Use of biomarkers indices in a sediment core to evaluate potential pollution sources in a subtropical reservoir in Brazil

The presence of PAHs, n-alkanes, pristane, and phytanes in core sediment from the Vossoroca reservoir (Parana, southern Brazil) was investigated. The total concentration of the 16 PAHs varied from 15.5 to 1646 μg kg⁻¹. Naphthalene was present in all layers (3.34–74.0 μg kg⁻¹). The most abundant and dominant n-alkanes were n-C₁₅ and n-C₃₆, with average concentrations of 198.1 ± 46.8 and 522.9 ± 167.7 μg kg⁻¹, respectively. Lighter n-alkanes were distributed more evenly through the layers and showed less variation, specially n-C₉, n-C₁₂, and n-C₁₈, with average concentrations of 14.6 ± 3.0, 31.6 ± 1.9, and 95.0 ± 5.2 μg kg⁻¹, respectively; heavier n-alkanes were more unevenly distributed.     

Influence of sieving time on the efficiency and accuracy of grain‐size analysis of beach and dune sands

Grain size is a fundamental property of sediments and is commonly used to describe sedimentary facies and classify sedimentary environments. Among the various conventional techniques utilized to determine grain‐size frequency distributions, sieving is the most widely applied procedure. The accuracy of such analyses is, among other factors, strongly dependent on the sieving time. However, despite a substantial amount of research in this field, optimal sieving times for different types of sediments have, to date, not been established. In this article, the influence of sieving time on grain‐size analyses of medium‐grained microtidal and mesotidal beach and dune sands has been determined. To assess the precision of important textural parameters, such as median grain size, sorting, skewness and kurtosis, an error analysis was carried out for different sieving times (2, 5, 10, 15 and 20 minutes). After calibrating the analytical and sampling methodologies, significant deviations were registered when sieving time was less than 10 minutes. However, such deviations were very small and grain‐size distributions remained almost identical for sieving times of 10 minutes and longer, relative errors being as low as 0% in some cases.     

Experimental data on SOA formation from mixtures of anthropogenic and biogenic organic compounds

Secondary organic aerosols (SOA) constitute a significant fraction of the atmospheric particulate matter. Theses particles are formed as a consequence of the oxidation reaction of certain organic gases that leads to the formation of low-volatility compounds. As for other pollutants, air quality models allow the simulation of particle levels and thus models constitute a powerful tool in air quality management. Nevertheless, the accepted use of models must be based on the validation of its capacity to reproduce observed concentrations. Air monitoring sites provide measured information of a large variety of ambient pollutants. Unfortunately, measurements on SOA are not normally available, as current monitoring networks do not include instrumentation to distinguish primary from secondary sources of organic carbonaceous aerosol. This paper presents a set of photooxidation experiments performed in the European Photorreactor (EUPHORE) smog chamber (CEAM, Spain) under different experimental conditions to investigate SOA formation. The use of chambers allows the isolation of atmospheric chemistry and aerosol formation processes. Thus, although these measurements were obtained at initial precursor concentrations higher than those in atmospheric conditions, they constitute a valuable set of information for SOA model evaluation purposes.     

Greenhouse gases mitigation against climate change: United States-Mexico border study case

Solar radiation is one of the most important energy resources of our planet. The interest in its use as a renewable and clean energy to mitigate the greenhouse gases (GHG) effects has increased significantly. This paper evaluates the measurements of global solar radiation and its energy potential and presents a comparison between both of them, as an example of the effort to reduce GHG emissions. The measurements were made with pyranometers installed in the city of Mexicali, Baja California, located in northwestern Mexico, and the city of Yuma, Arizona, located in the southwestern United States. Separated by a distance of 96 km, both cities have a sustained development and are climatically similar, since they present numerous sunny days, extreme hot temperatures and little precipitation. The results presented show differences in their behavior and in the solar radiation measurement values, especially for the critical spring and summer seasons, with values 15.73% (0.042 kW/m²) higher in Mexicali with respect to Yuma. Energy power is estimated, and it is discussed with some variables as global solar radiation, rainfall, air temperature, relative humidity and climatology of clear, partly cloudy, and cloudy days. With this estimation, the solar energy used and GHG avoided is projected for Mexicali. It is assessed that 291 tons of GHG are prevented. The Mexicali values of potential energy are higher than those of Yuma; therefore, this solar and energy comparative study provides reasons to develop these technologies in Mexico, but solar technologies should be deployed also in Yuma. The measured data at the regional level demonstrate their importance, and the relevance of the proposed mitigation strategy for climate change.     

