Solute concentrations of overland flow water in a cultivated field: spatial variations,intra‐ and inter‐storm trends

Major solute concentrations in overland flow water (OFW) were measured in an agricultural field of Brittany (western France). Two storm events were monitored in detail to examine the short time‐scale processes. During one year, samples were taken at different positions on the slope after each storm event to describe the spatial and seasonal variations of OFW chemistry. Although the total dissolved load in OFW is not much higher than in rain water, distinctive features are observed. K⁺, Ca²⁺, NH₄ , Cl⁻ and SOare the major solutes. The main origin of the elements (sea salts, exchangeable soil complex or fertilizers) determined most of the variations observed. Spatial variations along the slope are mainly seen for exchangeable cations, while seasonal variations are predominant for sea salts. Rainfall intensity and suspended sediment load induce strong differences between the two storm events studied in detail. However, the within‐storm variations and the seasonal monitoring show that this relationship is complex. Within‐storm variations suggest that, in addition to desorption processes, mixing with pre‐event water may occur. The lack of a relationship between sediment load and dissolved load is attributed to the high rate of the exchange processes, which has been checked by a simple experiment in vitro. It is concluded that the conditions of the transit of water on the field (velocity, length, status of the surface, crusted or not) may well play a major role in the chemical changes between rain water and OFW. The results suggest that vegetated buffer strips designed to reduce the sediment load only, and not the amount of overland flow, will have little effect on the transfer of dissolved pollutants to the watercourses. Copyright © 1999 John Wiley & Sons, Ltd.     

Uraniferous bitumen nodules in the Talvivaara Ni–Zn–Cu–Co deposit (Finland): influence of metamorphism on uranium mineralization in black shales

In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite.     

Benchmarking sustainability in cities: The role of indicators and future scenarios

Scenarios are a useful tool to help think about and visualise the future and, as such, are utilised by many policymakers and practitioners. Future scenarios have not been used to explore the urban context in much depth, yet have the potential to provide valuable insights into the robustness of decisions being made today in the name of sustainability. As part of a major research project entitled Urban Futures, a toolkit has been developed in the UK to facilitate the use of scenarios in any urban context and at any scale relevant to that context. The toolkit comprises two key components, namely, (i) a series of indicators comprising both generic and topic area-specific indicators (e.g., air quality, biodiversity, density, water) that measure sustainability performance and (ii) a list of characteristics (i.e., 1–2-sentence statements about a feature, issue or small set of issues) that describe four future scenarios. In combination, these two components enable us to measure the performance of any given sustainability indicator, and establish the relative sensitivity or vulnerability of that indicator to the different future scenarios. An important aspect of the methodology underpinning the toolkit is that it is flexible enough to incorporate new scenarios, characteristics and indicators, thereby allowing the long-term performance of our urban environments to be considered in the broadest possible sense.     

Water and nutrient predictions in ungauged basins: set-up and evaluation of a model at the national scale

Abstract

A dynamic water quality model, HYPE, was applied to a large, data-sparse region to study whether reliable information on water quantity and water quality could be obtained for both gauged and ungauged waterbodies. The model (called S-HYPE) was set up for all of Sweden (～450 000 km²), divided into sub-basins with an average area of 28 km². Readily available national databases were used for physiographic data, emissions and agricultural practices, fixed values for representative years were used. Daily precipitation and temperature were used as the dynamic forcing of the model. Model evaluation was based on data from several hundred monitoring sites, of which approximately 90% had not been used in calibration on a daily scale. Results were evaluated using the Nash-Sutcliffe efficiency (NSE), correlation and relative errors: 92% of the spatial variation was explained for specific water discharge, and 88% and 59% for total nitrogen and total phosphorus concentrations, respectively. Day-to-day variations were modelled with satisfactory results for water discharge and the seasonal variation of nitrogen concentrations was also generally well captured. In 20 large, unregulated rivers the median NSE for water discharge was 0.84, and the corresponding number for 76 partly-regulated river basins was 0.52. In small basins, the NSE was typically above 0.6. These major achievements relative to previous similar experiments were ascribed to the step-wise calibration process using representative gauged basins and the use of a modelling concept, whereby coefficients are linked to physiographic variables rather than to specific sites.

Editor D. Koutsoyiannis

Citation Strömqvist, J., Arheimer, B., Dahné, J., Donnelly, C. and Lindström, G., 2012. Water and nutrient predictions in ungauged basins: set-up and evaluation of a model at the national scale. Hydrological Sciences Journal, 57 (2), 229–247.     

