Grain boundary diffusion in enstatite

We have investigated grain boundary diffusion rates in enstatite by heating single crystals of quartz packed in powdered San Carlos olivine (Mg_0.90Fe_0.10)₂SiO₄ at controlled oxygen fugacities in the range 10^?5.7 to 10^?8.7?atm and temperatures from 1350° to 1450?°C for times from 5 to 100?h at 1?atm total pressure. Following the experiments, the thickness of the coherent polycrystalline reaction rim of pyroxene that had formed between the quartz and olivine was measured using backscatter scanning imaging in the electron microprobe. Quantitative microprobe analysis indicated that the composition of this reaction phase is (Mg_0.92Fe_0.08)₂Si₂O₆. The rate of growth of the pyroxene increases with increasing temperature, is independent of the oxygen fugacity, and is consistent with a parabolic rate law, indicating that the growth rate is controlled by ionic diffusion through the pyroxene rim. Microstructural observations and platinum marker experiments suggest that the reaction phase is formed at the olivine-pyroxene interface, and is therefore controlled by the diffusion of silicon and oxygen. The parabolic rate constants determined from the experiments were analyzed in terms of the oxide activity gradient across the rim to yield mean effective diffusivities for the rate-limiting ionic species, assuming bulk transport through the pyroxene layer. These effective diffusivities are faster than the lattice diffusivities for the slowest species (silicon) calculated from creep experiments, but slower than measured lattice diffusivities for oxygen in enstatite. Thus, silicon grain boundary diffusion is most likely to be the rate-limiting process in the growth of the pyroxene rims. Also, as oxygen transport through the pyroxene rims must be faster than silicon transport, diffusion of oxygen along the grain boundaries must be faster than through the lattice. The grain boundary diffusivity for silicon in orthopyroxenite is then given by D¯gbSiδ=(3.3±3.0)×10^?9f0.0O₂e^?400±65/RT?m³s^?1, where the activation energy for diffusion is in kJ/mol, and δ is the grain boundary width in m. Calculated growth rates for enstatite under these conditions are significantly slower than predicted by an extrapolation from similar experiments performed at 1000?°C under high pressure (hydrous) conditions by Yund and Tullis (1992), perhaps due to water-enhancement of diffusion in their experiments.     

Historical Changes in the Flood Hazard at Khartoum, Sudan: Lessons and Warnings for the Future

The 1988 floods at Khartoum were frequently described as "unprecedented". However, an examination of evidence for floods caused by the Nile and rain storms during the nineteenth and twentieth centuries leads to the conclusion that neither the Nile flood nor the rain storms nor their coincidence in one season were unprecedented and that similar situations will recur.We argue that most problems were created by complacency, lack of planning and mismanagement. We conclude with some simple suggestions for flood amelioration in the future and warn that complacency is the single most important phenomenon likely to recur to the detriment of Greater Khartoum in the future.     

PHOTOGRAMMETRIC DATA CAPTURE: AN INEXPENSIVE ALTERNATIVE

A case is made for the development of an inexpensive and portable data capturing unit which could be used with existing mirror stereoscopes and which could provide an accuracy sufficient for most digital map databases. The results of simulation experiments to test the accuracy of the system are presented.     

A techno-economic comparison of power systems for autonomousunderwater vehicles

This paper compares lead-acid batteries, sodium-sulfur batteries, solid polymer fuel cells and closed-cycle diesel engines for autonomous underwater vehicle (AUV) applications. The service is described in terms of a parametric mission and life cycle. A generic AUV is used as a basis for comparison. Power systems are evaluated by two criteria: (1) submerged endurance capability and (2) life cycle cost. This study determines categories of service for which each power system is preferred. The solid polymer fuel cell can provide greater submerged endurance than other power systems examined. For extremely long duration AUV missions, the fuel cell is the required system, indicating a possible market niche for today's fuel cell technology. Considering cost projections for each power system, the results also show that the SPFC can become cost-competitive with conventional technologies, particularly for services characterized by high levels of utilization     

Metamorphic evolution of exhumed middle to lower crustal rocks in the Mojave Extensional Belt, southern California, USA

The Waterman Metamorphic Complex of the central Mojave Desert was exposed as a consequence of early Miocene detachment-dominated extension. However, it has evidence consistent with a more extensive geological history that involves collision of a crustal fragment(s), tectonic thickening by overthrusting and two periods of extension. The metamorphic complex contains granitoid intrusives and felsic mylonitic gneisses as well as polymetamorphic rocks that include marble, calc-silicate, quartzite. mafic granulite, pyribolite, amphibolite, migmatite and biotite schist. The latter group of rocks was affected by an initial series of high-grade metamorphic events (M1 and M2) and a localized lower grade overprint (M3). The initial metamorphism (M1) can be separated into two stages along its high-grade P–T path: M1a, a granulite facies metamorphism at 800–850° C and 7.5–9 kbar and Mlb, an upper amphibolite facies overprint at 750–800° C and 10–12 kbar. M1a developed mineral assemblages and textures consistent with granulite facies conditions at a reduced activity of H₂O and is associated with intense ductile deformation (D1) and minor local partial melting. M1b overprinted the granulite assemblages with a series of hydrous phases under conditions of increasing pressure and H₂O activity and is accompanied by little or no deformation. M2 developed at lower pressures and temperatures (650–750° C, 4.5–5.5 kbar) and is distinguished by a second local overprint of hydrous phases that reflects an input of aqueous fluids probably associated with the intrusion of a series of granitic dykes and veins. Effects of M3 are confined to the Mitchel detachment zone, an anastomosing early Miocene detachment fault, and are characterized by local ductile/brittle deformation (D2) of the pre-existing high-grade rocks and granitoid intrusives and by the production of mylonites and mylonitic gneisses under greenschist facies conditions (300–350° C, 3–5 kbar). The initial overprint (M1a) represents metamorphism, devolatilization and minor partial melting of supracrustal rocks under granulite facies conditions as a consequence of tectonic and, possibly, magmatic thickening. The increasing pressure transition of M1a to M1b reflects a period of continued compressional tectonism, thrusting and influx of H₂O, in part, locally related to crystallization of partial melts. The near isothermal decompression between M1b and M2 probably represents a pre-112-Ma extensional episode that may have been the result of a decompressional readjustment of a thickened crust. Following the initial extensional event, the metamorphic complex remained at depths of 10–17 km for at least 90 Ma until it was uplifted following Miocene extension. M3 develops locally in response to this second extensional period resulting from the early Miocene detachment faulting.     

