The impact of African aridity on the isotopic signature of Atlantic deep waters across the Middle Pleistocene Transition

A high resolution analysis of benthic foraminifera as well as of aeolian terrigenous proxies extracted from a 37 m-long marine core located off the Mauritanian margin spanning the last ~ 1.2 Ma, documents the possible link between major continental environmental changes with a shift in the isotopic signature of deep waters around 1.0–0.9 Ma, within the so-called Mid-Pleistocene Transition (MPT) time period. The increase in the oxygen isotopic composition of deep waters, as seen through the benthic foraminifera δ¹⁸O values, is consistent with the growth of larger ice sheets known to have occurred during this transition. Deep-water mass δ¹³C changes, also estimated from benthic foraminifera, show a strong depletion for the same time interval. This drastic change in δ¹³C values is concomitant with a worldwide 0.3‰ decrease observed in the major deep oceanic waters for the MPT time period. The phase relationship between aeolian terrigeneous signal increase and this δ¹³C decrease in our record, as well as in other paleorecords, supports the hypothesis of a global aridification amongst others processes to explain the deep-water masses isotopic signature changes during the MPT. In any case, the isotopic shifts imply major changes in the end-member δ¹⁸O and δ¹³C values of deep waters.     

Unreported fishing, hungry people and political turmoil: the recipe for a food security crisis in Madagascar?

Madagascar, the world's fourth largest island, is one of the world's poorest developing countries, and its people depend heavily on marine resources for subsistence and income. Exports of these resources and foreign fishing access agreements are also important, at least from a large-scale economic perspective. In recent years, concerns have been voiced amongst local fishers and industry groups regarding the growth of the country's fishing effort. Despite these concerns, existing knowledge of the scale, composition and trends of Malagasy fisheries remains poor, and there is negligible information regarding unreported catches and illegal fishing in Madagascar's waters. Small-scale fisheries, which are often substantial in developing countries such as Madagascar, are often unreported or underestimated. Unfortunately, fisheries legislations, management plans and foreign fishing access agreements are often influenced by these incomplete data, leading to serious over-estimations of resource availability. This also appears to be the situation in Madagascar, where the reconstruction of total catches by all Malagasy fisheries sectors conducted here showed that total catches between 1950 and 2008 were twice the volume reported by national fisheries agencies. Most importantly, much of the subsistence sector is missing from official statistics, and signs of decline have already been observed in several stocks, suggesting that current levels of catches are likely to be exceeding sustainable yields. This has profound implications for the economic and ecological sustainability of fisheries, as well as food security in a country where people rely heavily on the ocean for their daily protein needs and livelihoods.     

Physical behaviour of Cretaceous calcareous nannofossil ooze: Insight from flume studies of disaggregated chalk

Geomorphic features such as drifts, sediment waves and channels have been documented in the Upper Cretaceous of north‐west Europe. These features are interpreted to result from bottom currents and have been used to refine chalk depositional models and quantify palaeocirculation patterns. Chalk was first deposited as calcareous nannofossil ooze and geomorphic features are the result of sediment reworking after deposition. There is limited knowledge on the processes that govern nannofossil ooze mobility, thus forcing uncertainty onto numerical models based on sedimentological observations. This article provides an extensive view of the erosional and depositional behaviour of calcareous nannofossil ooze based on experimental work using annular flumes. A fundamental observation of this study is the significant decrease of nannofossil ooze mobility with decreasing bed porosity. Erosion characteristics, labelled as erosion types, vary with total bed porosity (φ) and applied shear stress (τ₀). High‐porosity ooze (φ >80%) is characterized by constant erosion rates (E_m). At φ <77%, however, erosion characteristics showed greater variance. Surface erosion was typically followed by transitional erosion (with asymptotically decreasing E_m), and stages of erosion with constant, and exponential erosion rates. The estimated erosion thresholds (τ_c) vary from ca 0·05 to 0·08 Pa for the onset of surface erosion and up to ca 0·19 Pa for the onset of constant erosion (φ of 60 to 85%). Variability of deposition thresholds (τ_cd) from ca 0·04 to 0·13 Pa reflects the influence of variable suspended sediment concentration and τ₀ on settling particle size due to the identified potential for chalk ooze aggregation and flocculation. Additionally, deposition thresholds seem to be affected by the size of eroded aggregates whose size correlates with bed porosity. Lastly, slow sediment transport without resuspension occurred in high‐porosity ooze as surface creep, forming low‐relief sedimentary features resembling ripples. This process represents a previously undescribed mode of fine‐grained nannofossil ooze transport.     

