Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

辽吉东部层状混合岩的成因

辽吉东部的层状混合岩与上、下围岩始终保持整合接触,反映它的体系基本上是封闭的,没有外来组份的加入。其组构、岩石化学、微量元素和稀土资料等表明层状混合岩不足岩浆型的,而是重熔岩浆型的,其原岩是沉积变质岩。     

The Influence of Chlorine on the Determination of Combined Water: An Investigation of a Correction Procedure

Differential thermal analysis, pH determination and ion chromatography were used to investigate the interference of chlorine in the determination of combined water (H₂O⁺) by the Penfield tube gravimetric method. The magnitude of the chlorine interference was quantified and a correction method was proposed to obtain accurate results for H₂O⁺. The method was applied to the determination of H₂O⁺ in deep sea sediments containing chlorine and certified reference materials of oceanic polymetallic nodules.     

桥梁气象专题研究与服务

根据实际开展的桥梁气象专题研究，分析桥梁气象研究与服务如何面对国内大型桥梁建设发展趋势所带来的机遇和挑战，提出开展桥梁气象研究与服务的必要性，并从桥位气候背景、桥位气象参数取值、桥梁气象研究方法以及桥梁施工及营运期气象服务与保障等方面介绍桥梁气象专题研究及服务应开展的主要内容，同时，给出一个已投入实际使用的桥梁施工期气象环境监测与预警系统的建设思路。     

多普勒雷达基本观测量直接同化对模式物理量场的影响

在GRAPES一3DVar雷达同化模块的基础上,建立了多普勒径向速度和基本反射率因子的直接同化观测算子,实现了雷达反射率因子和径向速度的直接同化,并对2007年7月3日的江淮梅雨进行了模拟试验。结果表明,多普勒径向速度的直接同化的主要影响表现在风场上,能够改善几乎整个三维风场分析,在雷达影响半径范围内,风场明显得到加强,影响当时天气的系统及其高低层配置被合理模拟,但对湿度场影响甚微。雨水混合比的直接同化的主要影响表现在湿度场上,改进了模式对湿度场的模拟,对降水的影响十分显著,有利于准确模拟降水的发展和维持,减小了Spin—up现象;其亦可使整个风场微弱增强,但影响甚微。     

The characteristics of ultraviolet radiation in arid and semi-arid regions of China

Measurements of the broadband global solar radiation (R _S) and total ultraviolet radiation (the sum of UV-A and UV-B) were conducted from 2005 to 2010 at 9 sites in arid and semi-arid regions of China. These data were used to determine the temporal variability of UV and UV/R _S and their dependence on the water vapor content and clearness index. The dependence of UV/R _S on aerosol optical depth (AOD) and water vapor content was also investigated. In addition, a simple and efficient empirically model suited for all-weather conditions was developed to estimate UV from R _s. The annual average daily UV level in arid and semi-arid areas is 0.61 and 0.59 MJ m^?2 d^?1, respectively. The highest value (0.66?±?0.25 MJ m^?2 d^?1) was recorded at an arid area at Linze. The lowest value (0.53?±?0.22 MJ m^?2 d^?1) was recorded at a semi-arid area at Ansai. The highest daily value of UV radiation was measured in May, whereas the lowest value was measured in December. The monthly variation of the UV/R _s ratio ranged from 0.41 in Aksu to 0.35 in Qira. The monthly mean value of UV/R _s gradually increased from November and then decreased in August. A small decreasing trend of UV/R _s was observed in the arid and semi-arid regions due to recently increasing amounts of fine aerosol. A simple and efficient empirically model suit for all-weather condition was developed to estimate UV from R _s. The slope a and intercept b of the regression line between the estimated and measured values were close to 1 and zero, respectively. The relative error between the estimated and measured values was less than 11.5%. Application of the model to data collected from different locations in this region also resulted in reasonable estimates of UV.     

水平离散网格与大气运动

从线性浅水方程组出发,在Arakawa A-E网格和z网格上,从频率和群速方面讨论了这六种网格对大气中的两种重要的波动：惯性重力波和Rossby波的描述能力。结果表明：C、z、E网格比其它网格产生的歪曲都要小。     

东胜区污染状况分析

文章利用东胜区主要污染源排放情况以及2005年9月1日-2007年8月31日每日SO2、NO2、PM10浓度监测值和2005-2007年SO2、NO2、PM10平均值,分析了东胜区主要污染类型、污染物来源以及东胜区近3年SO2、NO2、PM10监测值日、月、季、年分布特征和变化规律;提出了消减大气污染物排放的对策。     

风应力的旋转和辐散分量在ENSO循环中作用的数值试验研究

将 1 960～ 1 991年的月平均 FSU风应力资料分解为旋转部分和辐散辐合部分 ,分别用以强迫模式海洋。所用的模式为一个 2层热带太平洋区域海洋模式。结果表明 ,就季节变化而言 ,不论是用旋转分量还是散合分量强迫海洋 ,都不能产生合理的冷舌 ,哪怕将旋转或散合分量放大一倍或缩小二分之一 ,也不能使冷舌的强度和分布得到合理的改善。若采用气候平均的含有季节变化的风应力 (未对旋转和辐散分量进行分离 ) ,则可产生与实际相符的海表温度分布。在此基础上 ,分别叠加旋转和辐散分量的年际异常部分 ,通过对海洋的强迫 ,可产生海表温度异常。在年际异常旋转分量的强迫下 ,可产生较强的 SSTA振荡且具有明显的 ENSO周期 ;而在辐散辐合年际异常风应力的强迫下 ,则产生较弱的 SSTA,且振荡频率较高 ,ENSO周期不很明显。这些结果说明 ,风应力的涡旋和辐散辐合分量在海温季节变化和年际变化的形成中具有不同的作用 ,即合理的冷舌分布需要风应力旋转分量和散合分量同时作用于海洋方可产生 ,而仅有异常风应力的旋转强迫就可产生合理的 EL Nino/ La Nina现象。同时 ,风应力的辐散辐合分量在海洋平均状态的形成过程中是重要的 ,但在 EN-SO过程中就对海洋的作用而言则不如旋转分量重要。     

闽北邵武地区水系沉积物地球化学特征及找矿预测

邵武地区位于浙中—武夷山(隆起)W-Sn-Mo-Au-Ag-Pb-Zn-Nb-Ta-(叶腊石)-萤石成矿带(Ⅲ-81), 闽西北萤石矿成矿亚带(Ⅳ-1)的西南部, 具有较好的找矿前景。本次综合研究元素的地球化学特征参数, 元素R聚类相关性、单元素异常特征等, 表明F、Au、Pb、Zn、Nb、Ta等元素具有一定的找矿潜力, 并圈定单元素异常652个, 综合异常26处; 依据水系沉积物异常、筛选、评序及主要异常解释推断的成果, 结合区内成矿地质构造背景, 圈定村尾—下炉铅锌矿、吴家塘—南山下萤石矿、祝岭—洋半天萤石矿和铅锌矿、半岭—张厝萤石矿找矿预测区4处, 为该区下一步找矿工作提供了勘查方向和重要参考; 优选出半岭—张厝萤石矿找矿预测区, 通过野外路线地质调查、槽探等手段进行了异常查证, 得到了较好的找矿预期效果。