Spatial characterization of the location of potentially leaky wells penetrating a deep saline aquifer in a mature sedimentary basin

This work was motivated by considerations of potential leakage pathways for CO₂ injected into deep geological formations for the purpose of carbon sequestration. Because existing wells represent a potentially important leakage pathway, a spatial analysis of wells that penetrate a deep aquifer in the Alberta Basin was performed and various statistical measures to quantify the spatial distribution of these wells were presented. The data indicate spatial clustering of wells, due to oil and gas production activities. The data also indicate that the number of wells that could be impacted by CO₂ injection, as defined by the spread of an injected CO₂ plume, varies from several hundred in high well-density areas to about 20 in low-density areas. These results may be applied to other mature continental sedimentary basins in North America and elsewhere, where detailed information on well location and status may not be available.     

Single Column Sequential Extraction of Ra,Nd, Th,Pa and U from a Natural Sample

A new procedure allowing the sequential extraction of Ra, Nd, Th, Pa and U from the same initial natural sample (sea or river waters, particles, sediments, rocks) is proposed. Extraction recoveries were better than 90%. Procedural blanks ranged from 80 pg (for Nd) to below 1 fg, the detection limit of the MC‐ICP‐MS used (for Pa); all were negligible compared with the amounts of elements currently determined. Based on classical anionic resins attached to a peristaltic pump allowing precise flow rate control, this procedure allowed a consequent reduction of the sample size, which improved the sampling resolution and reduced the sampling cost. It also ensured a better consistency of the samples for the five tracers.     

Hydrogeologic Controls on Induced Seismicity in Crystalline Basement Rocks Due to Fluid Injection into Basal Reservoirs

A series of M_b 3.8–5.5 induced seismic events in the midcontinent region, United States, resulted from injection of fluid either into a basal sedimentary reservoir with no underlying confining unit or directly into the underlying crystalline basement complex. The earthquakes probably occurred along faults that were likely critically stressed within the crystalline basement. These faults were located at a considerable distance (up to 10 km) from the injection wells and head increases at the hypocenters were likely relatively small (～70–150 m). We present a suite of simulations that use a simple hydrogeologic‐geomechanical model to assess what hydrogeologic conditions promote or deter induced seismic events within the crystalline basement across the midcontinent. The presence of a confining unit beneath the injection reservoir horizon had the single largest effect in preventing induced seismicity within the underlying crystalline basement. For a crystalline basement having a permeability of 2 × 10^?17 m² and specific storage coefficient of 10^?7/m, injection at a rate of 5455 m³/d into the basal aquifer with no underlying basal seal over 10 years resulted in probable brittle failure to depths of about 0.6 km below the injection reservoir. Including a permeable (k_z = 10^?13 m²) Precambrian normal fault, located 20 m from the injection well, increased the depth of the failure region below the reservoir to 3 km. For a large permeability contrast between a Precambrian thrust fault (10^?12 m²) and the surrounding crystalline basement (10^?18 m²), the failure region can extend laterally 10 km away from the injection well.     

Biofiltration of fishpond effluents and accumulation of N-compounds (phycobiliproteins and mycosporine-like amino acids) versus C-compounds (polysaccharides) in Hydropuntia cornea (Rhodophyta)

The biofiltration capacity, biomass-yield and accumulation of N- and C-compounds of Hydropuntia cornea were analyzed. Algae were grown in different conditions for 28 d: outdoor and indoor, with or without fishpond effluents. N-uptake efficiency of these effluents was higher than 95% after 7 d both outdoors and indoors. N-enriched conditions reduced the extent of photoinhibition and increased the maximal quantum yield in H. cornea. The biomass-yield was higher in outdoor grown-algae after 7 d and decreased independently of the treatment after 28 d. N, acid polysaccharide (AP) and mycosporine-like amino acid (MAA)-yields decreased throughout the experiment in all conditions. The highest MAA-yield was observed in fishpond effluent outdoor-grown algae, indicating a positive effect of increased radiation on MAA accumulation. However, APs were higher under N-depleted conditions. The use of MAAs as UV-screening and antioxidants, and the use of AP as immunostimulants are discussed.     

Atmospheric inorganic aerosol of a non-industrial city in the centre of an industrial region of the North of Spain,and its possible influence on the climate on a regional scale

Mineral particles could have influenced on the climate of Oviedo, a non-industrial city situated in the centre of an industrial zone of the North of Spain, increasing the temperature and the precipitations, in spite of the fact that “greenhouse gases” concentrations have diminished in this city in recent years. The directive (1999/30/EC) of the European Commission began to be applied in Oviedo in the year 2003. In agreement with this norm, our first aim was the identification of the inorganic particulate matter of the PM10 and PM2.5 fractions sampled in this city. X-ray diffraction and scanning electron microscopy coupled with X-ray dispersive energy spectrometry were used. The percentages of the different mineral phases of the PM were obtained by a Rietveld refinement of powder X-ray diffraction data. The compositions of the PM10 and PM2.5 fractions of this city are similar. Sulphates are the most abundant particles in the both fractions. Most sulphates, nitrates and sal-ammoniac would have formed by reaction between solid, liquid and/or gas particles and they could be associated with the power stations near to the city and traffic. Wüstite and haematites come from the iron and steel industries of Gijón and Avilés. The main natural sources of halite and carbonates and silicates are sea spray and soil resuspension by the wind, respectively.     

