The origin of Neogene tectonic rotations in the Galatean volcanic massif, central Anatolia

A paleomagnetic study was carried out on Neogene volcanic rocks at 30 sites within the Galatean massif (40.4°N, 31.5°E) to determine possible block rotations due to stress variations. Two phases of rotation could be characterized as the result of Neogene volcanic activity. We suggest that the first stage of rotation was isolated in Early Middle Miocene calc-alkali rocks, with a relative counterclockwise rotation of R ± ΔR = −20.2 ± 9.3° with respect to Eurasia. This accommodates the south-westward rotational collapse of the Western Anatolia peninsula across a pole on the Bitlis suture. In the neotectonic period, on other hand, a relative clockwise rotation of R ± ΔR = 27.3 ± 6.4° with respect to Eurasia is predicted. In contrast to the uniform clockwise rotations, extremely large clockwise rotations up to 264° are restricted in a narrow zone between two dextral faults. We believe that the second stage rotations support the idea of individual microblock rotations due to deformation along the North Anatolian Fault zone.     

A higher order continuum model for the dynamic shear behaviour of multi-storey frames

A continuum model is developed to predict the response of multi-storey frames to dynamic excitations. The equations of the proposed theory are derived in a systematic manner using smoothing operations. The order of the theory is kept arbitrary. To appraise the validity of the theory natural frequencies and vibration shapes predicted by discrete and continuum models are compared. This comparison provides valuable information about goodness of the proposed model because natural frequencies and vibration shapes represent spectral structure of the theory. The most crucial finding obtained from the analysis is that, as an implication of the smoothing operations used in the derivation of the theory, one should define an effective height which is equal to the height of the frame plus half of the height of the top storey. The numerical results indicated that the use of effective height in the analysis improves the prediction of the theory considerably. It is found also that the number of modes the continuum model can describe correctly increases with the number of storeys and that the lowest number of storeys for which the theory can be used is three. Further, it is observed that an increase in the order of the theory improves greatly its prediction and that in the presence of non-uniform distributions of frame properties, such as, of mass, stiffness, etc., the theory still remains valid.     

Paleomagnetic results from Northeast Anatolia: remagnetization in Late Cretaceous sandstones and tectonic rotation at the Eastern extension of the Izmir–Ankara–Erzincan suture zone

Paleomagnetic results obtained from Upper Cretaceous sandstones in Northeastern Anatolia demonstrate that the entire area from Erzincan to Kars has been remagnetised. The remagnetisation was acquired before the Middle Eocene collision between the Eastern Pontides and the Arabian Platform because Middle Eocene sandstones carry primary natural remanent magnetisations. The post-folding in situ mean direction of the Upper Cretaceous sandstones is compared with mean directions of younger, Middle Eocene to present rock formations. As a result, a two-stage antagonistic rotation mechanism is proposed. First, the collision between the Pontides and the Taurides between Late Cretaceous and Middle Eocene was associated by clockwise rotation of  ~ 26°. In the second stage between Middle Eocene and Middle Miocene and beyond, counterclockwise rotations up to ~ 52° of the Pontide and Anatolide blocks and clockwise rotations of the Van Block were characterised by regional shortening and westward escape.     

The Relationship of Urban Expansion,Landscape Patterns and Ecological Processes in Denizli,Turkey

Perforation, dissection, fragmentation, shrinkage and attrition in ecosystems take place due to urbanization. In this study, where and when temporal and spatial heterogeneity occurs is tried to be explained by taking human intervention in landscape pattern and processes in and around the city of Denizli into account and how this heterogeneity affects habitat conditions within the scope of landscape ecology. Landscape pattern metrics were estimated in order to reveal the change in habitats and present the properties of the landscape. 30 pattern indicators on class and pattern levels, which are important to show human–environment interaction, were analyzed in order to indicate the features of the landscape such as area, side, shape and dispersion. To this end, LANDSAT TM/7–ETM/8-OLI satellite images of 1987 and 2013 were classified for laying the foundations of the analysis. Analyses showed that between 1987 and 2013, complicated shape features, increase in edge habitats, de-growth in core areas and eventually fragmentation in landscape have been dominant. Heterogenic structure in landscape has increased. This points not to the self-functioning of the landscape, but to the domination of human intervention over the landscape. Particularly, due to urban growth and sprawl, fragmentation, isolation and habitat loss in croplands have increased. This study sets forth the usefulness of remote sensing, GIS and landscape metrics in understanding how urban dynamics and ecosystems change in developing urban politics.     

