上地幔超高压流体的金刚石压砧实验研究

地球深部流体主要是NaCl-H2O溶液,越到地球深部,它赋存的温度、压力越高,性质状态也不断变化,反之,亦然。当NaCl-H2O流体进入和脱离(上升过程)超临界状态时,其性质会发生截然不同的变化,影响着各种地质过程。使用金刚石压砧在高温高压下原位观测流体的实验,用谱学方法,结合同步辐射光源技术,成为定量化研究地球深部高温超高压流体的有效方法。作者使用同步辐射光源的红外谱研究了10GPa下的NaCl-H2O溶液;在地球化学动力学实验室研究了3GPa,650℃下的NaCl-H2O溶液红外谱,此测量方法可以提供温度压力和体积等数据,能研究其状态。NaCl-H2O溶液红外谱表明水分子主要振动谱受压力和温度影响是不同的。压力增加促使水分子主要振动谱向低波数变化。但是温度增加的效应相反。常温高压下水被压缩,结晶向紧密堆积变化。高温高压下的水有气、液、固和超临界流体各相。水分子间的氢键在近临界态开始减弱,氢键网络被破坏。     

新疆西昆仑科库西里克铅锌矿床地质及元素地球化学特征

新疆西昆仑地区科库西里克铅锌矿床赋存于中元古界长城系大理岩层间断裂带内.本文阐述了该矿床区域地质和地球化学背景,矿体特征及矿石成分,微量元素及稀土元素变化特点,并与区内密西西比型塔木—卡兰古铅锌矿床进行了比较.研究表明,科库西里克铅锌矿床矿体围岩—大理岩微量元素和稀土元素含量高于矿石,Rb、Th明显富集,Ce略富集,Ti亏损;矿石微量元素含量变化较大,Rb正异常明显,Ba、Nb、Zr、Ti负异常,既继承了围岩特征,又保留了成矿热液的成分特点.而塔木—卡兰古铅锌矿床的矿石与围岩的元素地球化学特征一致.据此认为科库西里克铅锌矿床成矿作用受中元古界长城系大理岩和断裂构造控制,成矿过程中有岩浆热液的加入.     

湖南骑田岭芙蓉矿田成岩成矿时代的厘定及其地质意义

通过对湖南骑田岭岩体芙蓉超单元南溪单元中粒斑状角闪石黑云母二长花岗岩、芙蓉矿田白腊水矿区的10号矿脉中蚀变花岗岩型锡矿石、19号矿脉中矽卡岩型矿石矿物、42号含矿花岗斑岩体和ZK801钻孔(80~90m)的细粒花岗岩的Rb-Sr、Sm-Nd和锆石SHRIMP U-Pb同位素年代学研究,分别获得南溪单元弱蚀变花岗岩全岩Rb-Sr等时线年龄为146±10Ma(95%可信度)和岩体锆石SHRIMP U-Pb年龄为155±6Ma(95%可信度),蚀变矿化花岗岩锆石SHRIMP U-Pb年龄为156±5Ma(95%可信度),10号蚀变花岗岩型矿脉矿石的Rb-Sr等时线年龄为137±5Ma(95%可信度),19号矽卡岩型矿脉的矿石—矿物Sm-Nd等时线年龄为133±15Ma(95%可信度);42号含矿花岗斑岩体锆石SHRIMP U-Pb年龄为146±5Ma(95%可信度);ZK801钻孔中细粒花岗岩全岩的Rb-Sr等时线年龄为140±7Ma(95%可信度)。上述精确的年代学研究结果表明,芙蓉超单元花岗岩侵位时间为燕山早期,而不是印支期。由此推测骑田岭芙蓉超单元花岗岩形成于早—中侏罗世,它的构造环境可能为地壳处于强烈剪切挤压晚期,而区内花岗斑岩和细粒花岗岩岩浆活动可能发生在140~145Ma之间,其构造环境可能为地壳由挤压剪切向拉张伸展转化的时期形成的;白腊水矿区不同类型矿床年代学研究结果(133~141Ma)清楚地表明,其成矿作用的时间与区内花岗斑岩和细粒花岗岩的岩浆活动时间有明显的耦合关系。据此推断,骑田岭芙蓉锡矿是在晚侏罗世,地壳由挤压剪切向拉张伸展转化的时期形成的。而与芙蓉花岗岩主体侵入岩浆活动无直接成生关系。     

四川会理大岩子铂钯矿的地质地球化学特征及找矿前景浅析

四川会理县大岩子铂钯矿床是目前国内品位最高的独立铂族元素矿床之一,也是一个独特的热液成因矿床。矿区及区域上的镁铁质岩浆岩可能是铂族元素的初始来源,震旦系白云岩是其有利的容矿围岩,构造控制下的热液活动促使了铂族元素的迁移富集。地表氧化带蓝铜矿化白云岩矿石的PGE含量最高可达27.13×10-6,坑道中相对新鲜橄辉岩的PGE含量为1.068×10-6,强烈蚀变橄辉岩含PGE0.528×10-6,地表蚀变后橄辉岩的PGE含量为0.435×10-6,表明铂族元素可能发生了活化转移。整个攀西地区基性超基性岩发育,后期构造活动强烈,有利的围岩广泛分布,因而具备形成热液型铂族元素矿床的条件,找矿前景看好。     

