Benthic mucilaginous aggregates in the Mediterranean Sea: Origin, chemical composition and polysaccharide characterization

Benthic mucilaginous aggregates are frequently formed in various parts of the Mediterranean basin, as in the Tyrrhenian and Adriatic Seas. Notwithstanding their wide spatial distribution, the role played by these aggregates in the biogeochemical cycling of organic matter is still largely unknown.The characteristics of the benthic aggregates examined in the present study showed that they are different from other mucilaginous aggregates, such as the “pelagic” ones that can form in the same areas in the water column and subsequently sediment to the seafloor. The aggregates are usually formed of structures of the filamentous macroalgae Acinetospora crinita, Chrysonephos lewisii and Nematochrysopsis marina. The elemental composition of the aggregates showed a marine macrophyte origin on the basis of the bulk organic matter content of the aggregates. Carbohydrates and proteins account for 26.6 to 55.9% of the organic carbon in the mucilage, respectively. Monosaccharide composition of exopolysaccharides in the mucilage aggregates revealed a characteristic pattern, with galactose, xylose or mannose and fucose as the major components. The relatively high content of deoxysugars is another distinctive feature. The abundant sulphate and uronic groups present in the polysaccharides in addition to their macromolecular dimensions and elongation contribute to inter-chain aggregation. Electron microscopic observations suggest that the polysaccharide fraction is the main macromolecular component in the formation of the persistent gel network in the aggregates.     

Small centres damaged by 2009 L’Aquila earthquake: on site analyses of historical masonry aggregates

This paper is focused on the illustration of on site works developed on some historical centres struck by L’Aquila earthquake of April 6, 2009 starting from the first emergency phase. The large number of minor historical centres damaged and the highly differentiated level of damage occurred implied the need of different procedures to study them. The common goal of all these studies is to illustrate the variability of the seismic response of historical masonry buildings trying to identify both the causes that have increased the damage (vulnerabilities) and the factors that have limited or prevented it (strengths). The preliminary results allow to formulate a first evaluation in view of drawing up reconstruction plans.     

Cold subduction zone in northern Calabria (Italy) revealed by lawsonite–clinopyroxene blueschists

Lawsonite blueschists are important markers of cold subduction zones, subjected to intense fluid circulation. This is because lawsonite preservation in exhumed blueschists and eclogites is typically linked to cold exhumation paths, accompanied by hydration. In the Catena Costiera (Calabria, southern Italy), lawsonite–clinopyroxene blueschists of the Diamante–Terranova Unit, affected by ductile shearing and retrogression, are exposed. Blueschists contain zoned clinopyroxene crystals, showing core–rim compositional variation from diopside to omphacite and hosting primary inclusions of lawsonite and titanite. Thermodynamic modelling of phase equilibria in the NCKFMASHTO system revealed peak metamorphic conditions of 2.0–2.1 GPa and 475–490°C for the Alpine subduction in Calabria. The subsequent post-peak metamorphic evolution mainly proceeded along a decompression and cooling path up to ~1.1 GPa and ~380°C. The final exhumation stages are recorded in the sheared blueschists where a mylonitic to ultramylonitic foliation developed at ~0.7 GPa and 290–315°C. Therefore, the P–T evolution of the Diamante–Terranova blueschists mostly occurred in the stability field of lawsonite, sustained by H₂O-saturated conditions during the exhumation path. The results of this study indicate that the blueschists underwent peak metamorphic conditions higher than previously thought, reaching a maximum depth of ~70 km under a very cold geothermal gradient (~6.6°C/km), during the Eocene subduction of the Ligurian Tethys oceanic crust in Calabria.     

Exploiting the use of physical information for the calibration of a lumped hydrological model

In hydrological modelling, the challenge is to identify an optimal strategy to exploit tools and available observations in order to enhance model reliability. The increasing availability of data promotes the use of new calibration techniques able to make use of additional information on river basins. In the present study, a lumped hydrological model—designed with the aim of utilizing remotely sensed data—is introduced and calibrated, adopting four different schemes that adopt, to varying extents, available physical information. The physically consistent conceptualization of the hydrological model used allowed development of a step by step calibration based on a combination of information, such as remotely sensed data describing snow cover, recession curves obtained from streamflow measurements, and time series of surface run‐off obtained with a baseflow mathematical filter applied to the streamflow time‐series. Results suggest that the use of physical information in the calibration procedure tends to increase model reliability with respect to approaches where the parameters are calibrated using an overall statistic based, considerably or exclusively, on streamflow data.     

