In Situ Monitoring of Vapor Phase TCE Using a Chemiresistor Microchemical Sensor

A chemiresistor microchemical sensor has been developed to detect and monitor volatile organic compounds in unsaturated and saturated subsurface environments. A controlled study was conducted at the HAZMAT Spill Center at the Nevada Test Site, where the sensor was tested under a range of temperature, moisture, and trichloroethylene (TCE) concentrations. The sensor responded rapidly when exposed to TCE placed in sand, and it also responded to decreases in TCE vapor concentration when clean air was vented through the system. Variations in temperature and water vapor concentration impacted baseline chemiresistor signals, but at high TCE concentrations the sensor response was dominated by the TCE exposure. Test results showed that the detection limit of the chemiresistor to TCE vapor in the presence of fluctuating environmental variables (i.e., temperature and water vapor concentration) was on the order of 1000 parts per million by volume, which is about an order of magnitude higher than values obtained in controlled laboratory environments. Automated temperature control and preconcentration is recommended to improve the stability and sensitivity of the chemiresistor sensor.     

A review of the physics and ecological implications of the thermal bar circulation

Following recent applications of numerical modelling and remote sensing to the thermal bar phenomenon, this paper seeks to review the current state of knowledge on the effect of its circulation on lacustrine plankton ecosystems. After summarising the literature on thermal bar hydrodynamics, a thorough review is made of all plankton observations taken in the presence of a thermal bar. Two distinct plankton growth regimes are found, one with production favoured throughout the inshore region and another with a maximum in plankton biomass near the position of the thermal bar. Possible explanations for the observed distributions are then discussed, with reference to numerical modelling studies, and the scope for future study of this interdisciplinary topic is outlined.     

Papua New Guinea Highlands: palaeomagnetic constraints on terrane tectonics

Oblique convergence since the Early Cenozoic between the northward-moving Australian plate, westward-moving Pacific plate and almost stationary Eurasian plate has created a world-ranking tectonic zone in the eastern Indonesia–New Guinea–Southwest Pacific region (Tonga–Sulawesi megashear) that is notorious for its complex mix of tectonic styles and terrane juxtapositions. Unlike an ancient analog—the Mesozoic–Cenozoic Cordillera of North America—palaeomagnetic constraints on terrane motions in the zone are few. To improve the framework of quantitative control on such motions and therefore our understanding of the development of the zone, results of a palaeomagnetic study in the Highlands region of Papua New Guinea (PNG), in the southern part of the New Guinea Orogen, are reported. The study yields new insights into terrane tectonics along the Australian craton's active northern margin and confirms the complexity of block rotations to be expected at the local scale in tectonically intricate zones. The study is based on more than 500 samples (21 localities) collected from an interior and an exterior zone of New Guinea's central cordillera. The two zones are separated by the Tahin and Stolle–Lagaip–Kaugel Fault zones and collectively represent the para-autochthonous northern margin of the Australian craton. Samples from the interior zone, which in the study area comprises a cratonic spur of uncertain—probably displaced—origin, come from Triassic to Miocene sediments and subordinate volcanics of the Kubor Anticline, Jimi Terrane, and Yaveufa Syncline (16 localities) in the central and eastern Highlands. Samples from the exterior zone, which represent a basement-involved, Pliocene foreland fold-and-thrust belt, come from Middle Eocene to Middle Miocene carbonates and clastics (five localities) in the southern Highlands of the Papuan Fold Belt. Results permit us to constrain the tectonic evolution of the two zones palaeomagnetically. Using mainly thermal demagnetization techniques, three main magnetic components have been identified in the collection: (1) a recent field overprint of both normal and reverse polarity; (2) a pervasive overprint of mainly normal polarity that originated during extensive Middle to Late Miocene intrusive activity in the central cordillera; and (3) a primary component which has been identified in only 7 of the 21 localities (5 of 11 stratigraphic units represented in the collection). All components show patterns of rotation that are consistent within the zones, but differ between them. In the interior zone (central and eastern Highlands), large-scale counterclockwise rotations of between 30°+ and 100°+ have been established throughout the Kubor Anticline and Jimi Terrane, with some clockwise rotation present in the southern part of the Yaveufa Syncline. In contrast, in the Mendi area of the exterior zone (southern Highlands), clockwise rotations of between 30°+ and 50°+ can be recognized. These contrasting rotation patterns across the Tahin and Stolle–Lagaip–Kaugel Fault zones indicate decoupling of the two tectonic zones, probably along basement-involved faults. The clockwise rotations in the southern Highlands of the Papuan Fold Belt are to be expected from its structural grain, and are probably governed by regional basement faults and transverse lineaments. In contrast, the pattern of counterclockwise rotations in the Kubor Anticline–Jimi Terrane cratonic spur of the central and eastern Highlands was unexpected. The pattern is interpreted to result from non-rigid rotation of continental terranes as they were transported westward across the northeastern margin of the Australian craton. This margin became reorganised after the Middle Miocene, when the steadily northward-advancing Australian craton impinged into the westward-moving Pacific plate/buffer-plate system. Transpressional reorganisation under the influence of the sinistral Tonga–Sulawesi megashear became enhanced with Mio-Pliocene docking, and subsequent southward overthrusting, of the Finisterre Terrane onto the northeastern margin of the Australian craton.     