Recurrent Red-tides in the Southampton Water Estuary Caused by the Phototrophic CiliateMesodinium rubrum

In the Southampton Water estuary (southern England, U.K.), red-tides caused by the planktonic, phototrophic ciliateMesodinium rubrum(=Myrionecta rubra) occur during most summers and sometimes in autumn. These events were investigated in detail between 1985 and 1987 and were characterized by levels of chlorophylla(chl a) of over 100 μg l⁻¹, cell numbers ofM. rubrumof over 1×10³ ml⁻¹, oxygen saturations of around 150%, and depleted numbers of macrozooplankton. Initiation of red-water did not appear to be triggered by irradiance or nutrients, but coincided with an increase in temperature and water column stability. This enhanced stability was promoted by increased surface to bottom gradients of both temperature and salinity, and by reduced mixing during neap tides. Development of red-water was accompanied by removal of most of the dissolved NH⁺₄from the water column, whereas some NO⁻₃persisted, presumably maintained by freshwater input. NO⁻₃and NH⁺₄gradually returned to pre-bloom concentrations as the red-water declined in late summer. Maximal biomass ofM. rubrumappeared to be limited by irradiance, and self-shading probably imposed an upper limit of around 300 mg chl a m⁻²within the water column. At the observed levels of chl a, irradiance values within the population maximum between 1 and 3 m depth were only just of the order (≈15 μmol photons m⁻² s⁻¹) required to balance estimated respiratory demands. Oxygen concentration became undersaturated during the late bloom phase, with minimal values of 20–30% saturation recorded in deeper waters; however, despite this and reduced numbers of macrozooplankton, direct deleterious effects on other organisms were not observed.     

The β Cephei instability strip

We carried out a series of linear stability analyses of the radial and low-degree non-radial p modes for stellar models with initial masses of     . The stellar models were computed by using convective overshoot distance     , 0.25 and 0.40  H _P. Our numerical results show that the β Cephei instability strip forms a horn-shaped region pointing upwards near the main sequence on the Hertzsprung–Russell diagram (HRD). The lower part of the instability strip for the radial modes join the zero-age main-sequence (ZAMS) at     , while the top of the instability strip extends up to     . The instability strip for the non-radial modes is even wider. The overall instability strip is dominated by the radial and non-radial fundamental modes. The first overtone (the radial-order index     is also pulsationally unstable. We have shown that the β Cephei stability is almost independent of the overshoot parameter d _over used for the stellar models, while it depends critically on the metal abundance. With decreasing metal abundance, the instability region shrinks and eventually disappears for     .     

Brightness Variation and Proper Motions of Three Objects in the Cygnus Region

The results of an investigation of three peculiar objects in the Cygnus region are given. One of them was already known to be a Herbig-Haro object. In accordance with its observational characteristics, the second object is, in all probability, a T Tauri star. The physical character of the last object is not yet entirely clear, but from the properties of its emission in the near infrared range it is probably also a T Tauri star. The proper motions of the objects have been measured. It is shown that all three objects are members of a tight system of the Trapezium type and evidently are the results of the successive fragmentation of an original protostellar body.     

Nature of microstructure in pulsar radio emission

We present a model for microstructure in pulsar radio emission. We propose that micropulses result from alteration of the radio wave generation region by nearly transverse drift waves propagating across the pulsar magnetic field and encircling the bundle of the open magnetic field lines. It is demonstrated that such waves can modify the curvature of the field lines significantly. This, in turn, affects strongly fulfilment of the resonance conditions necessary for the excitation of radio waves. The time-scale of micropulses is therefore determined by the wavelength of the drift waves. The main features of the microstructure are naturally explained within the framework of this model.     

The mass of the white dwarf in the recurrent nova U Scorpii

We present spectroscopy of the eclipsing recurrent nova U Sco. The radial velocity semi-amplitude of the primary star was found to be     from the motion of the wings of the He  ii λ 4686-Å emission line. By detecting weak absorption features from the secondary star, we find its radial velocity semi-amplitude to be     . From these parameters, we obtain a mass of     for the white dwarf primary star and a mass of     for the secondary star. The radius of the secondary is calculated to be     , confirming that it is evolved. The inclination of the system is calculated to be     , consistent with the deep eclipse seen in the light-curves. The helium emission lines are double-peaked, with the blueshifted regions of the disc being eclipsed prior to the redshifted regions, clearly indicating the presence of an accretion disc. The high mass of the white dwarf is consistent with the thermonuclear runaway model of recurrent nova outbursts, and confirms that U Sco is the best Type Ia supernova progenitor currently known. We predict that U Sco is likely to explode within ∼700 000 yr.