广西大厂锡矿田侵入岩SHRIMP锆石U-Pb年龄及其意义

应用高精度SHRIMP锆石U-Pb方法对广西大厂锡矿田不同类型中—酸性侵入岩进行了系统的定年研究,获得龙箱盖含斑黑云母花岗岩的成岩年龄为93±1Ma,斑状花岗岩91±1Ma,石英闪长玢岩脉(西岩墙)91±1Ma,花岗斑岩脉(东岩墙)91±1Ma,四者在测试误差范围内基本一致,微量元素特征及稀土配分模式相近,为同期不同阶段岩浆活动的产物。区内成岩与锡多金属成矿的时代相一致,均形成于板内伸展剪切的构造环境,应同属燕山晚期构造—热事件的产物。     

青城子小佟家堡子、林家金矿成矿流体特征及成矿机制

小佟家堡子、林家金矿是青城子铅锌、金、银矿集区的中-大型金矿床,金矿床与沉积-变质期硅化岩关系密切。通过与矿区尖山岩体、新岭岩体中流体包裹体对比研究表明,金矿床与尖山岩体中主要发育水溶液包裹体,极少量的CO2包裹体、含CO2三相包裹体,而新岭岩体除发育以上包裹体外,还发育含子矿物多相包裹体。测温结果显示金矿床成矿流体温度为110～335℃,盐度3．9％～16．2％NaClrq拉曼光谱分析表明金矿床流体成分以H2O为主,少量的CO2、CH4等气体,表明成矿流体属NaCl-H2O体系。金矿床与尖山岩体中流体包裹体温度、盐度及成分相近,推断成矿流体主要来自沉积-变质期。     

Water, organic matter, nitrogen and phosphorus contents in sediment of a large-scale mariculture area in the Zhelin Bay of eastern Guangdong Province, China

The Zhelin Bay is one of the most important bays for large-scale mariculture in Guangdong Province, China. Owing to the increasing human population and the expanding mariculture in the last two decades, the ecological environment has greatly changed with frequent harmful algal blooms. A monthly survey of water content, organic matter （TOM）, and various forms of nitrogen and phosphorous in sediment from July 2002 to July 2003 in the bay was conducted. The results showed that the water content was correlated significantly with TOM and various forms of nitrogen and phosphorus and can be used as proxy for quick and rough estimate of these factors in the future surveys. TOM was also correlated significantly with various forms of nitrogen and phosphorus, indicating that it was one of the key factors affecting the concentrations and distributions of nitrogen and phosphorus in the investigated waters. Average total Kjeldhal nitrogen （TkN） content was（ 1 113.1 ± 382.5）μg/g and average total phosphorus （TP） content was（567.2± 223.3）μg/g, and both were much higher than those of similar estuaries in China and elsewhere. Average nitrogen and phosphorus tended to be higher inside than outside the bay, higher at aquaculture than non-aquaculture areas, and higher at fish-cage culture than oyster culture areas, suggesting that large-scale mariculture inside the bay played an important role in the eutrophication of the Zhelin Bay. Various forms of nitrogen and phosphorus concentrations were higher during the warm season （July--September）, which was due to the increased decomposition and concentration of organic matter resulted from the fast growth and high mortality of the cultured species. Compared with July 2002, TkN and TP contents were much higher in July 2003, in consonance with the eutrophication of the Zhelin Bay. Because exchangeable phosphorus （Ex-P）, iron-bounded phos- phorus （Fe-P） and organic phosphorus （OP） combined accounted for 34.3% of the TP and authigenic phosphorus （Au-P     

Causes of rockfalls in Al-Huwayshah area,Yemen

According to topography of Yemen,most areas and villages are located at obligated crest,toe of mountain and under cliffs.Therefore Al-Huwayshah consisting of Tawilah sandstone group is characterized by steep slope reach to 90° in some areas.This area is affected by strong tectonic movements and faults that occurred during the geological epochs.This effect enhances to find out fractures and joints as well as the rocks become brittle and ready to slide depending on the position of area.And there are some frac...     

Extending self-organizing maps for supervised classification of remotely sensed data

An extended self-organizing map for supervised classification is proposed in this paper. Unlike other traditional SOMs, the model has an input layer, a Kohonen layer, and an output layer. The number of neurons in the input layer depends on the dimensionality of input patterns. The number of neurons in the output layer equals the number of the desired classes. The number of neurons in the Kohonen layer may be a few to several thousands, which depends on the complexity of classification problems and the classification precision. Each training sample is expressed by a pair of vectors ： an input vector and a class codebook vector. When a training sample is input into the model, Kohonen＇s competitive learning rule is applied to selecting the winning neuron from the Kohouen layer and the weight coefficients connecting all the neurons in the input layer with both the winning neuron and its neighbors in the Kohonen layer are modified to be closer to the input vector, and those connecting all the neurons around the winning neuron within a certain diameter in the Kohonen layer with all the neurons in the output layer are adjusted to be closer to the class codebook vector. If the number of training sam- ples is sufficiently large and the learning epochs iterate enough times, the model will be able to serve as a supervised classifier. The model has been tentatively applied to the supervised classification of multispectral remotely sensed data. The author compared the performances of the extended SOM and BPN in remotely sensed data classification. The investigation manifests that the extended SOM is feasible for supervised classification.     

Characteristics and evolution of lacustrine turbidite of Chang-7 Member of Yanchang Formation in northern Shaanxi

Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.