Eastern Laurentia in Rodinia: constraints from whole-rock Pb and U/Pb geochronology

Whole-rock Pb isotopic signatures and U/Pb geochronology refute a Rodinian correlation of northeastern Laurentia and proto-Andean Amazonia. According to this previously proposed model, the Labrador–Scotland–Greenland Promontory (LSGP) of northeastern Laurentia collided with the proto-Andean margin of Amazonia, at the Arica Embayment, during the Grenville/Sunsás Orogeny (ca. 1.0 Ga). Links between the two margins were based upon the correlation of the LSGP with Arequipa-Antofalla Basement (AAB), a Proterozoic block along the proto-Andean margin of Amazonia adjacent to the Arica Embayment. Specifically, similarities in 1.8–1.0 Ga basement rocks in both regions suggested that the AAB was originally a piece of the LSGP. Furthermore, similarities in unique, post-collisional, but pre-rift, glacial sedimentary sequences also supported a link between the AAB and LSGP.Tests of these apparent similarities fail to support correlation of the AAB and the LSGP and, thus, eliminate a direct link between northeastern Laurentia and southwestern Amazonia in Rodinia. However, Pb isotopic compositions and U/Pb geochronology provide the basis for two new correlations, namely, (1) the ca. 1.3–1.0 Ga basement in the central and southern Appalachians may be an allochthonous block that was transferred to Laurentia from Amazonia at ca. 1.0 Ga, and (2) an allochthonous AAB may be a piece of the Kalahari Craton that was transferred to Amazonia at ca. 1.0 Ga. Based on these new correlations and a previously proposed Grenvillian connection between southern Laurentia (Llano) and Kalahari, we propose that Amazonia may have collided with a contiguous southeastern Laurentia/Kalahari margin at ca. 1.0 Ga.     

Late Pleistocene and early Holocene rivers and wetlands in the Bonneville basin of western North America

Field investigations at Dugway Proving Ground in western Utah have produced new data on the chronology and human occupation of late Pleistocene and early Holocene lakes, rivers, and wetlands in the Lake Bonneville basin. We have classified paleo-river channels of these ages as “gravel channels” and “sand channels.” Gravel channels are straight to curved, digitate, and have abrupt bulbous ends. They are composed of fine gravel and coarse sand, and are topographically inverted (i.e., they stand higher than the surrounding mudflats). Sand channels are younger and sand filled, with well-developed meander-scroll morphology that is truncated by deflated mudflat surfaces. Gravel channels were formed by a river that originated as overflow from the Sevier basin along the Old River Bed during the late regressive phases of Lake Bonneville (after 12,500 and prior to 11,000 ¹⁴C yr B.P.). Dated samples from sand channels and associated fluvial overbank and wetland deposits range in age from 11,000 to 8800 ¹⁴C yr B.P., and are probably related to continued Sevier-basin overflow and to groundwater discharge. Paleoarchaic foragers occupied numerous sites on gravel-channel landforms and adjacent to sand channels in the extensive early Holocene wetland habitats. Reworking of tools and limited toolstone diversity is consistent with theoretical models suggesting Paleoarchaic foragers in the Old River Bed delta were less mobile than elsewhere in the Great Basin.     

