Performance of the In Situ Microcosm Technique for Measuring the Degradation of Organic Chemicals in Aquifers

An in situ microcosm (ISM) consists of a stainless steel cylinder isolating about 2 L of the aquifer and is equipped with valves allowing for loading and sampling from the ground surface. During the last five years, this technique has been used frequently to study the degradation of organic chemicals in polluted and pristine aquifers representing different redox environments. The ISM technique has great potential for providing field-relevant degradation potentials and rate constants, but care must be taken in using the equipment and interpreting the results. This paper provides details concerning the installation and operation of an ISM and presents experiences concerning data interpretation and monitoring of redox conditions.     

The influence of trench migration on slab penetration into the lower mantle

A two-dimensional numerical convection model in cartesian geometry is used to study the influence of trench migration on the ability of subducted slabs to penetrate an endothermic phase boundary at 660 km depth. The transient subduction history of an oceanic plate is modelled by imposing plate and trench motion at the surface. The viscosity depends on temperature and depth. A variety of styles of slab behaviour is found, depending predominantly on the trench velocity. When trench retreat is faster than 2–4 cm/a, the descending slab flattens above the phase boundary. At slower rates it penetrates straight into the lower mantle, although flattening in the transition zone may occur later, leading to a complex slab morphology. The slab can buckle, independent of whether it penetrates or not, especially when there is a localised increase in viscosity at the phase boundary. Flattened slabs are only temporarily arrested in the transition zone and sink ultimately into the lower mantle. The results offer a framework for understanding the variety in slab geometry revealed by seismic tomography.     

Dunes of the Gran Desierto Sand-Sea,Sonora, Mexico

The Gran Desierto Sand-Sea contains dunes of crescentic and star form in simple, compound, and complex varieties. The dunes have developed in bimodal to complex wind regimes of intermediate energy. Transitions from simple through compound to complex crescentic dunes are associated with regional changes in wind regimes. Growth of large star dunes takes place by merging of smaller crescentic and reversing dunes from southerly directions and reworking of sand by northerly and westerly winds. Although wind regimes appear to be the major control of dune morphology in this sand-sea, there is a close correlation between the spacing of simple crescentic dunes and the grain size of the coarse 20th percentile.     

Heat transport by variable viscosity convection and implications for the Earth's thermal evolution

The case is presented that the efficiency of variable viscosity convection in the Earth's mantle to remove heat may depend only very weakly on the internal viscosity or temperature. An extensive numerical study of the heat transport by 2-D steady state convection with free boundaries and temperature dependent viscosity was carried out. The range of Rayleigh numbers (Ra) is 10⁴?10⁷ and the viscosity contrast goes up to 250000. Although an absolute or relative maximum of the Nusselt number (Nu) is obtained at long wavelength in a certain parameter range, at sufficiently high Rayleigh number optimal heat transport is achieved by an aspect ratio close to or below one. The results for convection in a square box are presented in several ways. With the viscosity ratio fixed and the Rayleigh number defined with the viscosity at the mean of top and bottom temperature the increase of Nu with Ra is characterized by a logarithmic gradient β = ?ln(Nu)/? ln(Ra) in the range of 0.23–0.36, similar to constant viscosity convection. More appropriate for a cooling planetary body is a parameterization where the Rayleigh number is defined with the viscosity at the actual average temperature and the surface viscosity is fixed rather than the viscosity ratio. Now the logarithmic gradient β falls below 0.10 when the viscosity ratio exceeds 250, and the velocity of the surface layer becomes almost independent of Ra. In an end-member model for the Earth's thermal evolution it is assumed that the Nusselt number becomes virtually constant at high Rayleigh number. In the context of whole mantle convection this would imply that the present thermal state is still affected by the initial temperature, that only 25–50% of the present-day heat loss is balanced by radiogenic heat production, and the plate velocities were about the same during most of the Earth's history.     

The Fuelwood Crisis in Southern Africa — Relating Fuelwood Use to Livelihoods in a Rural Village