Hydromechanical Analysis of Masonry Gravity Dams and their Foundations

A numerical model for the hydromechanical analysis of masonry dams based on the discrete element method is presented. The dam and the rock foundation are represented as block assemblies, and a coupled flow-stress analysis is performed in an integrated manner for the entire system. Complex block shapes may be obtained by assembling elementary blocks into macroblocks, allowing the application of the model to situations ranging from equivalent continuum to fully discontinuum analysis. A contact formulation was developed based on an accurate edge–edge approach, incorporating mechanical and hydraulic behavior. The main numerical aspects are described, with an emphasis in the flow analysis explicit algorithm. An application to an existing masonry dam is presented, analyzing its present condition, with excessive seepage, and the proposed rehabilitation intervention. An evaluation of sliding failure mechanisms was also performed, showing the expected improvement in the safety of the structure.     

Framing vulnerability, risk and societal responses: the MOVE framework

The paper deals with the development of a general as well as integrative and holistic framework to systematize and assess vulnerability, risk and adaptation. The framework is a thinking tool meant as a heuristic that outlines key factors and different dimensions that need to be addressed when assessing vulnerability in the context of natural hazards and climate change. The approach underlines that the key factors of such a common framework are related to the exposure of a society or system to a hazard or stressor, the susceptibility of the system or community exposed, and its resilience and adaptive capacity. Additionally, it underlines the necessity to consider key factors and multiple thematic dimensions when assessing vulnerability in the context of natural and socio-natural hazards. In this regard, it shows key linkages between the different concepts used within the disaster risk management (DRM) and climate change adaptation (CCA) research. Further, it helps to illustrate the strong relationships between different concepts used in DRM and CCA. The framework is also a tool for communicating complexity and stresses the need for societal change in order to reduce risk and to promote adaptation. With regard to this, the policy relevance of the framework and first results of its application are outlined. Overall, the framework presented enhances the discussion on how to frame and link vulnerability, disaster risk, risk management and adaptation concepts.     

Strutted Excavation in Soft Soil Incorporating a Jet-Grout Base Slab: Analysis Considering the Consolidation Effect

The influence of the consolidation on a strutted excavation in soft soil is analysed using a computer code based on the finite element method. A base jet-grout slab is considered in order to improve stability against bottom heave failure and minimize wall displacements. The numerical model incorporates the Biot consolidation theory (coupled formulation of the flow and equilibrium equations) with soil constitutive relations simulated by the p–q–θ critical state model. Special emphasis is given to the analysis, during and after the construction period, of the pore pressures, shear stresses, stress levels and displacements in the ground, as well as strut compression loads, wall displacements and bending moments, earth pressures on the wall faces and compression loads and bending moments on the jet-grout slab. The safety factor against bottom heave is also evaluated from the finite element analysis considering formulations of the critical state soil mechanics, and also compared to values obtained with traditional methods that use limit equilibrium approach and bearing capacity fundamentals.     

