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981.
An evaluation of the global variations in the major element chemistry of arc basalts 总被引:2,自引:0,他引:2
Arc volcanoes occur at convergent margins with a wide range in subduction parameters, and variations in these parameters might be expected to lead to variations in the chemistry of magmas parental to arcs. Major element analyses from approximately 100 volcanic centers within 30 arcs, normalized to 6% MgO to minimize the effects of crystal fractionation, display wide variations. Na2O and CaO at 6% MgO (Na6.0 and Ca6.0) correlate remarkably well with the thickness of the overlying crust. These systematics are consistent with two possible models. In the first model, the crust behaves as a chemical filter; where the crust is thick, magmas crystallize at higher pressure and interact more extensively with the arc crust. Modeling of high-pressure crystallization and assimilation, however, does not reproduce the associated variations in Na6.0 and Ca6.0 without calling upon complicated combinations of fractionating phases and assimilants. In the second model, crustal thickness determines the height of the mantle column available for melting beneath arc volcanoes. If melting begins beneath arcs at similar depths, then the column of mantle that undergoes decompression melting is much shorter beneath the thickest arc crust. The shorter mantle column for arcs built on thick crust will lead to smaller extents of melting in the mantle, and hence higher Na6.0 and lower Ca6.0 in the parental magmas. Modeling shows that variations in the extent of melting in the mantle can easily account for the associated variations in Ca6.0 and Na6.0. The abundances of the other major elements at 6% MgO do not correlate well with crustal thickness, or any other subduction parameter. Co-variation of some of these other major elements (e.g., Si6.0 and Fe6.0) within individual arcs suggests that they are strongly influenced by local crustal level processes that obscure partial melting systematics. Correction for the crustal processes improves the relationship between Na6.0 and Ca6.0 that is so readily explained by partial melting. The extents of melting in the mantle beneath arc volcanoes estimated from the ranges in Na6.0 and Ca6.0 are remarkably similar to those estimated beneath mid-ocean ridges. This observation provides further evidence that the mantle wedge, and not the slab, melts beneath arc volcanic fronts. 相似文献
982.
983.
Radon Distribution in Domestic Water of Texas 总被引:1,自引:0,他引:1
Irina Cech Charles Kreitler Howard Prichard Alfonso Holguin Mengistu Lemma 《Ground water》1988,26(5):561-569
984.
985.
Douglas G. Mose Charles Chrosniak Stephen W. Kline George W. Mushrush 《Pure and Applied Geophysics》1990,133(2):213-227
Attempts to predict which geographic areas should be associated with a high percentage of homes with unusually high indoor radon levels in Virginia and Maryland have been based on estimates of soil radon and soil permeability for geological units. This method is found to be less successful and probably less cost-effective than the use of total-gamma aeroradioactivity maps. 相似文献
986.
Arlin J. Krueger Louis S. Walter Charles C. Schnetzler Scott D. Doiron 《Journal of Volcanology and Geothermal Research》1990,41(1-4)
The eruptions of Nevado del Ruiz in 1985 were unusually rich in sulfur dioxide. These eruptions were observed with the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which can quantitatively map volcanic sulfur dioxide plumes on a global scale. A small eruption, originally believed to be of phreatic origin, took place on September 11, 1985. However, substantial amounts of sulfur dioxide from this eruption were detected with TOMS on the following day. The total mass of SO2, approximately 9 ± 3 × 104 metric tons, was deposited in two clouds, one in the upper troposphere, the other possibly at 15 km near the stratosphere.The devastating November 13 eruptions were first observed with TOMS at 1150 EST on November 14. Large amounts of sulfur dioxide were found in an arc extending 1100 km from south of Ruiz northeastward to the Gulf of Venezuela and as an isolated cloud centered at 7°N on the Colombia-Venezuela border. On November 15 the plume extended over 2700 km from the Pacific Ocean off the Colombia coast to Barbados, while the isolated mass was located over the Brazil-Guyana border, approximately 1600 km due east of the volcano. Based on wind data from Panama, most of the sulfur dioxide was located at 10–16 km in the troposphere and a small amount was quite likely deposited in the stratosphere at an altitude above 24 km.The total mass of sulfur dioxide in the eruption clouds was approximately 6.6 ± 1.9 × 105 metric tons on November 14. When combined with quiescent sulfur dioxide emissions during this period, the ratio of sulfur dioxide to erupted magma from Ruiz was an order of magnitude greater than in the 1982 eruption of El Chichon or the 1980 eruption of Mount St. Helens. 相似文献
987.
Youxue Zhang David Walker Charles E. Lesher 《Contributions to Mineralogy and Petrology》1989,102(4):492-513
Crystal dissolution may include three component processes: interface reaction, diffusion and complications due to convection. We report here a theoretical and experimental study of crystal dissolution in silicate melt without convection. A reaction-diffusion equation is developed and numerically solved. The results show that during non-convective crystal dissolution in silicate melt, the interface melt composition reaches a constant or stationary saturation composition in less than a second, hence interface reaction is not the rate-determining step and crystal dissolution in silicate melt is usually diffusion-controlled. Crystal dissolution experiments (designed to suppress convection) show that the concentration profiles of all components propagate into the melt according to the square root of run duration, and that the dissolution distance is also proportional to the square root of run duration. Thus our experiments confirm that the dissolution is diffusion controlled, which is consistent with our numerical calculations. For some principal equilibrium-determining components, concentration profiles conform approximately to the analytical solution of the diffusion equation with a constant effective binary diffusion coefficient. Diffusive dissolution rates (which are inversely proportional to square root of time) can thus be predicted from the phase equilibria and the effective binary diffusion coefficients. To predict steady-state convective dissolution rates, the thickness of the boundary layer must be known. If the convective compositional boundary layer thickness around a dissolving crystal aggregate or near the wall of a magma chamber during convection is about 2 cm or larger, then convective dissolution would rarely result in any significant alteration of original melt. Our dissolution experiments also illustrate the complexity of the diffusion process. Uphill diffusion is common, especially during olivine dissolution into andesitic melt where a majority of the components show the effect of diffusion up their own concentration gradients. Uphill diffusion has implications to the understanding of crystal zoning, and suggests caution is required in applying least squares mass balance analysis to magmatic rocks affected by processes involving diffusion. 相似文献
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989.
990.