苏门答腊中部Panti早始新世S型花岗岩地球化学特征及其新特提斯构造意义

苏门答腊地处特提斯构造域与印度洋岛弧系统之内,区内广泛发育中-新生代火成岩.这些火成岩对特提斯构造带的延伸及界定具有重要意义,但目前对于苏门答腊岛的研究程度较低.本文选取苏门答腊岛中部Panti地区的花岗岩进行了岩相学、锆石年代学、锆石原位Hf同位素和全岩地球化学研究.年代学研究表明,Panti花岗岩锆石U-Pb年龄为...     

Simultaneous stabilization of arsenic, lead, and copper in contaminated soil using mixed waste resources

In the present study, stabilization treatment using waste resource stabilizers was performed for soil contaminated with As and heavy metals (Pb and Cu). Calcined oyster shell (COS) and coal mine drainage sludge (CMDS) were used as a mixed stabilizing agent for a wet-curing duration of 28 days. After the stabilization treatment, the treatment process efficiency was evaluated by the results of various batch- and column-leaching tests. Neutral and weak acid extraction methods, such as water-soluble extraction and SPLP, did not exhibit satisfactory results for heavy metal stabilization, even if they showed very low leachability. On the other hand, TCLP and 0.1 M HCl extraction showed that the stabilizers significantly reduced the amount of heavy metals leached from the soil, which strongly supports the thesis that the stabilization treatment is efficient in the acidic leaching conditions that were explored. Specifically, in the 0.1 M HCl extraction, the reduction efficiencies of As, Pb, and Cu leachings were more than 90 %, compared with control experiments. This study demonstrates that the application of waste resources for the stabilization of As and heavy metals is feasible. However, some limitations observed in the experiments should be considered in future studies, such as the mobilization of alkali-soluble elements, and in particular, exchangeable fractions of Cu. In addition, the treatment efficiency can be evaluated by different leaching methods, which suggests that multidirectional approaches are required for the proper evaluation of stabilization treatment.     

Holocene palaeoflood events recorded by slackwater deposits along the lower Jinghe River valley,middle Yellow River basin,China

Palaeoflood slackwater deposits (SWDs), are the natural record of overbank flooding and are often found within aeolian loess‐soil profiles along the river valleys of the middle Yellow River basin. These pedo‐stratigraphic sequences are studied using a multi‐disciplinarily approach to reconstruct Holocene hydro‐climatic variations. Our field investigations along the lower Jinghe River valley have identified palaeoflood SWDs at several sites along the riverbanks based on sedimentological criteria. Analytical results, including magnetic susceptibility, particle‐size distribution and concentrations of chemical elements, indicate that these well‐sorted palaeoflood SWD beds were deposited from the suspended sediment load in floodwaters. We identify two episodes of extraordinary palaeoflood events along the Jinghe River valley. These hydro‐climatic events were dated to 4200–4000 and 3200–2800 a BP, by using the optically stimulated luminescence method in combination with archaeological dating of retrieved anthropogenic remains, and with pedo‐stratigraphic correlations with the previously studied Holocene pedo‐stratigraphy in the Jinghe River drainage basin. The flooding events are therefore considered to be a regional expression of known climatic events in the northern hemisphere and demonstrate Holocene climate was far from stable. This study provides important data in understanding the interactions between regional hydro‐climatic systems and global change in semi‐arid and sub‐humid regions. Copyright © 2012 John Wiley & Sons, Ltd.     

New evidence on the Neogene uplift of South Tianshan: constraints from the (U–Th)/He and AFT ages of borehole samples of the Tarim basin and implications for hydrocarbon generation

We identified a Neogene rapid uplift-denudation event of the South Tianshan based on apatite (U–Th)/He and apatite fission track (AFT) ages in Tertiary rocks of the Tarim basin, using borehole samples. The (U–Th)/He thermochronology can be used to reveal the tectono-thermal events with lower temperature than that of AFT thermochronology and has not been used previously to study the uplift of the Tianshan Mountain. Using these data, we show the relationship between the uplift of the South Tianshan and the subsidence/deposition of the northern Tarim basin during the Neogene. The apatite helium ages reveal the migration of uplift, erosion and deposition in the northern Tarim basin. A rapid uplift of the South Tianshan during the Miocene and a corresponding rapid subsidence in the northern Tarim basin occurred. However, in the Pliocene, the Kuqa Depression and South Tianshan uplifted and eroded at the same time and in turn provided the detrital source rocks for the Northern Uplift of the Tarim basin. In contrast to earlier studies, we arrive at the conclusion that the South Tianshan experienced rapid uplift in the Miocene based on (U–Th)/He data of apatite obtained from borehole samples collected in the Tarim basin itself, and not from the bordering mountain chain. Combined apatite (U–Th)/He and fission track thermochronometry enables reconstruction of thermal histories of sedimentary rocks between 40 and 120°C, and this has implications for the generation of liquid hydrocarbon in the 65–120°C range in the basin. Thermal and burial histories of typical samples were also modelled to show the rapid uplift in our study. Our works not only provide a new evidence for the South Tianshan uplift but also indicate that there is a coupling between uplift and subsidence in the South Tianshan and adjacent northern part of the Tarim basin, which controlled hydrocarbon accumulation in the Kuqa Depression and Northern Uplift of the Tarim basin.     

