Distribution and Trophic Importance of Anthropogenic Nitrogen in Narragansett Bay: An Assessment Using Stable Isotopes

Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary (macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ¹⁵N) and carbon (δ¹³C). The δ¹⁵N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source loading. There is also evidence of a west to east gradient of heavy to light values of δ¹⁵N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ¹⁵N values in macroalgae there reflected preferential uptake of ¹⁴N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of dissolved C species may control the observed δ¹³C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ¹⁵N (13.2 ± 0.54‰ SD) and δ¹³C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ¹⁵N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources.     

Automated Kerogen Classification in Microscope Images of Dispersed Kerogen Preparation

We develop the classification part of a system that analyses transmitted light microscope images of dispersed kerogen preparation. The system automatically extracts kerogen pieces from the image and labels each piece as either inertinite or vitrinite. The image pre-processing analysis consists of background removal, identification of kerogen material, object segmentation, object extraction (individual images of pieces of kerogen) and feature calculation for each object. An expert palynologist was asked to label the objects into categories inertinite and vitrinite, which provided the ground truth for the classification experiment. Ten state-of-the-art classifiers and classifier ensembles were compared: Naïve Bayes, decision tree, nearest neighbour, the logistic classifier, multilayered perceptron (MLP), support vector machines (SVM), AdaBoost, Bagging, LogitBoost and Random Forest. The logistic classifier was singled out as the most accurate classifier, with an accuracy greater than 90. Using a 10 times 10-fold cross-validation provided within the Weka software, we found that the logistic classifier was significantly better than five classifiers (p<0.05) and indistinguishable from the other four classifiers. The initial set of 32 features was subsequently reduced to 6 features without compromising the classification accuracy. A further evaluation of the system alerted us to the possible sensitivity of the classification to the ground truth that might vary from one human expert to another. The analysis also revealed that the logistic classifier made most of the correct classifications with a high certainty.     

Variation in the composition of Lake Bonneville marl: a potential key to lake-level fluctuations and paleoclimate

Lake Bonneville marl provides a stratigraphic record of lake history preserved in its carbonate minerals and stable isotopes. We have analyzed the marl in shallow cores taken at three localities in the Bonneville basin. Chronology for the cores is provided by dated volcanic ashes, ostracode biostratigraphy, and a distinctive lithologic unit believed to have been deposited during and immediately after the Bonneville Flood.A core taken at Monument Point at the north shore of Great Salt Lake encompasses virtually the entire Bonneville lake cycle, including the 26.5 ka Thiokol basaltic ash at the base and deposits representing the overflowing stage at the Provo shoreline at the top of the core. Two cores from the Old River Bed area near the threshold between the Sevier basin and the Great Salt Lake basin (the main body of Lake Bonneville) represent deposition from the end of the Stansbury oscillation ( 20 ka) to post-Provo time ( 13 ka), and one core from near Sunstone Knoll in the Sevier basin provides a nearly complete record of the period when Lake Bonneville flooded the Sevier basin (20–13 ka).In all cores, percent calcium carbonate, the aragonite to calcite ratio, and percent sand were measured at approximately 2-cm intervals, and ¹⁸O and ¹³C were determined in one core from the Old River Bed area. The transgressive period from about 20 ka to 15 ka is represented in all cores, but the general trends and the details of the records are different, probably as a result of water chemistry and water balance differences between the main body and the Sevier basin because they were fed by different rivers and had different hypsometries. The Old River Bed marl sections are intermediate in position and composition between the Monument Point and Sunstone Knoll sections. Variations in marl composition at the Old River Bed, which are correlated with lake-level changes, were probably caused by changes in the relative proportions of water from the two basins, which were caused by shifts in water balance in the lake.This is the second paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.     

Large,solid particles in the clouds of Venus: Do they exist?

The discovery of large, solid particles in the clouds of Venus is one of the most significant findings of Pioneer Venus because it means that a substantial mass of the clouds is composed of a material other than sulfuric acid. The evidence which suggests that solid particles form a distinctive size mode is reexamined. The mode is defined by a discontinuity between two size ranges of the Pioneer Venus particle size spectrometer. This discontinuity could represent a real size mode. However, it could also be an artifact of the measurement technique. R. G. Knollenberg (1984) discusses several possible instrumental effects which might have caused this discontinuity. It is hypothesized herein that such effects did occur and that the large particles are really the tail of the mode 2 sulfuric acid particle size distribution and are not a separate mode of solid particles. Using such a revised size distribution, it is shown that all of the Pioneer Venus and Venera optical data from the lower clouds can be explained with sulfuric acid droplets without introducing any solid particles. As a by-product of this analysis, it is also found that the upper clouds of Venus must contain a material with a higher refractive index than sulfuric acid. A small quantity of sulfur could account for this observation.     

Solar irradiance changes caused by g-modes and large scale convection

Solar irradiance measurements from the ACRIM experiment show a clear response to the rotation periods of g-mode oscillations (l = 1, 2, and 3) and their first harmonics. Peaks in the ACRIM spectrum at 16.6, 18.3, 20.7, 36.5, and - 71 days all lie within about 1% of periods arising from g-mode rotation. This means that the g-modes are a fundamental cause of irradiance fluctuations. On time scales of months and less they modulate the irradiance by means of transient flows of global scale which they stimulate in the Sun's convective envelope. Dimensional arguments indicate that the flows carry up heat at an average rate 10^-3 L which is not in conflict with observed changes in the irradiance. Five additional tests for g-modes and large-scale convection are given. An instability is described which undermines diffusion models of sunspot energy storage.     