Paleoecology of two marine oxygen isotope stage 7 sites correlated by the Sheep Creek tephra, northwestern North America

Pollen analysis at two sites, correlated by the presence of the 190,000 yr-old Sheep Creek tephra, documents fluctuations in vegetation and climate consistent with this date and indicates that the records span marine oxygen isotope stage 7 and the stage 6/7 transition. Dawson Cut, near Fairbanks, Alaska, provides a 5.2-m-long pollen record of interglacial boreal forest succeeded by shrub tundra and then forest/tundra. Ash Bend, Stewart River, central Yukon, provides a 9.5-m-long record of interglacial boreal forest succeeded by forest/tundra, shrub tundra, and herbaceous tundra. The replacement of forest at both sites by more open or tundra vegetation indicates warm interglacial conditions giving way to cold and arid climate. It is not clear whether stage 7 was warmer than the present. The warm-cool-warm climate oscillation evident at both sites may correlate to Lake Baikal substages 7a, 7b, and 7c. Sheep Creek tephra fell on forest/tundra vegetation.     

Lower-crustal rifting in the Rukwa Graben, East Africa

An M_w 5.9 earthquake occurred in the Lake Rukwa rift, Tanzania, on 1994 August 18, and was well recorded by 20 broad-band seismic stations at distances of 160 to 800 km and 21 broad-band stations at teleseismic distances. The regional and teleseismic waveforms have been used to investigate the source characteristics of the main shock, and also to locate aftershocks that occurred within three weeks of the main shock. Teleseismic body-wave modelling yields the following source parameters for the main shock: source depth of 25 ± 2 km, a normal fault orientation, with a horizontal tension axis striking NE-SW and an almost vertical pressure axis (Nodal Plane I: strike 126°–142°, dip 63°–66°, and rake 280°–290°; Nodal Plane II: strike 273°–289°, dip 28°–31°, and rake 235°–245°), a scalar moment of 4.1 times 10¹⁷ N m, and a 2 s impulsive source time function. Four of the largest aftershocks also nucleated at depths of 25 km, as deduced from regional sPmp–Pmp times. The nodal planes are broadly consistent with the orientation of both the Lupa and Ufipa faults, which bound the Rukwa rift to the northeast and southwest, respectively. The rupture radius of the main shock, assuming a circular fault, is estimated to be 4 km with a corresponding stress drop of 6.5 MPa. Published estimates of crustal thickness beneath the Rukwa rift indicate that the foci of the main shock and aftershocks lie at least 10 km above the Moho. The presence of lower-crustal seismicity beneath the Rukwa rift suggests that the pre-rift thermal structure of the rifted crust has not been strongly modified by the rifting, at least to depths of 25 km.     

Phase relations of osumilite and dehydration melting in pelitic rocks: a simple thermodynamic model for the KFMASH system

 Thermodynamic modelling of (1) osumilite solid solutions and (2) dehydration melting in pelitic compositions within the KFMASH system is quite successful in reproducing the invariant and univariant reactions determined in experimental studies. Even though rather preliminary, such melt thermodynamic models may be very useful in interpolating and extrapolating the limited information available from a small number of experimental runs. These methods allow the compositions of all phases to be monitored as a function of pressure, temperature and equilibrium phase assemblage for any desired bulk composition. Locating the higher variance phase fields (e.g. quadrivariant, quinivariant) is often difficult or impossible by inspection, but is made relatively easy using thermodynamic software such as thermocalc. In the KFMASH system the calculated partition of Fe and Mg between osumilite, garnet, cordierite, orthopyroxene and biotite are shown to be in good agreement with experimental and natural data and allow reliable calculation of mineral compositions coexisting with quartz-saturated and H₂O-undersaturated melts for a variety of bulk compositions. These phase diagram calculations allow quite tight limits to be placed on the pressure, temperature and water activity conditions which accompanied metamorphism of natural osumilite occurrences in Nain, Namaqualand, and Rogaland. At fixed bulk composition, the initial melting of pelites by dehydration of biotite can occur via univariant, divariant or trivariant equilibria depending upon pressure of metamorphism. Of particular interest is that, for low pressures or more magnesian bulk compositions, fluid-absent melting begins by generating liquid from the high-variance assemblage biotite+cordierite+K-feldspar+ quartz. This type of modelling allows investigation, at least qualitatively, of the fine scale details of melt production as a function of changes in pressure, temperature and bulk composition. Received: 29 November 1995 / Accepted: 22 April 1996