The aim of the paper is to examine wood as a source of fuel energy in rural South Africa and factors influencing its usage. The analysis is based on household profiles and characteristics (e.g., gender, caste, population and income) in a livelihood framework. Fuelwood consumption was estimated to be 692 kg/capita, and 4343 kg/user household per annum, valued at $311 per household. Consumption was modelled in relation to informal and formal cash incomes, and population of children, female and male adults. However, only the population of female adults could significantly influence consumption of fuelwood. This implied that where there were more women in a household, consumption was likely to be high. This might be due to the majority of women doing the cooking and heating in the household. Any change in the value of cash income of households had no significant impacts on fuelwood consumed. Cash incomes might therefore not be strong determinants of the types of energy used by rural households. The average quantity of wood consumed for fuel energy in summer was not significantly different from consumption in winter. Some households perpetually used more wood than others. The study further showed that harvesting of wood for fuel energy is not opportunistic, but requires reallocation of time for other livelihood activities in times of shortage. The fuelwood crisis is not simple and not only about shortage of fuelwood and/or population growth but linked to household profiles and other livelihood strategies and subsequently vulnerability of households. These would require thorough investigation and understanding in relation to precise demand and supply data for fuelwood before the fuelwood problem can be sufficiently managed. This revised version was published online in August 2006 with corrections to the Cover Date.     

Secular variation in numerical geodynamo models with lateral variations of boundary heat flow

We study magnetic field variations in numerical models of the geodynamo, with convection driven by nonuniform heat flow imposed at the outer boundary. We concentrate on cases with a boundary heat flow pattern derived from seismic anomalies in the lower mantle. At a Rayleigh number of about 100 times critical with respect to the onset of convection, the magnetic field is dominated by the axial dipole component and has a similar spectral distribution as Earth’s historical magnetic field on the core-mantle boundary (CMB). The time scales of variation of the low-order Gauss coefficients in the model agree within a factor of two with observed values. We have determined the averaging time interval needed to delineate deviations from the axial dipole field caused by the boundary heterogeneity. An average over 2000 years (the archeomagnetic time scale) is barely sufficient to reveal the long-term nondipole field. The model shows reduced scatter in virtual geomagnetic pole positions (VGPs) in the central Pacific, consistent with the weak secular variation observed in the historical field. Longitudinal drift of magnetic field structures is episodic and differs between regions. Westward magnetic drift is most pronounced beneath the Atlantic in our model. Although frozen flux advection by the large-scale flow is generally insufficient to explain the magnetic drift rates, there are some exceptions. In particular, equatorial flux spot pairs produced by expulsion of toroidal magnetic field are rapidly advected westward in localized equatorial jets which we interpret as thermal winds.     

Integrity of Clay Till Aquitards to DNAPL Migration: Assessment Using Current and Emerging Characterization Tools

Field investigations were carried out to determine the occurrence of tetrachloroethene (PCE) dense nonaqueous phase liquid (DNAPL), the source zone architecture and the aquitard integrity at a 30‐ to 50‐year old DNAPL release site. The DNAPL source zone is located in the clay till unit overlying a limestone aquifer. The DNAPL source zone architecture was investigated through a multiple‐lines‐of‐evidence approach using various characterization tools; the most favorable combination of tools for the DNAPL characterization was geophysical investigations, membrane interface probe, core subsampling with quantification of chlorinated solvents, hydrophobic dye test with Sudan IV, and Flexible Liner Underground Technologies (FLUTe) NAPL liners with activated carbon felt (FACT). While the occurrence of DNAPL was best determined by quantification of chlorinated solvents in soil samples supported by the hydrophobic dye tests (Sudan IV and NAPL FLUTe), the conceptual understanding of source zone architecture was greatly assisted by the indirect continuous characterization tools. Although mobile or high residual DNAPL (S _t > 1%) only occurred in 11% of the source zone samples (intact cores), they comprised 86% of the total PCE mass. The dataset, and associated data analysis, supported vertical migration of DNAPL through fractures in the upper part of the clay till, horizontal migration along high permeability features around the redox boundary in the clay till, and to some extent vertical migration through the fractures in the reduced part of the clay till aquitard to the underlying limestone aquifer. The aquitard integrity to DNAPL migration was found to be compromised at a thickness of reduced clay till of less than 2 m.     

Development of the HEFT and NuSTAR focusing telescopes

Hard X-ray/soft gamma-ray astrophysics is on the verge of a major advance with the practical realization of technologies capable of efficiently focusing X-rays above 10 keV. Hard X-ray focusing telescopes can achieve orders of magnitude improvements in sensitivity compared to the instruments based on coded apertures and collimated detectors that have traditionally been employed in this energy band. Compact focal planes enable high-performance detectors with good spectral resolution to be employed in efficient, low-background configurations. We have developed multilayer coated grazing incidence optics and solid state Cadmium Zinc Telluride focal plane systems for the High Energy Focusing Telescope (HEFT) balloon-borne experiment, and for the Nuclear Spectroscopic Telescope Array (NuSTAR) Small Explorer satellite. In this paper we describe the technologies, telescope designs, and performance of both experiments.