Science aspects of a mission beyond the planets

A mission out of the planetary system, launched about the year 2000, could provide valuable data concerning characteristics of the heliopause, the interstellar medium, stellar distances (by parallax measurements), low-energy cosmic rays, interplanetary gas distribution, and mass of the solar system. Secondary objectives include investigation of Pluto. Candidate science measurements, instruments, and instrument development needs are discussed. The mission should extend from 400 to 1000 AU from the Sun. A heliocentric hyperbolic escape velocity of 50–100 km/sec or more is needed to attain this distance within a reasonable mission duration (20–50 years). The trajectory should be toward the incoming interstellar gas. For a year 2000 launch, a Pluto encounter and orbiter can be included. A second mission targeted parallel to the solar axis would also be worthwhile.     

Kriging with imprecise (fuzzy) variograms. I: Theory

Imprecise variogram parameters are modeled with fuzzy set theory. The fit of a variogram model to experimental variograms is often subjective. The accuracy of the fit is modeled with imprecise variogram parameters. Measurement data often are insufficient to create good experimental variograms. In this case, prior knowledge and experience can contribute to determination of the variogram model parameters. A methodology for kriging with imprecise variogram parameters is developed. Both kriged values and estimation variances are calculated as fuzzy numbers and characterized by their membership functions. Besides estimation variance, the membership functions are used to create another uncertainty measure. This measure depends on both homogeneity and configuration of the data.     

Radiative transfer in spherical shell atmospheres: I. Rayleigh scattering

A comparison is made between the plane-parallel approximation and the more realistic spherical shell approximation for the radiance reflected from a planetary atmosphere. In this paper we have considered a planet of radius 6371 km (the Earth) with a homogeneous, conservative, Rayleigh scattering atmosphere extending to a height of 100 km. We have found significant departures from the plane-parallel approximation. Radiance versus height distributions for both single and multiple scattering are presented. Results are presented for the fractional radiance from altitudes in the atmosphere which contribute to the total unidirectional reflected radiance at the top of the atmosphere. We have referred to this as the radiance versus height distribution in the sequel. These data will be very useful for both remote sensing applications and planetary spectroscopy. We have also found that gross violations of the principle of reciprocity do occur in the spherical shell approximation.     

Heat-producing elements in the lunar mantle: Insights from ion microprobe analyses of lunar pyroclastic glasses

We provide new estimates for the abundance of heat-producing elements in the lunar mantle by using SIMS techniques to measure the concentrations of thorium and samarium in lunar pyroclastic glasses. Lunar pyroclastic glasses are utilized in this study because they represent quenched products of near-primary melts from the lunar mantle and as such, they provide compositional information about the mantle itself. Thorium and samarium were measured because: (1) Th is not significantly fractionated from Sm during partial melting of the pyroclastic glass source regions, which are dominated by olivine and pyroxene. Therefore, the Th/Sm ratios that we measure in the pyroclastic glasses reflect the Th/Sm ratio of the pyroclastic glass source regions. (2) Strong correlations between Th, U, and K on the Moon allow us to use measured Th concentrations to estimate the concentrations of U and K in the pyroclastic glasses. (3) Th, Sm, U, and K are radioactive elements and as such, their concentrations can be used to investigate heat production in the lunar mantle.The results from this study show that the lunar mantle is heterogeneous with respect to heat-producing elements and that there is evidence for mixing of a KREEP component into the source regions of some of the pyroclastic glasses. Because the source regions for many of the glasses are deep (?400 km), we propose that a KREEP component was transported to the deep lunar mantle. KREEP enriched sources produce 138% more heat than sources that do not contain KREEP and therefore, could have provided a source of heat for extended periods of nearside basaltic magmatism. Data from this study, in conjunction with models for the fractional crystallization of a lunar magma ocean, are used to show that the average lunar mantle contains 0.15 ppm Th, 0.54 ppm Sm, 0.039 ppm U, and 212 ppm K. This is a greater enrichment in radiogenic elements than some earlier estimates, suggesting a more prolonged impact of radiogenic heat on nearside basaltic volcanism.     

Molecular simulations of metal adsorption to bacterial surfaces

The atomic-scale interactions that occur between cations and the metal-binding cell wall components common to many gram-positive bacteria were investigated using molecular simulations techniques. We examined the adsorption of Cd and Pb onto peptidoglycan and teichoic acid components of the bacterial cell wall using classical energy force field methods. Within the framework of molecular mechanics and the Cerius² modeling software, we used energy minimization, conformational analysis, and molecular dynamics to examine the different components of the cell wall and to determine relative binding energies and structural configurations of the cell wall components, both with and without the metals present. Electronic structure calculations of representative metal-organic complexes validate the more practical classical methods required in simulating the large number of atoms associated with the cell wall components. The classical force field simulations were conducted in both gas phase and solvated periodic cells. Force field-based simulation techniques can adequately describe the interactions of Cd with the cell wall, defining both metal ion coordinations and binding distances. However, the classical force field approach is inconsistent in describing the observed Pb-cell wall interactions due to possible limitations in the force field parameters, the propensity for Pb to form hydroxides at circumneutral pH, or the dominance of other adsorption mechanisms.