What information do policy makers need to develop climate adaptation plans for smallholder farmers? The case of Central America and Mexico

Scientific and technical information can increase the ability of policy makers to make strategic decisions. However, climate change policy is often formulated without significant input from science. We examine whether the availability and accessibility of information related to climate change is a major barrier for policy action on climate change adaptation for smallholder farmers. We also investigate whether scientific information related to climate change is available and used in policy making in Central America and Mexico. Our online survey of 105 decision makers indicated that a lack of scientific and technical information hinders policy makers from developing policies to help smallholder farmers adapt to climate change. Specific needs include information on the impacts of climate change on water availability for agriculture and the areas that are or will be prone to flooding, droughts or landslides. Information about the location of the farmers who are most vulnerable to climate change, the projected temperature and precipitation in agricultural areas and the expected impacts of climate change on crop yields or animal productivity, is also needed. Despite high interest in having scientific information guide policy making, many respondents indicated that policy makers rarely use this information in adaptation planning. In addition to ensuring that relevant information is available to inform policy making, technical and scientific information must be published in venues that are readily accessible for policy makers, easy to understand, and written in a format that is policy-relevant. It is also critical that scientific articles provide specific recommendations for achieving desired policy outcomes.     

Distribution of Sargassum muticum on the North West coast of Spain: Relationships with urbanization and community diversity

Invasions are common in coastal marine environments where proximity to urban areas should influence the number of non-native organisms due to the likelihood of unintentional introductions from urban centers. Invasive species are widely recognised as important agents of global change, and can colonize new habitats and even cause local extinction of native species. This study was focused on the invasive marine macroalga Sargassum muticum, a problematic invasive species on the West coast of America and in European waters. An intensive survey was carried out along the Galician coast (North West of Spain) from March to August 2008 to determine the current distribution of this species, and its relationship with level of urbanization and native macroalgal diversity. We sampled the presence of S. muticum and native macroalgae in the mid and low intertidal zones of twenty rocky shores distributed along ten rias. Rias were grouped into high and scarcely urbanized based on their population density. Results indicated that S. muticum was present in nine out of the ten rias, confirming its presence in most of the intertidal rocky shores of Galicia twenty years after it was first observed. The presence of S. muticum was not related to the degree of urbanization of the rias, and its distribution and abundance did not seem to be influenced by diversity or functional groups of native algae. In addition, there was a great variability in the percentage cover, number and length of individuals amongst localities and rias suggesting that both large-scale and local processes may play a role in the distribution of this species. This study highlights the importance of future research into the distribution and impact of introduced algae and proves the urgent need for monitoring programmes and increasing efforts to prevent and control new introductions.     

Multiphase Modeling of Geologic Carbon Sequestration in Saline Aquifers

Geologic carbon sequestration (GCS) is being considered as a climate change mitigation option in many future energy scenarios. Mathematical modeling is routinely used to predict subsurface CO₂ and resident brine migration for the design of injection operations, to demonstrate the permanence of CO₂ storage, and to show that other subsurface resources will not be degraded. Many processes impact the migration of CO₂ and brine, including multiphase flow dynamics, geochemistry, and geomechanics, along with the spatial distribution of parameters such as porosity and permeability. In this article, we review a set of multiphase modeling approaches with different levels of conceptual complexity that have been used to model GCS. Model complexity ranges from coupled multiprocess models to simplified vertical equilibrium (VE) models and macroscopic invasion percolation models. The goal of this article is to give a framework of conceptual model complexity, and to show the types of modeling approaches that have been used to address specific GCS questions. Application of the modeling approaches is shown using five ongoing or proposed CO₂ injection sites. For the selected sites, the majority of GCS models follow a simplified multiphase approach, especially for questions related to injection and local‐scale heterogeneity. Coupled multiprocess models are only applied in one case where geomechanics have a strong impact on the flow. Owing to their computational efficiency, VE models tend to be applied at large scales. A macroscopic invasion percolation approach was used to predict the CO₂ migration at one site to examine details of CO₂ migration under the caprock.     

The Iberian-Roman Humid Period (2600-1600 cal yr BP) in the Zoñar Lake varve record (Andalucía, southern Spain)

The Iberian-Roman Humid Period (IRHP, 2600-1600 cal yr BP), is the most humid phase of the last 4000 yr in southern Spain as recorded in the sedimentary sequence of Zoñar Lake (37°29′00″N, 4°41′22″ W, 300 m a.s.l.). A varve chronology supported by several AMS ¹⁴C dates allows study of the lake evolution at annual scale in response to human impact and climate changes. There are four climate phases within this period: i) gradual transition (2600-2500 yr ago, 650-550 BC) from a previous arid period; ii) the most humid interval during the Iberian-Early Roman Epoch (2500-2140 yr ago, 550-190 BC); iii) an arid interval during the Roman Empire Epoch (2140-1800 yr ago, 190 BC AD 150); and iv) a humid period synchronous with the decline of the Roman Empire (1800-1600 yr ago, AD 150-350). Varve thickness and geochemical proxies show a multi-decadal cyclicity similar to modern North Atlantic Oscillation (NAO) (60, 20 years) and solar variability cycles (11 yr). The timing and the structure of this humid period is similar to that described in Eastern Mediterranean and northern European sites and supports the same large-scale climate control for northern latitudes and the Mediterranean region.