The onset of the Messinian salinity crisis in the deep Eastern Mediterranean basin

Astronomical tuning of the Messinian pre‐salt succession in the Levant Basin allows for the first time the reconstruction of a detailed chronology of the Messinian salinity crisis (MSC) events in deep setting and their correlation with marginal records that supports the CIESM ( 2008 ) 3‐stage model. Our main conclusions are (1) MSC events were synchronous across marginal and deep basins, (2) MSC onset in deep basins occurred at 5.97 Ma, (3) only foraminifera‐barren, evaporite‐free shales accumulated in deep settings between 5.97 and 5.60 Ma, (4) deep evaporites (anhydrite and halite) deposition started later, at 5.60 Ma and (5) new and published ⁸⁷Sr/⁸⁶Sr data indicate that during all stages, evaporites precipitated from the same water body in all the Mediterranean sub‐basins. The wide synchrony of events and ⁸⁷Sr/⁸⁶Sr homogeneity implies inter‐sub‐basin connection during the whole MSC and is not compatible with large sea‐level fall and desiccation of the Mediterranean.     

Petrography and provenance of Upper Cretaceous – Palaeogene sandstones in the foreland basin system of Central Nepal

Sedimentary deposits of the Cretaceous to Miocene Tansen Group of Lesser Himalayan association in central Nepal record passive-margin sedimentation of the Indian Continent with direct deposition onto eroded Precambrian rocks (Sisne Formation onto Kaligandaki Supergroup rocks), succeeded by the appearance of orogenic detritus as the Indian continent collided with Asia on a N-dipping subduction zone. Rock samples from two field traverses were examined petrographically and through detrital zircon U–Pb dating, one traverse being across the Tansen Group and another across the Higher and Tethyan Himalaya (TH). The Tansen Group depositional ages are well known through fossil assemblages. We examined samples from three units of the Tansen Group (Amile, Bhainskati, and Dumri Formations). The Sedimentary petrographic data and Qt F L and Qm F Lt plots indicate their ‘Quartzose recycled’ nature and classify Tansen sedimentary rocks as ‘recycled orogenic’, suggesting Indian cratonic and Lower Lesser Himalayan (LLH) sediments as the likely source of sediments for the Amile Formation (Am), the TH and the Upper Lesser Himalaya (ULH) as the source for the Bhainskati Formation (Bk), and both the Tethyan and Higher Himalaya (HH) as the major sources for the Dumri Formation (Dm). The Cretaceous–Palaeocene pre-collisional Am is dominated by a broad detrital zircon U–Pb ~1830 Ma age peak with neither Palaeozoic nor Neoproterozoic zircons grains, but hosts a significant proportion (23%) of syndepositional Cretaceous zircons (121–105 Ma) would be contributions from the LLH volcanosedimentary arc, Gangdese batholith (including the Xigaze forearc). The other formations of the Tansen Group are more similar to Tethyan units than to Higher Himalaya Crystalline (HHC). From the analysed samples, there is a lack of distinctive evidence or HH detritus in the Tansen basin. Furthermore, the presence of ~23±1 Ma zircons from the HH unit suggests that they could not have been exposed until the earliest Miocene time.     

How many seasonal workers from the Pacific have been employed in New Zealand since the RSE scheme began?

This Research Note provides the first reliable figures on the numbers of seasonal workers from the Pacific Islands who participated in the Recognised Seasonal Employer (RSE) scheme between July 2007 and June 2022. The method for deriving these figures is explained briefly before examining the frequency of return by men and women for employment in subsequent seasons from the nine participating Pacific states. Clarification of the numbers of seasonal workers involved in the scheme, as distinct from work visas issued each year for RSE employment, is timely for two reasons. Firstly, the RSE scheme is under review in March 2023 by Immigration New Zealand. Secondly, the three major sources of Pacific seasonal labour are raising questions in 2023 about the impact of the scheme on their domestic labour markets and economies. Robust data on numbers of Pacific seasonal workers during the scheme's first 15 years contributes important information in both these contexts.     

Strain Associated with the Fault-Parallel Flow Algorithm During Kinematic Fault Displacement

Deformation studies require that geological bodies are kinematically moved along faults. Fault-parallel flow is one of a small number of kinematic restoration algorithms developed for this purpose. This scale-independent method describes how material nodes are displaced parallel to the fault plane, in the direction of fault movement. The one-dimensional strain of linear objects and two-dimensional strain of bodies within the hanging-wall during the restoration is shown for all cutoff angles and all angles of fault bends. A line moving over a fault bend is either shortened or extended depending on its initial orientation. However, the elongation of the line is significantly different under shortening and extension, with respect to the fault bend angle. The geometries of compressional fault systems, in which faults change angle by about 20 to 40°, generate low values of elongation. Modeling of extensional faults, which typically have steeper dips (60 to 80°) and therefore have tighter fault bends, causes high, unnatural values of elongation. The calculated strain ellipse ratios are directly proportional to the fault bend angle, corroborating the one-dimensional results. The fault-parallel flow method should be used primarily to kinematically restore and forward-model compressional faults, and other faults where the fault bend angles do not exceed 40°.     

