Origin of the Blue Ridge escarpment along the passive margin of Eastern North America

The Blue Ridge escarpment is a rugged landform situated within the ancient Appalachian orogen. While similar in some respects to the great escarpments along other passive margins, which have evolved by erosion following rifting, its youthful topographic expression has inspired proposals of Cenozoic tectonic rejuvenation in eastern North America. To better understand the post‐orogenic and post‐rift geomorphic evolution of passive margins, we have examined the origin of this landform using low‐temperature thermochronometry and manipulation of topographic indices. Apatite (U–Th)/He and fission‐track analyses along transects across the escarpment reveal a younging trend towards the coast. This pattern is consistent with other great escarpments and fits with an interpretation of having evolved by prolonged erosion, without the requirement of tectonic rejuvenation. Measured ages are also comparable specifically to those measured along other great escarpments that are as much as 100 Myr younger. This suggests that erosional mechanisms that maintain rugged escarpments in the early post‐rift stages may remain active on ancient passive margins for prolonged periods. The precise erosional evolution of the escarpment is less clear, however, and several end‐member models can explain the data. Our preferred model, which fits with all data, involves a significant degree of erosional escarpment retreat in the Cenozoic. Although this suggests that early onset of topographic stability is not required of passive margin evolution, more data are required to better constrain the details of the escarpment's development.     

Volcanic ash clouds affecting Northern Europe: the long view

The volcanic ash or ‘tephra’ cloud resulting from the relatively small (volume and VEI) eruption of the Icelandic volcano Eyjafjallajökull in 2010 caused major air travel disruption, at substantial global economic cost. On several occasions in the past few centuries, Icelandic eruptions have created ash and/or sulphur dioxide clouds which were detected over Europe (e.g. Hekla in 1947, Askja in 1875, and Laki in 1783). However, these historical observations do not represent a complete record of events serious enough to disrupt aviation in Europe. The only feasible evidence for this is within the geological tephra record. Ash layers are preserved in bogs and lakes where tephra deposited from the atmosphere is incorporated in the peat/mud. In this article we: 1, introduce the analysis of the Northern European sedimentary tephra record; 2, discuss our findings and modelling results; 3, highlight how these were misinterpreted by the popular media; and 4, use this experience to outline several existing problems with current tephra studies and suggest agendas for future research.     

Defining the distribution of arsenic species and plant nutrients in rice (Oryza sativa L.) from the root to the grain

The transport mechanisms of As from contaminated soil or irrigation water into roots and subsequently into grain, and the As species distribution—a toxicity determinant, is critical for assessing health risks imposed by As. However, the commonly-employed extraction of plant material with trifluoroacetic acid (TFA) has not proven successful in preserving inorganic As species. Synchrotron-based spectroscopic techniques are useful for discerning elemental distributions and chemical speciation of elements in situ. Here, we both characterize the mineral phases of Fe coatings on rice roots, and quantify plant nutrients and As species in situ on roots and grain samples. Arsenic in rice grains was present in bran layers as oxidized As (69-88% as As(V)_i and 12-31% as DMA) and in the germ as a mixture of As(V)_i and As(III)_i, but was non-detected from the endosperm, which is consistent with previous findings. The extent of Fe coatings on rice roots was variable and, when present, consisted of lepidocrocite (γ-FeOOH), goethite (α-FeOOH) and ferrihydrite (Fe(OH)₃·nH₂O). Arsenic was co-located with root Fe coatings, but our findings indicate that Fe is not a direct interceptor of As uptake, and is rather a bulk scavenger mostly near the air-water interface. On whole root mounts with Fe plaque, arsenic was present as mixed species of As(V)_i (44-66%) and As(III)_i (34-56%). Within a root cross-section, oxidized As species were dominant in the xylem (86% as As(V)_i and 14% as DMA) whereas mostly reduced species (71% as As(III)_i, 29% as AsGlu₃) resided within a vacuole adjacent to the xylem. This finding contrasts the prevailing view that As(V)_i is rapidly reduced in roots and transported to shoots as As(III)_i, and points to the importance of interspecies differences in As-uptake dynamics.     

Do paleoclimate proxies agree? A test comparing 19 late Holocene climate and sea‐ice reconstructions from Icelandic marine and lake sediments

Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP₂₅, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.     

A signature of the donor star in the extra-galactic X-ray binary LMC X−2

Two nights of phase-resolved medium-resolution Very Large Telescope spectroscopy of the extra-galactic low-mass X-ray binary LMC X−2 have revealed a 0.32 ± 0.02 d spectroscopic period in the radial velocity curve of the He  ii λ4686 emission line that we interpret as the orbital period. However, similar to previous findings, this radial velocity curve shows a longer term variation that is most likely due to the presence of a precessing accretion disc in LMC X−2. This is strengthened by He  ii λ4686 Doppler maps that show a bright spot that is moving from night to night. Furthermore, we detect narrow emission lines in the Bowen region of LMC X−2, with a velocity of   K _em= 351 ± 28 km s⁻¹  , that we tentatively interpret as coming from the irradiated side of the donor star. Since K _em must be smaller than K ₂, this leads to the first upper limit on the mass function of LMC X−2 of   f ( M ₁) ≥ 0.86  M_⊙  (95 per cent confidence), and the first constraints on its system parameters.     

Alteration of five organic compounds by glow discharge plasma and UV light under simulated Mars conditions

The Viking missions to Mars failed to detect any organic material in regolith samples. Since then, several removal mechanisms of organic material have been proposed. Two of these proposed methods are removal due to exposure to plasmas created in dust devils and exposure to UV irradiation. The experiments presented here were performed to identify similarities between the two potential removal mechanisms and to identify any compounds produced from these mechanisms that would have been difficult for the Viking instruments to detect. Five organic compounds, phenanthrene, octadecane, octadecanoic acid, decanophenone and benzoic acid, were exposed to a glow discharge plasma created in simulated martian atmospheres as might be present in dust devils, and to UV irradiation similar to that found at the surface of Mars. Glow discharge exposure was carried out in a chamber with 6.9 mbar pressure of a Mars like gas composed mostly of carbon dioxide. The plasma was characterized using emission spectroscopy and found to contain cations and excited neutral species including carbon dioxide, carbon monoxide, and nitrogen. UV irradiation experiments were performed in a Mars chamber which simulates the temperature, pressure, atmospheric composition, and UV fluence rates of equatorial Mars. The non-volatile residues left after each exposure were characterized by mass loss, infrared spectroscopy and high resolution mass spectrometry. Oxidized, higher molecular weight versions of the parent compounds containing carbonyl, hydroxyl and alkenyl functional groups were identified. The presence of these oxidized compounds suggests that searches for organic material in soils on Mars use instrumentation suitable for detection of compounds which contain the above functional groups. Discussions of possible reaction mechanisms are given.     

Evaluating techniques for sampling stream crayfish (Paranephrops planifrons)

We evaluated several capture and analysis techniques for estimating abundance and size structure of freshwater crayfish (Paranephrops planifrons) (koura) from a forested North Island, New Zealand stream to provide a methodological basis for future population studies. Direct observation at night and collecting with baited traps were not considered useful. A quadrat sampler was highly biased toward collecting small individuals. Handnetting at night and estimating abundances using the depletion method were not as efficient as handnetting on different dates and analysing by a mark‐recapture technique. Electrofishing was effective in collecting koura from different habitats and resulted in the highest abundance estimates, and mark‐recapture estimates appeared to be more precise than depletion estimates, especially if multiple recaptures were made. Handnetting captured more large crayfish relative to electrofishing or the quadrat sampler.