Novel Polymeric Resin for Solid Phase Extraction and Determination of Lead in Waters

Interest in preconcentration techniques for the determination of metals at ultratrace levels still continues increasingly because of some disadvantages of flameless atomic absorption spectrometry and the high costs of other sensitive methods in compared to flame atomic absorption spectrometry (FAAS). Among preconcentration techniques, solid‐phase extraction is the most popular because of a number of advantages. In this work, thiol‐containing sulfonamide resin was synthesized, characterized, and applied as a new sorption material for solid phase extraction and determination of lead in natural water samples. The optimization of experimental conditions was performed using the parameters including pH, contact time, and volumes of initial and elution solutions. After preconcentration procedure, FAAS was used for determinations. The synthesized resin exhibits the superiority in compared to the other adsorption reagents because of the fact that there is no necessity of any complexing reagent as well as high sorption capacity. Consequently, 280‐fold improvement in the sensitivity of analytical scheme was achieved by combining the slotted tube atom trap‐atomic absorption spectrometry (STAT‐FAAS) and the developed preconcentration method. The limit of detection was found to be 0.15 ng mL^?1. The Pb²⁺ concentrations in the studied water samples were found to be in the range of 0.9–6.7 ng mL^?1.     

Trace element contents and C-O isotope geochemistry of the different originated magnesite deposits in Lake District (Southwestern Anatolia), Turkey

