The effect of chlorite interlayering on <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar biotite dating: an <Superscript>40</Superscript>Ar–<Superscript>39</Superscript>Ar laser-probe and TEM investigations of variably chloritised biotites

Biotite is one of the most common minerals dated by the ⁴⁰Ar–³⁹Ar method. It frequently shows K contents below the expected stoichiometric value, suggesting the presence of low-K impurities. The most common low-K alteration product of biotite is chlorite. Therefore, it is important to understand the effects of chlorite interlayering on ⁴⁰Ar–³⁹Ar ages in order to correctly interpret ⁴⁰Ar–³⁹Ar data. This study examines the outcome of ⁴⁰Ar–³⁹Ar dating analyses on variably chloritised biotites from Ordovician intrusive rocks. The infrared (IR) laser-probe technique and different gas extraction methods were adopted. Incremental laser-heating data on bulk samples yielded hump-shaped age profiles with meaningless young and old age steps. Both the extent of anomalous old age steps and the degree of discordance of the age spectra were much more pronounced in the more chloritised biotite samples. In contrast, in situ data on rock chips and total-fusion ages on single biotite flakes yielded ages concordant with, or younger than, the inferred emplacement ages. Transmission electron microscopy (TEM) was used to texturally characterise biotite samples at the nanometre scale. It was also used to document the complex decomposition-transformation process affecting interlayered biotite–chlorite during in-vacuo IR-laser heating to temperatures ranging from ~600 to >1,000 °C. TEM results suggest that hump-shaped age profiles result from an interplay between ³⁹Ar_K redistribution by recoil during sample irradiation and differential release of argon isotopes hosted in three main reservoirs. These reservoirs are (from least to most retentive): extended defects, chlorite and biotite. The final descending age segment is attributed to the progressive release of argon with increasing temperature from large biotite domains for which ³⁹Ar_K recoil loss was less important. ⁴⁰Ar–³⁹Ar data support previous findings, which suggest that ⁴⁰Ar–³⁹Ar ages when recoil effects are minimised, provide minimum estimates that approach the true biotite age, when the pristine domains are analysed. The most effective approach for obtaining meaningful ⁴⁰Ar–³⁹Ar ages was using individual total-fusion analyses on carefully selected, single flakes previously split along the basal cleavage by wet-grinding and corresponding to a sample mass of a few micrograms.Editorial responsibility: I Parsons     

Thermochronology and exhumation rates of granitic intrusions at Mesa Central,Mexico

ABSTRACT

The Mesa Central of Mexico (MC) is an elevated plateau located 2000 m above sea level in central Mexico, where intrusions outcrop that register the history of exhumation-erosion occurring during the Late Cretaceous-Paleogene. The tectonic history of the region records formation of the Late Cretaceous-Paleogene ‘Mexican orogen’; this was followed by extension of the entire region and several plutons were then exhumed. The age and magnitude of the crustal uplift and erosion occurring during exhumation has not been addressed to date. Therefore, this study reports the crystallization and cooling ages of two plutons, the Tesorera Granodiorite and the Comanja Granite, and estimates their emplacement depths. Based on these data, the exhumation age of the Tesorera Granodiorite is estimated to be between ~73 Ma and ~63 Ma at an exhumation rate of ~528 m/m. y. and that of the Comanja Granite is 52 Ma and 48 Ma at an exhumation rate of ~2500 m/m. y. Exhumation-erosion event of the Tesorera Granodiorite was located on the trace of the San Luis-Tepehuanes Fault System and that of the Comanja Granite on the a trace of the El Bajío Fault System. Furthermore, the high exhumation rate in the Comanja Granite suggests that gravitational collapse played an important role during exhumation.     

Velocity of auroral arcs drifting equatorward from the polar cap

The drift velocity of an auroral arc is compared with the component of F-region plasma velocity in the same direction for ten cases where the arc is seen to move steadily equatorward for several minutes without any major change in appearance or orientation. In most cases the two velocities are close, but on two occasions the drift velocity of the arc is much higher than the plasma velocity. From the cases studied it appears that during the growth and recovery phase of the substorm cycle the arc moves with a velocity close to the convection velocity, but during the expansion phase this is not the case.     

Carbonatation processes at the El Berrocal natural analogue granitic system (Spain): inferences from mineralogical and stable isotope studies

The El Berrocal granite/U-bearing quartz vein system has been studied as a natural analogue of a high-level radioactive waste repository. The main objective is to understand the geochemical behaviour of natural radionuclides occurring under natural conditions. In this framework, the carbonatation processes have been studied from a mineralogical and isotopic ( and ) point of view, since carbonate anions are powerful complexing agents for U(VI) under both low-temperature hydrothermal and environmental conditions. The carbonatation processes in the system are identified by the presence of secondary ankerite, with minor calcite, scattered in the hydrothermally altered granite, and Mn calcite in fracture filling materials. The isotopic signatures of these carbonates lead us to conclude that ankerite and calcite from the former were formed at the end of the same hydrothermal process that altered the granite, at a temperature range of between 72° and 61°C for ankerite, and between 52° and 35°C for calcite. The effect of edaphic CO₂ on both carbonates, greater on calcite than on ankerite, is demonstrated. Calcites from fracture fillings are, at least, binary mixtures, in different proportions, of hydrothermal calcite, formed between 25° and <100°C, and supergenic calcite, formed at ≤25°C. According to their signatures, the effect of edaphic CO₂ in both calcites is also evident. It is assumed that: (i) hydrothermal calcite from fracture fillings and ankerite from the hydrothermally altered granite are the result of the same hydrothermal process, their chemical differences being due to the intensity of the water/rock interaction which was stronger in the altered granite than in the fractures; and (ii) all of these carbonatation processes are responsible for ancient and recent migration/retention of uranium observed in the hydrothermally altered granite and fracture fillings.     

Palynology suggests hydrocarbon mobilization in Ordovician of Kasba Tadla Basin,Morocco

Palynological analysis of twelve wells shows that the metamorphic gradient of the pre-Mesozoic in the Kasba Tadla Basin of Morocco increases rapidly northwest-, southeast-, and eastward, from the center of the Basin. In the center, the Ordovician may still be releasing mobile hydrocarbons.

---

Zusammenfassung Eine palynologische Untersuchung von zwölf Bohrungen zeigt, daß der thermale Gradient sich im Premesozoikum des Kasba-Tadla-Beckens in Marokko vom Zentrum des Beckens aus nach Nordwesten, Südosten und Osten schnell vergrößert. Es ist sehr wohl möglich, daß das Ordovizium des Beckenzentrums noch flüssige und gasförmige Kohlenwasserstoffverbindungen abgibt.

---

Résumé L'analyse palynologique de 12 sondages montre que le gradient métamorphique du pré-Mésozoïque dans le Basin du Kasba Tadla, au Maroc, augmente à partir du centre du Bassin vers le nordouest, le sudest et vers l'est. Il est possible que l'Ordovicien de la partie centrale du Bassin produise encore des hydrocarbures liquides et gaseux.

---

12 , Kasba Tadla -, - . , .

---

---

The authors gratefully acknowledge support of this project through Grant GF-32510-X from the National Science Foundation, Washington, D.C., U.S.A.     

Five-year bio-monitoring of aquatic ecosystems near Artigas Antarctic Scientific Base,King George Island

Fildes Peninsula, in King George Island, Antarctica, has a great concentration of international facilities, and it has clearly been affected by human activities. The objective of this 5-year study was ...