油气双相介质理论在辽西凹陷南部岩性圈闭中的应用

辽河西部凹陷是辽河拗陷主要的生油凹陷.随着勘探程度的提高,勘探难度不断增大,近年来对辽西凹陷鸳鸯沟和清水洼陷坡折带以下的岩性油气藏勘探需求日益旺盛.通过双相介质油气勘探方法,利用小波变化时频分析特性,提取地震波能量和频率成分,对工作区内探井频谱特征进行了样本学习,总结出了区内高产井和无油井的频谱特征,预测出勘探风险区域的油气富集程度,再结合地球物理反演技术,明确了下一步岩性圈闭的勘探潜力区域,以降低勘探风险.     

Early Estimation of Seismic Hazard for Strong Earthquakes in Taiwan

A shakemap system providing rapid estimates of strong ground shaking could be useful for emergency response providers in a damaging earthquake. A hybrid procedure, which combines site-dependent ground motion prediction models and the limited observations of the Real-Time Digital stream output system (RTD system operated by Central Weather Bureau, CWB), was set up to provide a high-resolution shakemap in a near-real-time manner after damaging earthquakes in Taiwan. One of the main factors that affect the result of ground motion prediction analysis is the existence of site effects. The purpose of this paper is to investigate the local site effects and their influence in the ground shaking and then establish an early estimation procedure of potential hazard for damaging earthquakes. Based on the attenuation law, the site effects of each TSMIP station are discussed in terms of a bias function that is site and intensity-level dependent function. The standard deviation of the site-dependent ground motion prediction model can be significantly reduced. The nonlinear behavior of ground soil is automatically taken into account in the intensity-level dependent bias function. Both the PGA and the spectral acceleration are studied in this study. Based on the RTD data, event correctors are calculated and applied to precisely estimate the shakemap of damaging earthquakes for emergency response.     

Improvement of saponification extraction method for fatty acids separation from geological samples

The conventional saponification method could result in lower recoveries and artificial changes of long-chain fatty acids. The main reason is the error judgment of the intermediate layer suspended between the aqueous and organic layer during the liquid–liquid extraction process. This study shows that the intermediate layer consists of lots of medium- to long-chain carboxylic salts for their special physical and chemical properties. An improved saponification extraction method is also developed and the results show that the carboxylic salts distributed in the intermediate layer could be obtained completely, which greatly enhances the authenticity and accuracy of fatty acid analysis. Additionally, the possible reasons of formation of the intermediate layer are also discussed.     

Primary melt from Sannome-gata volcano,NE Japan arc: constraints on generation conditions of rear-arc magmas

The conditions under which rear-arc magmas are generated were estimated using primary basalts from the Sannome-gata volcano, located in the rear of the NE Japan arc. Scoriae from the volcano occur with abundant crustal and mantle xenoliths, suggesting that the magma ascended rapidly from the upper mantle. The scoriae show significant variations in their whole-rock compositions (7.9–11.1 wt% MgO). High-MgO scoriae (MgO > ~9.5 wt%) have mostly homogeneous ⁸⁷Sr/⁸⁶Sr ratios (0.70318–0.70320), whereas low-MgO scoriae (MgO < ~9 wt%) have higher ⁸⁷Sr/⁸⁶Sr ratios (>0.70327); ratios tend to increase with decreasing MgO content. The high-MgO scoriae are aphyric, containing ~5 vol% olivine microphenocrysts with Mg# [100 × Mg/(Mg + Fe²⁺)] of up to 90. In contrast, the low-MgO scoriae have crustal xenocrysts of plagioclase, alkali feldspar, and quartz, and the mineralogic modes correlate negatively with whole-rock MgO content. On the basis of these observations, it is inferred that the high-MgO scoriae represent primary or near-primary melts, while the low-MgO scoriae underwent considerable interaction with the crust. Using thermodynamic analysis of the observed petrological features of the high-MgO scoriae, the eruption temperature of the magmas was constrained to 1,160–1,220 °C. Given that the source mantle was depleted MORB-source mantle, the primary magma was plausibly generated by ~7 % melting of a garnet-bearing spinel peridotite; taking this into consideration, and considering the constraints of multi-component thermodynamics, we estimated that the primary Sannome-gata magma was generated in the source mantle with 0.5–0.6 wt% H₂O at 1,220–1,230 °C and at ~1.8 GPa, and that the H₂O content of the primary magma was 6–7 wt%. The rear-arc Sannome-gata magma was generated by a lower degree of melting of the mantle at greater depths and lower temperatures than the frontal-arc magma from the Iwate volcano, which was also estimated to be generated by ~15 % melting of the source mantle with 0.6–0.7 wt% H₂O at ~1,250 °C and at ~1.3 GPa.