Influence of the Sonic Anemometer Temperature Calibration on Turbulent Heat-Flux Measurements

The speed of sound in moist air is discussed and a more accurate value for the coefficient of the linear dependence of sonic temperature on specific humidity is proposed. An analysis of speed-of-sound data measured by three sonic anemometers in a climate chamber and in the field shows that the temperature response of each instrument significantly influences not only the determination of sonic temperature, but also its fluctuations. The corresponding relative contribution to the error in the evaluation of the temperature fluctuations and the turbulent heat fluxes can be as high as 40%. The calibration procedure is discussed and a method of correction is proposed.     

Modelling probability of rainfall-induced shallow landslides in a changing climate, Otta, Central Norway

We analyse slope stability conditions for shallow landslides under an extreme precipitation regime with regard to present and future scenarios, in order to first study the effect of changes in precipitation on stability conditions, considering uncertainty in the model parameters, and second to evaluate which factors contribute the most to model output and uncertainty. We used a coupled hydrological-stability model to study the hydrological control on shallow landslides in different precipitation regimes, with reference to the case study of Otta, located in central east Norway. We included a wide range of climatic settings, taking intensity, duration of the extreme events and two different antecedent precipitation conditions into account. Eleven future scenarios were determined using results of down-scaled meteorological models. Considering the uncertainty in the soil parameters, we used the Monte Carlo approach and probability of failure resulting from 5,000 trials was calculated for each precipitation scenario. In unstable areas the probabilities of failure at present and future conditions were compared using a bootstrapping method. Sensitivity analysis was carried out to understand how variations in input parameters influence the output of the selected model. The results show changes in the modelled stability conditions only if the effect of antecedent precipitation is not taken into account. The uncertainties in the predicted extreme precipitation events, soil parameters, and antecedent precipitation conditions do not allow any accurate estimation of changes in stability conditions for shallow landslides.     

Stormwater quantity and quality response to climate change using artificial neural networks

This research investigates the potential impacts of climate change on stormwater quantity and quality generated by urban residential areas on an event basis in the rainy season. An urban residential stormwater drainage area in southeast Calgary, Alberta, Canada is the focus of future climate projections from general circulation models (GCMs). A regression‐based statistical downscaling tool was employed to conduct spatial downscaling of daily precipitation and daily mean temperature using projection outputs from the coupled GCM. Projected changes in precipitation and temperature were applied to current climate scenarios to generate future climate scenarios. Artificial neural networks (ANNs) developed for modelling stormwater runoff quantity and quality used projected climate scenarios as network inputs. The hydrological response to climate change was investigated through stormwater runoff volume and peak flow, while the water quality responses were investigated through the event mean value (EMV) of five parameters: turbidity, conductivity, water temperature, dissolved oxygen (DO) and pH. First flush (FF) effects were also noted. Under future climate scenarios, the EMVs of turbidity increased in all storms except for three events of short duration. The EMVs of conductivity were found to decline in small and frequent storms (return period < 5 years); but conductivity EMVs were observed to increase in intensive events (return period ≥ 5 years). In general, an increasing EMV was observed for water temperature, whereas a decreasing trend was found for DO EMV. No clear trend was found in the EMV of pH. In addition, projected future climate scenarios do not produce a stronger FF effect on dissolved solids and suspended solids compared to that produced by the current climate scenario. Copyright © 2010 John Wiley & Sons, Ltd.     

Sea Storms in the Adriatic Sea and the Western Mediterranean during the Last Millennium

Data regarding the frequency andoccurrence of sea storms in the Adriatic Sea and theWestern Mediterranean during the last millennium havebeen extracted from historical written sources. TheAdriatic Sea shows two anomalous periods of high stormfrequency: the first half of the 1500s and the secondhalf of the 1700s. In the 1500s the storms were morefrequent in autumn, while in the late 1700s theyoccurred at high frequency in winter. In the WesternMediterranean, storms had a higher frequency in thefirst half of the 1600s, with two lesser periods ofhigh frequency in the 1400s and at the end of the1700s. Although both records show a maximum frequencyof sea storms during the Spörer Minimum(1416–1534) of solar activity, sunspot series yieldno, or poor, correlation during the other periods oflowest activity, i.e., Oort Minimum (1010–1090), WolfMinimum (1282–1342), and Maunder Minimum (1645–1715),suggesting that a teleconnection between sea stormsand sunspots is improbable or masked in this region.No teleconnection was found either between the ElNiño-Southern Oscillation (ENSO) and surgesflooding Venice or the Western Mediterranean storms orbetween Venice surges and the Northern AtlanticOscillation (NAO).     

Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily - Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.