Sand transport measurements in Chioggia inlet,Venice lagoon: Theory versus observations

This paper presents results of recent measurements of sand transport made in Chioggia inlet as part of an extensive monitoring programme in the Venetian inlets. Measurements were made in order: (1) to define a relationship between sand transport magnitude and tidal flow; (2) to derive the thresholds for sand transport; (3) to identify the dominant modes of transport; (4) to evaluate the concentration profiles of sand within the benthic boundary layer; (5) to compare bedload transport observations with model predictions using existent bedload formulae; and (6) to produce yearly estimates of bedload transport across the inlet. The vertical distribution of sand in the water column was sampled using modified Helley–Smith bedload samplers at three sites. Transport was found to vary according to the flow and bed grain size, with considerable temporal and spatial variability. A difference of up to three orders of magnitude in transport was observed through the inlet, with higher transport rates measured on the seaward part. The dominant mode of transport in the central inlet was suspension, while bedload was dominant in the mouths. The measured profiles of sand concentration varied with the tidal stage and seabed grain size according to the Rouse parameter (R). R was high at the inlet mouths (1<R<2), indicative of a well-developed bedload layer. The inverse movability number (W_s/U_*) was also higher at these sites and appeared to be grain size dependant. Formulae for bedload transport were tested against field data; stochastic methods such as Einstein–Brown, Engelund–Hansen and Van Rijn produce the best fits. The coupled model SHYFEM-Sedtrans05 appears to simulate well observed transport for most conditions of flow. Long-term bedload predictions indicate a dominant export of sand, with a yearly average of 4500 m³.     

Iterative tomographic analysis based on automatic refined picking

The ever-growing size of data sets for active and passive seismic imaging makes the availability of automatic procedures for rapid analysis more and more valuable. Such procedures are especially important for time-critical applications like emergency decisions or re-orienting of ongoing seismic surveys. In this paper a new, iterative scheme for 3D traveltime tomography is presented. The technique, based on a tool originally developed for earthquake data, uses cross-correlation to examine waveform similarity and to adjust arrival times on seismic sections. A preliminary set of reference arrival times is first corrected by the cross-correlation lag and then used to build an initial 3D tomographic velocity model through a standard inversion code; traveltimes calculated from this model are then taken as new reference arrivals and the process of pick adjustment is repeated. The result is a tomographic image, upgraded and refined at each iteration of the procedure. The test performed on the waveform data set recorded during the 2001 SERAPIS active seismic survey in the gulfs of Naples and Pozzuoli (Southern Italy) shows that the 3D iterative tomography scheme produces a velocity image of the structure of the Campi Flegrei caldera which is consistent with the results from previous studies, employing just a fraction of the time needed by a human analyst to identify first breaks. We believe that this technique can be effectively employed for rapid analysis of large data-sets within time-critical or time-dependent tasks and for automatic 4D tomographic investigations.     

Summary findings of the fourth international radiocarbon intercomparison (FIRI)(1998–2001)

Interlaboratory comparisons have been widely used in applied radiocarbon science. These are an important part of ongoing quality assurance (QA) programmes, which are vital to the appropriate interpretation of the evidence provided by the ¹⁴C record in Quaternary applications (including climate change and environmental reconstruction). International comparisons of laboratory performance are an essential component of the quality assurance process in radiocarbon dating. If the user community is to have confidence in radiocarbon results, it needs to be assured that laboratories world wide are producing measurements that are reliable and in accordance with ‘good practice’. The findings from the most recent (completed in 2001) and extensive (more than 90 participating laboratories) radiocarbon intercomparison (FIRI) are reported here. This study was designed (i) to assess comparability, or otherwise, of the results from different laboratories and (ii) to quantify the extent and possible causes of any interlaboratory variation. The results demonstrate that there are no significant differences amongst the main measurement techniques (gas proportional counting, liquid scintillation counting and accelerator mass spectrometry (AMS)) but there is evidence of small laboratory offsets relative to known age samples for some laboratories. There is also evidence in some cases of underestimation of measurement precision. Approximately 10% of all results were classified as extreme (outliers) and these results were generated by 14% of the laboratories. Overall, the evidence supports the fact that radiocarbon laboratories are generally accurate and precise but that, notwithstanding internal QA procedures, some problems still occur, which can best be detected by participation in independent intercomparisons such as FIRI, where the results allow individual laboratories to assess their performance and to take remedial measures where necessary. The results from FIRI are significant in that they show a broad measure of agreement between measurements made in different laboratories on a wide range of materials and they also demonstrate no statistically significant difference between measurements made by radiometric or AMS techniques. Copyright © 2002 John Wiley & Sons, Ltd.     

Regional Fluxes Of Momentum And Sensible Heat Over A Sub-Arctic Landscape During Late Winter

Based on measurements at Sodankylä Meteorological Observatory the regional (aggregated) momentum and sensible heat fluxes are estimated for two days over a site in Finnish Lapland during late winter. The forest covers 49% of the area. The study shows that the forest dominates and controls the regional fluxes of momentum and sensible heat in different ways. The regional momentum flux is found to be 10–20% smaller than the measured momentum flux over the forest, and the regional sensible heat flux is estimated to be 30–50% of the values measured over a coniferous forest.The regional momentum flux is determined in two ways, both based on blending height theory. One is a parameterised method, the other represents a numerical solution of an aggregation model. The regional sensible heat flux is determined from the theory of mixed-layer growth. At near neutral conditions the regional momentum flux can be determined independently of the regional sensible heat flux. At unstable conditions the two models become coupled.The information that is needed by the parameterised blending height method and by the mixed-layer evolution method in order to derive the regional fluxes of momentum and sensible heat can be obtained from radiosonde profiles of wind speed and temperature.     