Vein-stockwork magnesite in the Madenli area, sedimentary huntite-magnesite in the A?a??t?rtar area, and lacustrine hydromagnesite in the Salda Lake area are located in the Bey?ehir-Hoyran and Lycian nappe rocks around Isparta and Burdur, Southwest Anatolia. The aim of this study is to understand trace element contents and carbon-oxygen isotope ratios in different originated magnesite, magnesite bearing huntite, and hydromagnesite deposits. Also, the element contents and isotope ratios of the magnesite occurrences are to compare with each other and similar magnesite occurrences in Turkey and world. It is found that the Madenli magnesite occurrences in the ?arkikaraa?aç ophiolites, A?a??t?rtar magnesite bearing huntite deposits in the lacustrine rocks of the Miocene-Pliocene, and the Salda hydromagnesite deposits in lacustrine basin on the Ye?ilova ophiolites. The paragenesis contains a common carbonate mineral magnesite, less calcite, serpentine, smectite, dolomite, and talc in the Madenli magnesite occurrences, mostly huntite and locally magnesite, dolomite, calcite, illite, quartz, and smectite in the A?a??t?rtar huntite-magnesite occurrences, and only hydromagnesite mineral in the Salda Lake hydromagnesite occurrences. Vein and stockwork Madenli magnesite deposits were recognized by higher total iron oxide concentrations (mean 1.10 wt%) than sedimentary A?a??t?rtar magnesite bearing huntite (mean 0.13 wt%) and lacustrine Salda hydromagnesite (mean 0.22 wt%) deposits. It is suggested that high Fe content (up to 5%) in the magnesite associated with ultramafic rocks than those from sedimentary environments (≤1% Fe). Based on average Ni, Co, Ba, Sr, As and Zr contents in the magnesite deposits, average Ni (134.63 ppm) and Co (15.19 ppm) contents in the Madenli magnesite and Salda hydromagnesite (36.85 ppm for Ni, 3.15 ppm for Co) have higher values than A?a??t?rtar huntite + magnesite (7.67 ppm for Ni and 0.89 ppm for Co). Average Ni-Co contents of these deposits can have close values depending on ophiolite host rock. Average Ba values of the Madenli (108.09 ppm) and A?a??t?rtar (115.88 ppm) areas are higher than those of Salda hydromagnesite (13.15 ppm). Sediment-hosted A?a??t?rtar magnesite-huntite deposits have the highest Sr contents (mean 505.81 ppm) as reasonably different from ultrabasic rock-related Madenli magnesite (mean 38.76 ppm) and Salda hydromagnesite (mean 36.70 ppm). The highest Sr content of sedimentary A?a??t?rtar deposits reveals that Sr is related to carbonate rocks. As and Zr contents have the highest average values (As 52.76 ppm and Zr 9.67 ppm) in the A?a??t?rtar deposits different from Madenli magnesite (As 0.54 ppm and Zr 1.67 ppm) and Salda hydromagnesite (As 0.5 ppm and Zr 2.58 ppm) deposits. High As and Zr concentrations in the A?a??t?rtar magnesite-huntite deposits may come from volcanic rocks in near country rocks. The δ ¹³C (PDB) isotope values vary between ?10.1 and ?11.4‰ in the Madenli magnesite, 7.8 to 8.8‰ for huntite, 1.7 to 8.3‰ for huntite + magnesite and 4.0‰ for limestone + magnesite in the A?a??t?rtar huntite-magnesite deposits, and 4.4 to 4.9‰ for Salda Lake hydromagnesite. The sources of the CO₂ are hydrothermal solutions, meteoric waters, groundwater dissolved carbon released from fresh water carbonates and marine limestone, soil CO₂, and plant C3 in the Madenli magnesite, and may be deep seated metamorphic reactions in limestone and shales of rich in terms of organic matter. The sources of CO₂ in A?a??t?rtar huntite and Salda hydromagnesite were meteoric water, groundwater dissolved inorganic carbon, fresh water carbonates, and marine limestone. The δ ¹⁸O (SMOW) isotope composition ranges from 26.8 to 28.1‰ in the Madenli magnesite, 30.4 to 32.4‰ for huntite and 29.8 to 35.5‰ for huntite + magnesite and 26.9‰ for limestone + magnesite in the A?a??t?rtar area, and 36.4 to 38.2‰ in the Salda Lake hydromagnesite. The Salda Lake hydromagnesite has heavier oxygen isotopic values than others. The sources of oxygen in the Madenli magnesite deposits are hydrothermal solutions, meteoric water, freshwater carbonates, and marine limestone, but the sources of oxygen of the A?a??t?rtar magnesite-huntite are meteoric water, fresh water carbonates, and marine limestone. The Salda Lake hydromagnesite has very high δ¹⁸O isotope values indicating a strong evaporitic environment. Magnesium (Mg⁺²) and silica are released by disintegration of very weathered-serpentinized ultrabasic rocks of all magnesite deposits and from partly dolomite and dolomitic limestone in the A?a??t?rtar magnesite bearing huntite deposits. In the A?a??t?rtar area, calcium (Ca⁺²) for huntite mineralization is provided by surrounding carbonate rocks. Based on isotopic data, host rocks, petrographic properties of the Madenli magnesite can be described as an ultramafic-associated hydrothermal vein mineralization corresponding to “Kraubath type” deposits, but A?a??t?rtar ve Salda Lake deposits are sedimentary mineralization (lacustrine/evaporitic) corresponding to “Bela Stena type” deposits. The estimated temperature using average δ¹⁸O isotope values is about 33.51 °C for Madenli magnesite, 48.33 °C for A?a??t?rtar huntite-magnesite, and 25 °C for Salda hydromagnesite. Based on isotope data, we can be say that the Madenli magnesite, A?a??t?rtar magnesite-huntite, and Salda hydromagnesite occur at low to moderate-low temperature water and alkaline (pH 8.5–10.5) under surface or near-surface conditions.     

An assessment of environmental impacts of quarry-blasting operation: a case study in Istanbul, Turkey

This study evaluates the impacts resulting from quarry-blasting operation on nearby buildings and structures as it generates ground vibration, air blast, and fly rocks. In this paper, first blasting operation and its possible environmental effects are defined. Then the methods of blast-vibration prediction and commonly accepted criteria to prevent damage were introduced. A field experimental work was conducted to minimize the vibration effects at Saribayir quarry as it is an identical case for the many quarries situated in and around Istanbul, Turkey. Although the local surrounding geology and rock mechanics have great influence on vibrations as uncontrollable parameter, the charge weight per delay, delay period, geometric parameters of the blasts were changed to solve the existing vibration problem in the studied quarry. To obtain a realistic result, 10 blasts were carried out and 30 seismic records were made in different places mainly very close the buildings and the other vulnerable structures around the quarry. The evaluation is performed whether the vibration level are within safe limits or not. The prediction equation based on scaled distance concept is also determined, however, it is a site-specific model and need to be updated when the quarry advances. The safe blast parameters which minimize the environmental effect were determined for the Saribayir quarry.