闽北早古生代岛弧火山岩的岩石地球化学特征

作者系统地研究了福建政和早古生代岛弧火山岩的岩石地球化学特征。研究表明该火山岩是以岛弧拉斑玄武岩-钙碱性火山岩组合为特征的岛弧火山岩系列，并具有从拉斑系列向钙碱性系列演化的特征；该火山岩源于亏损地幔，并且受到一定的陆壳物质混染，基性的拉斑玄武质系列受到陆壳物质混染较少，而中性钙碱性系列则受到较大程度混染。     

东天山康古尔金矿床成矿流体地球化学特征及其来源

新疆康古尔金矿床是分布于晚古生代火山岩区受脆韧性剪切带控制的蚀变岩型金矿。该矿床成矿流体具有中低温度（３２０～１００℃）、中等ＮａＣｌ质量分数（１１４％～１７０％）、弱还原等特征。包裹体气相成分以Ｈ２Ｏ和ＣＯ２为主,液相成分中富Ｎａ＋、Ｃｌ－,而贫Ｋ＋、Ｆ－。成矿流体δＤ为－４５‰～－６６‰,δ１８Ｏ为－８３４‰～２９８‰,（８７Ｓｒ／８６Ｓｒ）ｉ值为０７０７７～０７１０６,反映了成矿流体由变质水、大气降水和岩浆水混合组成的特点     

Geochemical characteristics,cooling history and mineralization significance of Zhangtiantang pluton in South Jiangxi Province,P.R. China

The zircon SHRIMP dating of the Zhangtiantang granite gave an age of 159±7 Ma., which shows that the granite was produced at the early Late Jurassic. The Ar-Ar plateau ages of biotite and K-feldspar from the Zhangtiantang pluton are 153.2±1.1 Ma and 135.8±1.2 Ma, respectively. The Ar-Ar anti-isochrone ages of biotite and K-feldspar are 152.5±1.7Ma and 135.4±2.7Ma, respectively. The ages represent the isotopic closure ages of minerals in the pluton. The Zhangtiantang granites are regarded as peraluminous crust-derived type granites to possess the typical geochemical characteristics of calc-alkaline rocks on continental margin, with enriched Si, K, Al (average value of A/CNK as 1.18), HREE, Rb, U, and Th, heavily depleted V, Cr, Co, Ni, Ti, Nb-Ta, Zr, Sr, P, and Ba, strongly negative Eu and common corundum normative (average value of C as 1.84). The εNd_(t) values of the Zhangtiantang granite are −5.84 to −7.79, and t _2DM values are 1.69 to 1.83 Ga, which indicates partial melting of continental-crust metamorphic sedimentary rocks during the Middle Proterozoic. The cooling history of the Zhangtiantang granitic pluton indicates that the cooling velocity of pluton was faster (about 67°C/Ma) from zircon (158 Ma) to biotite (152 Ma), and was slower (about12°C/Ma) from biotite (152.5 Ma) to K-feldspar (135.8 Ma). It can be deduced that the temporal gap (about 10 Ma) between the granite formmation and W-Sn mineralization in South China may be related to ordinary magma-hydrothermal processes by the variational cooling curve of the pluton. The Zhangtiantang pluton was formed in a compressive setting, with differentiation evolution and mineralization occurring in a relative relaxation setting.     

Interactions between basalts and oil source rocks in rift basins： CO2 generation

Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China.     

开发尺度的曲流河储层内部结构地震沉积学解释方法

曲流河地层内部结构复杂,岩性界面具有穿时性,传统的地震相分析法不能满足油藏开发地质研究中对储层内部结构精细解释的需要,急需探索有效的地震解释方法。采用基于探地雷达的露头探测、点坝复合体三维正演模拟和实际地震资料相结合的方法,分析了地震资料频率和地层厚度对曲流河内部结构地震反射特征的影响,研究了利用地层切片解释曲流河沉积结构的原理和方法,建立了开发尺度的曲流河内部结构地震沉积学解释技术。研究发现:(1)高频地震资料中地震反射能够反映曲流河侧积复合体边界,而低频地震资料中反射同相轴与岩性界面一致;(2)不同厚度的点坝侧积单元地震反射特征存在差异,造成反射剖面的多解性。同时指出曲流河内部结构地震沉积学解释的技术关键:(1)发挥地震资料平面与剖面信息的相互约束和补充;(2)将地质体作为三维空间发育的成因体,利用其平面与剖面特征的成因联系指导解释;(3)级次化解释方法,在不同级次上采用针对性的解释方法。将该方法应用于墨西哥湾新近系地震沉积学解释,实现了曲流河点坝复合体内部结构的三维刻画。     

Re–Os and U–Pb Geochronology of Porphyry and Skarn Types Copper Deposits in Jilin Province,NE China