Current and future atmospheric circulation at 500 hPa over Greenland simulated by the CMIP3 and CMIP5 global models

The Greenland ice sheet is projected to be strongly affected by global warming. These projections are either issued from downscaling methods (such as Regional Climate Models) or they come directly from General Circulation Models (GCMs). In this context, it is necessary to evaluate the accuracy of the daily atmospheric circulation simulated by the GCMs, since it is used as forcing for downscaling methods. Thus, we use an automatic circulation type classification based on two indices (Euclidean distance and Spearman rank correlation using the daily 500 hPa geopotential height) to evaluate the ability of the GCMs from both CMIP3 and CMIP5 databases to simulate the main circulation types over Greenland during summer. For each circulation type, the GCMs are compared to three reanalysis datasets on the basis of their frequency and persistence differences. For the current climate (1961–1990), we show that most of the GCMs do not reproduce the expected frequency and the persistence of the circulation types and that they simulate poorly the observed daily variability of the general circulation. Only a few GCMs can be used as reliable forcings for downscaling methods over Greenland. Finally, when applying the same approach to the future projections of the GCMs, no significant change in the atmospheric circulation over Greenland is detected, besides a generalised increase of the geopotential height due to a uniform warming of the atmosphere.     

Magnetic resonance sounding applied to aquifer characterization

Magnetic resonance sounding (MRS) is distinguished from other geophysical tools used for ground water investigation by the fact that it measures a magnetic resonance signal generated directly from subsurface water molecules. An alternating current pulse energizes a wire loop on the ground surface and the MRS signal is generated; subsurface water is indicated, with a high degree of reliability, by nonzero amplitude readings. Measurements with varied pulse magnitudes then reveal the depth and thickness of water saturated layers. The hydraulic conductivity of aquifers can also be estimated using boreholes for calibration. MRS can be used for both predicting the yield of water supply wells and for interpolation between boreholes, thereby reducing the number of holes required for hydrogeological modeling. An example of the practical application of MRS combined with two-dimensional electrical imaging, in the Kerbernez and Kerien catchments area of France, demonstrates the efficiency of the technique.     

Chalcophile element geochemistry of the Boggy Plain zoned pluton, southeastern Australia: a S-saturated barren compositionally diverse magmatic system

The behavior of the platinum group elements (PGE) and Re in felsic magmas is poorly understood due to scarcity of data. We report the concentrations of Ni, Cu, Re, and PGE in the compositionally diverse Boggy Plain zoned pluton (BPZP), which shows a variation of rock type from gabbro through granodiorite and granite to aplite with a SiO₂ range from 52 to 74 wt %. In addition, major silicate and oxide minerals were analyzed for Ni, Cu, and Re, and a systematic sulfide study was carried out to investigate the role of silicate, oxide, and sulfide minerals on chalcophile element geochemistry of the BPZP. Mass balance calculation shows that the whole rock Cu budget hosted by silicate and oxide minerals is <13 wt % and that Cu is dominantly located in sulfide phases, whereas most of the whole rock Ni budget (>70 wt %) is held in major silicate and oxide minerals. Rhenium is dominantly hosted by magnetite and ilmenite. Ovoid-shaped sulfide blebs occur at the boundary between pyroxene phenocrysts and neighboring interstitial phases or within interstitial minerals in the gabbro and the granodiorite. The blebs are composed of pyrrhotite, pyrite, chalcopyrite, and S-bearing Fe-oxide, which contain total trace metals (Co, Ni, Cu, Ag, Pb) up to ~16 wt %. The mineral assemblage, occurrence, shape, and composition of the sulfide blebs are a typical of magmatic sulfide. PGE concentrations in the BPZP vary by more than two orders of magnitude from gabbro (2.7–7.8 ppb Pd, 0.025–0.116 ppb Ir) to aplite (0.05 ppb Pd, 0.001 ppb Ir). Nickel, Cu, Re, and PGE concentrations are positively correlated with MgO in all the rock types although there is a clear discontinuity between the granodiorite and the granite in the trends for Ni, Rh, and Ir when plotted against MgO. Cu/Pd values gradually increase from 6,100 to 52,600 as the MgO content decreases. The sulfide petrology and chalcophile element geochemistry of the BPZP show that sulfide saturation occurred in the late gabbroic stage of magma differentiation. Segregation and distribution of these sulfide blebs controlled Cu and PGE variations within the BPZP rocks although the magma of each rock type may have experienced a different magma evolution history in terms of crustal assimilation and crystal fractionation. The sulfide melt locked in the cumulate rocks must have sequestered a significant portion of the chalcophile elements, which restricted the availability of these metals to magmatic-hydrothermal ore fluids. Therefore, we suggest that the roof rocks that overlay the BPZP were not prospective for magmatic-hydrothermal Cu, Au, or Cu–Au deposits.