basin margin coastline. Fieldwork, augmented by digital outcrop techniques (LiDAR and photogrammetry) and clast-count compositional analysis allowed identification of 16 stratigraphic units that are grouped into six types of depositional elements: A—mudstone-dominated sheets, B—conglomerate-dominated lobes, C—conglomerate channel belts and sandstone sheets, D—sandstone channel belts, E—sandstone-dominated broad shallow lobes, F—sandstone-dominated sheets with broad shallow channels. The formation represents an axial system sourced by a hinterland-fed Mavro delta, with minor contributions from a transverse system of conglomerate-dominated lobes sourced from intrabasinal highs. The results of clast compositional analysis enable precise attribution for the different sediment sources to the deep-water system and their link to other stratigraphic units in the area. Structures in the Amphithea fault block played a major role in controlling the location and orientation of sedimentary systems by modifying basin-floor gradients due to a combination of hangingwall tilt, displacement of faults internal to the depocentre and folding on top of blind growing faults. Fault activity also promoted large-scale subaqueous landslides and eventual uplift of the whole fault block.     

Mercury speciation in surface and deep waters of the Mediterranean Sea

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.     

Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.     

Internal generation of waves: Delta source function method and source term addition method

In this study, we investigate two internal wave generation methods in numerical modeling of time-dependent equations for water wave propagation, i.e., delta source function method and source term addition method, the latter of which has been called the line source method in literatures. We derive delta source functions for the Boussinesq-type equations and extended mild-slope equations. By applying the fractional step splitting method, we show that the delta source function method is equivalent to the source term addition method employing the energy velocity. This suggests that the energy velocity should be used rather than the phase velocity for the transport of incident wave energy in the source term addition method. Finally, the performance of the delta source function method is verified by accurately generating nonlinear cnoidal waves as well as linear waves for horizontally one-dimensional cases.