Isotope and trace element geochemistry of Colorado Plateau volcanics

Basalts from the San Francisco Peaks and North Rim of Grand Canyon, nephelinites from the Hopi Buttes and Navajo minettes (Colorado Plateau) have been analyzed for trace element contents and Sr, Nd, Pb isotope compositions. The ages increase eastward from the Quaternary (basalt) to 5 Ma (nephelinite) and 30 Ma (minette) as does the depth of melt generation inferred from xenolith mineralogy and major element geochemistry.

The three rock types present an enrichment of incompatible elements (although minettes present negative concentration spikes for Nb, Zr, Ti, Ba, Sr) relative to other magma types. The chondrite-normalized Ce/Yb ratio changes from 8–22 (basalt) to 25–30 (nephelinite) and 33–60 (minette) and reflects small degrees of partial melting of a mantle source with a garnet/clinopyroxene ratio increasing with depth. The negative Eu anomaly present in minette, the low Sr/Nd and high Pb/Ce suggest the presence of a recycled continental crust component in their mantle source.

The ⁸⁷Sr/⁸⁶Sr ratio varies from 0.7032-0.7045 (basalt and nephelinite) to 0.7052-0.7071 (minette), while ε_Nd is remarkably more constant at +0.8 to +3.7 (nephelinite) and −2.6 to +2.2 (basalt and minette). Good linear correlations are observed in both ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb diagrams with basalt being the least and nephelinite the most radiogenic and indicate a 2.3 ±0.1 Ga age and a Th/U of 3.4.

Three lithospheric source components are indicated: a) an OIB-type depleted mantle source, b) an end-member with unradiogenic Sr, Nd and Pb for basalt and nephelinite and c) a recycled crustal component for minette.     

Non-linear effects in internal-tide beams, and mixing

A non-linear non-hydrostatic model (MIT-gcm) is used to study the generation and propagation of internal tides. The model domain covers a continental slope and neighbouring parts of the deep ocean and shelf. Uniformity in the along-slope direction is assumed. We focus on the non-linear evolution of the internal tide once generated. In particular, we show that in the main region of generation, over the upper part of the slope, small-scale features occur, indicative of breaking and mixing. Far from the generation region, non-linear processes are important in the reflection of the beam at the bottom, where higher harmonics are generated. This implies an energy transfer toward higher frequencies and the resulting shape of the energy spectra is consistent with observations. Turbulent and mixing processes are analysed by employing an adiabatic sorting method; thus, we calculate the development in time of the available potential energy, the variation in the background potential energy due to irreversible processes, and the distribution of the Cox number (the local turbulent diffusivity normalized by the background diffusivity) over the slope. With rotation, the transfer of energy to higher harmonics is reduced.     

Comparison of C and N stable isotope ratios between surface particulate organic matter and microphytoplankton in the Gulf of Lions (NW Mediterranean)

Carbon and nitrogen stable isotope ratios of particulate organic matter (POM) in surface water and 63–200 μm-sized microphytoplankton collected at the fluorescence maximum were studied in four sites in the Gulf of Lions (NW Mediterranean), a marine area influenced by the Rhone River inputs, in May and November 2004. Some environmental (temperature, salinity) and biological (POM, Chlorophyll a and phaeopigments contents, phytoplankton biomass and composition) parameters were also analysed. Significantly different C and N isotopic signatures between surface water POM and microphytoplankton were recorded in all sites and seasons. Surface water POM presented systematically lower δ¹³C (∼4.2‰) and higher δ¹⁵N (∼2.8‰) values than those of microphytoplankton, due to a higher content of continental and detrital material. Seasonal variations were observed for all environmental and biological parameters, except salinity. Water temperature was lower in May than in November, the fluorescence maximum was located deeper and the Chlorophyll a content and the phytoplankton biomass were higher, along with low PON/Chl a ratio, corresponding to spring bloom conditions. At all sites and seasons, diatoms dominated the phytoplankton community in abundance, whereas dinoflagellate importance increased in autumn particularly in coastal sites. C and N isotopic signatures of phytoplankton did not vary with season. However, the δ¹⁵N of surface water POM was significantly higher in November than in May in all sites likely in relation to an increase in ¹⁵N/¹⁴N ratio of the Rhone River POM which influenced surface water in the Gulf of Lions. As it is important to determine true baseline values of primary producers for analysing marine food webs, this study demonstrated that C and N isotopic values of surface water POM cannot be used as phytoplankton proxy in coastal areas submitted to high river inputs.     