Determination of Selenium Concentrations in NIST SRM 610, 612, 614 and Geological Glass Reference Materials Using the Electron Probe, LA-ICP-MS and SHRIMP II

A combination of EMPA, sensitive high resolution ion microprobe (SHRIMP II) and/or LA-ICP-MS techniques was used to measure the concentration of selenium (Se) in NIST SRM 610, 612, 614 and a range of reference materials. Our new compiled value for the concentration of Se in NIST SRM 610 is 112 ± 2 μg g⁻¹. The concentration of Se in NIST SRM 612, using NIST SRM 610 for calibration, determined using LA-ICP-MS (confirmed using SHRIMP II) was 15.2 ± 0.2 μg g⁻¹. The concentration of Se in NIST SRM 614, using LA-ICP-MS was 0.394 ± 0.012 μg g⁻¹. LA-ICP-MS determination of Se in synthetic geological glasses BCR-2G, BIR-1G, TB-1G and the MPI-DING glasses showed a range in concentrations from 0.062 to 0.168 μg g⁻¹. Selenium in the natural glass, VG2, was 0.204 ± 0.028 μg g⁻¹.     

Weathering, dust, and biocycling effects on soil silicon isotope ratios

Silicon isotope ratios (δ³⁰Si) of bulk mineral materials in soil integrate effects from both silicon sources and processing. Here we report δ³⁰Si values from a climate gradient of Hawaiian soils developed on 170 ka basalt and relate them to patterns of soil chemistry and mineralogy. The results demonstrate informative relationships between the mass fraction of soil Si depletion and δ³⁰Si. In upper (<1 m deep) soil horizons along the climate gradient, Si depletion correlates with decreases of residual δ³⁰Si values in low rainfall soils and increases in high rainfall soils. Strong positive correlation between soil δ³⁰Si and dust-derived quartz and mica content show that both trends are largely controlled by the abundance of these weathering-resistant minerals. The data also lend support to the idea that fractionation of Si isotopes in secondary phases is controlled by partitioning of silicon between dissolved and precipitated products during the initial weathering of primary basalt. Secondary mineral δ³⁰Si values from lower (>1 m deep) soil horizons generally correlate with the isotope fractionation predicted by a study of dissolved Si in basalt-watershed rivers and driven by preferential ²⁸Si removal from the dissolved phase during precipitation. In contrast, after correcting for the influence of dust, secondary mineral Si depletion and δ³⁰Si values in shallow (<1 m deep) soil horizons showed evidence of biocycling induced Si redistribution and substantially lower δ³⁰Si values than predicted. Low δ³⁰Si values in shallow soil horizons compared to predictions can be attributed to repeated fractionation as secondary minerals undergo additional cycles of dissolution and precipitation. Primary mineral weathering, secondary mineral weathering, dust accumulation, and biocycling are major processes in terrestrial Si cycling and these results demonstrate that each can be traced by δ³⁰Si values interpreted in conjunction with mineralogy and measures of Si depletion.     

The role of geoarchaeology in the interpretation of fragmented buildings and occupation surfaces: The case of coastal settlements in northeast Scotland

Around the world, poorly preserved buildings and occupation deposits often represent the primary evidence for archaeological structures and settlements. Integrated geoarchaeological methods, such as soil chemistry and micromorphology, can be used to maximise the information obtained from such deposits regarding site preservation and the use of space. However, archaeologists are often reluctant to apply these methods if they suspect that preservation is poor or stratigraphy is not visible in the field. To assess the role that geoarchaeology can play in the interpretation of fragmented and poorly preserved structures, this paper presents the results of two case studies in which multiple geoarchaeological methods (microrefuse analysis, pH, electrical conductivity, magnetic susceptibility, loss-on-ignition, portable XRF and micromorphology) were applied to poorly preserved occupation deposits and fragmented buildings in early medieval coastal settlements in northeast Scotland. Micromorphology proved to be fundamental for recognising and understanding the composition of occupation deposits that had formerly been floor surfaces. It also aided interpretations for the use of space and maintenance practices and improved an understanding of the post-depositional processes that had affected stratigraphic visibility at the macroscale. When subjected to principal component analysis, the geochemical, magnetic and microrefuse data were able to provide new details about activity areas, and successfully identified and filtered out the effects of post-medieval contamination. Most significantly, the integrated approach demonstrates that fragmented buildings and poorly preserved occupation surfaces can retain surviving characteristics of the use of space, even if the floor surfaces were not preserved well enough to be clearly defined in the field or in thin section.