Jilin Province in NE China lies on the eastern edge of the Xing–Meng Orogenic Belt. Mineral exploration in this area has resulted in the discovery of numerous large, medium, and small sized Cu, Mo, Au, and Co deposits. To better understand the formation and distribution of both the porphyry and skarn types Cu deposits of the region, we examined the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of the mineralization. The Binghugou Cu deposit yields a zircon U–Pb age for quartz diorite of 128.1 ± 1.6 Ma; the Chang'anpu Cu deposit yields a zircon U–Pb age for granite porphyry of 117.0 ± 1.4 Ma; the Ermi Cu deposit yields a zircon U–Pb age for granite porphyry of 96.8 ± 1.1 Ma; the Tongshan Cu deposit yields molybdenite Re–Os model ages of 128.7 to 130.2 Ma, an isochron age of 129.0 ± 1.6 Ma, and a weighted mean model age of 129.2 ± 0.7 Ma; and the Tianhexing Cu deposit yields molybdenite Re–Os model ages of 113.9 to 115.2 Ma, an isochron age of 114.7 ± 1.2 Ma, and a weighted mean model age of 114.7 ± 0.7 Ma. The new ages, combined with existing geochronology data, show that intense porphyry and skarn types Cu mineralization was coeval with Cretaceous magmatism. The geotectonic processes responsible for the genesis of the Cu mineralization were probably related to lithospheric thinning. By analyzing the accumulated molybdenite Re–Os, zircon U–Pb, and Ar–Ar ages for NE China, it is concluded that the Cu deposits formed during multiple events coinciding with periods of magmatic activity. We have identified five phases of mineralization: early Paleozoic (~476 Ma), late Paleozoic (286.5–273.6 Ma), early Mesozoic (~228.7 Ma), Jurassic (194.8–137.1 Ma), and Cretaceous (131.2–96.8 Ma). Although Cu deposits formed during each phase, most of the Cu mineralization occurred during the Cretaceous.     

矿物流体包裹体中的羧酸

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...     

基于边坡渐进破坏特征对传统极限平衡法几点假设的合理分析

边坡的渐进破坏特征一直以来是边坡计算仿真中的一个难点。实际边坡的破坏很少是一个整体达到极限状态,突然滑动的过程,往往是逐步发展由局部破坏到最终整体失稳,即临界状态小扰动导致的链式多米洛骨牌式失稳。利用颗粒流软件,设计了0.1 m粒径高10 m土坡的数值模型,粒间黏聚力为36 kPa,摩擦系数为0.36。初始模型在重力作用下不会发生破坏,通过单独折减粒间黏聚力到18 kPa使得边坡破坏,监测竖向颗粒组group的变化获取每20 000个时间步的边坡破坏形态,实现200 000个时间步内边坡的渐进破坏过程。边坡总是从局部开始破坏,坡体物质的运移造成次一级破坏,形成最终的近似弧形的滑动面,说明滑体不是整体下滑,不是刚体,不是整体达到极限状态;坡体内应力的变化也不是单调的,有涨有落,均区别于当前极限平衡法中有限条块的刚体假设;滑动面上同时达到极限状态假设,问题本身是静不定的,通过给出条间力的传递方式使之静定可解;整体分析不能考虑破坏的局部化和渐进特征。这说明边坡计算方法的未来在于能反映动力问题和材料破坏特征的离散元方法。     

西藏措勤晚白垩世英安岩的厘定与地球化学特征

野外地质调查和SHRIMP锆石U/Pb地质年代学研究表明,拉萨地块中带措勤地区发育一套形成于晚白垩世中期的英安岩(88.5±1.2 Ma)。该套火山岩具有岛弧火山岩的地球化学特征,为地壳深部岩浆岩部分熔融形成的Ⅰ型岩浆岩,经历了明显的斜长石分离结晶作用。与同时代的侵入岩相比,该套火山岩为高度演化的岩浆,Rb/Sr比值较高,但Sr/Y比值较低。在拉萨地块内部,广泛发育的90～85 Ma的岩浆作用与新特提斯洋的北向俯冲作用相关。     

中国海洋的珊瑚-珊瑚礁: 南海中央区珊瑚-珊瑚礁生物多样性特征

珊瑚是地球上最古老的原住民,具有近6×108年的发育史,弱势群居、喜温和原地长成是珊瑚的基本特征。作者介绍了珊瑚-珊瑚礁的基本特征,综述了跨十年调查的研究区珍贵照片资料和相关认识,指出中国是全球主要的珊瑚-珊瑚礁国家,地位举足轻重;珊瑚-珊瑚礁作为地球生物多样性的代表,造岛、固礁、护鱼、防护岛岸流失,形成南海四大群岛280余座岛、礁、滩、沙,所构建庞大海洋生态系统是无与伦比的海洋生态资源和寸土寸金的南海海洋国土。提出划分南海珊瑚-珊瑚礁为中央区和周缘区2个分布区,阐述了南海中央区珊瑚-珊瑚礁的基本特征,系统汇集报道了间隔10年2个科考航次调查在浅水礁盘浮潜、至20 m水深浅潜-深潜和礁盘及开展岛、礁、滩、沙地质调查的发现,包括科学定名46种六放石珊瑚和6种八放软珊瑚等成果,同时,收集了西沙、中沙、东沙和南沙群岛海域的相关调查航次珊瑚照片;进一步阐述了单体环礁和复合环礁的特征及分布,并进行了初步对比,指出永乐环礁是南海唯一一个真正的切合达尔文模式的环礁,也是环礁发展到最高阶段的产物,构成现代海洋珊瑚-珊瑚礁形成演化研究最好的天然实验室。