Characterization of Oscillatory Motions in the Stable Atmosphere of a Deep Valley

In a valley sheltered from strong synoptic effects, the dynamics of the valley atmosphere at night is dominated by katabatic winds. In a stably stratified atmosphere, these winds undergo temporal oscillations, whose frequency is given by $N \sin {\alpha }$ N sin α for an infinitely long slope of constant slope angle $\alpha $ α , $N$ N being the buoyancy frequency. Such an unsteady flow in a stably stratified atmosphere may also generate internal gravity waves (IGWs). The numerical study by Chemel et al. (Meteorol Atmos Phys 203:187–194, 2009) showed that, in the stable atmosphere of a deep valley, the oscillatory motions associated with the IGWs generated by katabatic winds are distinct from those of the katabatic winds. The IGW frequency was found to be independent of $\alpha $ α and about $0.8N$ 0.8 N . Their study did not consider the effects of the background stratification and valley geometry on these results. The present work extends this study by investigating those effects for a wide range of stratifications and slope angles, through numerical simulations for a deep valley. The two oscillatory systems are reproduced in the simulations. The frequency of the oscillations of the katabatic winds is found to be equal to $N$ N times the sine of the maximum slope angle. Remarkably, the IGW frequency is found to also vary as $C_\mathrm{w}N$ C w N , with $C_\mathrm{w}$ C w in the range $0.7$ 0.7 – $0.95$ 0.95 . These values for $C_\mathrm{w}$ C w are similar to those reported for IGWs radiated by any turbulent field with no dominant frequency component. Results suggest that the IGW wavelength is controlled by the valley depth.     

Effect of climate change and increased atmospheric CO2 on hydrological and nitrogen cycling in an intensive agricultural headwater catchment in western France

Climate change and increased atmospheric CO₂ concentration can impact hydrological and nitrogen cycling at the catchment scale. The objective of this study is to assess these impacts in an intensive agricultural headwater catchment in western France. A calibrated and validated agro-hydrological model was driven by output of the climate model ARPEGE under the A1B emission scenario over 30-year simulation periods. Our study indicated that with climate warming and increased atmospheric CO₂, the main trends in water balance were a decrease in annual actual evapotranspiration (AET), a decrease in annual discharge and wetland extent, and a decrease in spring and summer of groundwater recharge and soil-water content. Not considering the effects of increased atmospheric CO₂ in the agro-hydrological model led to overestimating discharge decrease and underestimating AET decrease and wetland extent. Climate change could influence N cycling by increasing soil N mineralisation, increasing soil denitrification in wetlands and upstream areas, and decreasing NO₃–N load to streams. Since wetlands appear to be sensitive to climate change, improving modelling to better predict their responses is an important issue, especially to help plan sustainable management of these vulnerable areas.     

Distinct export dynamics for dissolved and particulate phosphorus reveal independent transport mechanisms in an arable headwater catchment

This paper investigates particulate phosphorus (PP) and soluble reactive phosphorus (SRP) concentrations at the outlet of a small (5 km²) intensively farmed catchment to identify seasonal variability of sources and transport pathways for these two phosphorus forms. The shape and direction of discharge‐concentration hystereses during floods were related to the hydrological conditions in the catchment during four hydrological periods. Both during flood events and on an annual basis, contrasting export dynamics highlighted a strong decoupling between SRP and PP export. During most flood events, discharge‐concentration hystereses for PP were clockwise, indicating mobilization of a source located within or near the stream channel. Seasonal variability of PP export was linked to the availability of stream sediments and the export capacity of the stream. In contrast, hysteresis shapes for SRP were anticlockwise, which suggests that SRP was transferred to the stream via subsurface flow. Groundwater rise in wetland soils was likely the cause of this transfer, through the hydrological connectivity it created between the stream and P‐rich soil horizons. SRP concentrations were the highest when the relative contribution of deep groundwater from the upland domain was low compared with wetland groundwater. Hence, soils from non‐fertilized riparian wetlands seemed to be the main source of SRP in the catchment. This conceptual model of P transfer with distinct hydrological controls for PP and SRP was valid throughout the year, except during spring storm events, during which PP and SRP exports were synchronized as a consequence of overland flow and erosion on hillslopes. Copyright © 2015 John Wiley & Sons, Ltd.