Thrust tectonics and paleogene syntectonic sedimentation in the Empordà area,southeastern Pyrenees

Abstract

The structure of the southern Pyrenees, east of the Albanyà fault (Empordà area), consists of several Alpine thrust sheets. From bottom upwards three main structural units can be distinguished : the Roc de Frausa, the Biure-Bac Grillera and the Figueres units. The former involves basement and Paleogene cover rocks. This unit is deformed by E-W trending kilometric-scale folds, its north dipping floor thrust represents the sole thrust in this area. The middle unit is formed by an incomplete Mesozoic succession overlain by Garumnian and Eocene sediments. Mesozoic rocks internal structure consists of an imbricate stack. The floor thrust dips to the south and climbs up section southwards. The upper unit exibits the most complete Mesozoic sequence. Its floor thrust is subhorizontal. The lower and middle units thrust in a piggy-back sequence. The upper unit was emplaced out of sequence.

Lower Eocene sedimentation in the Biure-Bac Grillera unit was controlled by emergent imbricate thrusts and synchronic extensional faults. One of these faults (La Salut fault) represents the boundary between a platform domain in the footwall and a subsident trough in the hangingwall. Southward thrust propagation produces the inversion of these faults and the development of cleavage-related folds in their hangingwalls (buttressing effect). This inversion is also recorded by syntectonic deposits, which have been grouped in four depositional sequences. The lower sequences represent the filling on the hangingwall trough and the upper sequences the spreading of clastics to the south once the extensional movement ends.     

Genesis of the Ibero-Armorican arc

Abstract

The Ibero-Armorican arc is continuous between Iberia and Armorica; its curvature increased with time due to subduction followed by continental collision; indentation produced left lateral transpression in Iberia and right-lateral transpression in Armorica. It is argued that whereas the antithetic shear is predominant in Iberia, in Armorica a synthetic shear prevailed because the identer rotated anticlockwise between the opposed forelands of the Variscan Fold Belt. It is proposed that the major Rheic ocean, closed by subduction towards the inner part of the arc, solving the space problem of centripetal vergences.     

Spatio-Temporal Patterns of Submerged Macrophytes in Three Hydrologically Altered Mediterranean Coastal Lagoons

Rice cultivation in the Ebro Delta (Catalonia, Spain) has inverted the natural hydrological cycles of coastal lagoons and decreased water salinities for over 150 years. Adjustments in the water management practices—in terms of source and amount of freshwater inputs—have resulted in changes in the diversity, distribution and productivity of submerged angiosperms. Between the 1970s and late 1980s, a massive decline of the aquatic vegetation occurred in the Encanyissada–Clot and Tancada lagoons, but little information on the status is available after the recovery of macrophytes in the 1990s. Here, we evaluate the influence of salinity regimes resulting from current water management practices on the composition, distribution, seasonal abundance and flowering rates of submersed macrophytes, as well as on the occurrence of epiphyte and drift macroalgae blooms in three coastal lagoons. Our results show that Ruppia cirrhosa is the dominant species in the Encanyissada lagoon (185.97?±?29.74 g?DW?m^?2?year^?1; 12–27?‰ salinity) and the only plant species found in the Tancada lagoon (53.26?±?10.94 g?DW?m²?year^?1; 16–28?‰ salinity). Flowering of R. cirrhosa (up to 1,011?±?121 flowers?m^?2) was only observed within the Encanyissada and suggests that mesohaline summer conditions may favor these events. In contrast, low salinities in Clot lagoon (～3–12?‰) favor the development of Potamogeton pectinatus (130.53?±?13.79 g?DW?m²?year^?1) with intersperse R. cirrhosa (8.58?±?1.71 g?DW?m^?2) and mixed stands of P. pectinatus and Najas marina (up to ～57 g?DW?m^?2?year^?1) in some reduced areas. The peak biomasses observed during the study are 88 to 95 % lower than maximum values reported in the literature at similar salinities, and there is also little or no recovery in some areas compared to last reports more than 20 years ago. The main management actions to restore the natural diversity and productivity of submersed angiosperms, such as the recovering of the seagrass Zostera noltii, should be the increase of salinity during the period of rice cultivation, by reducing freshwater inputs and increasing flushing connections with the bays.