Inorganic ions and trace metals bulk deposition at an Atlantic Coastal European region

The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl^?, NO₃ ^?, SO₄ ^2?, Na⁺, K⁺, Ca²⁺, Mg²⁺ and NH₄ ⁺) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites.     

Tectonic heritage in drainage pattern and dynamics: the case of the French South Alpine Foreland Basin (ca. 45–20 Ma)

The spatial and temporal organization of depositional environments in drainage networks of foreland basins reflect the tectonic and erosional dynamics associated with the development of mountain belts. We provide field evidences for the initiation and evolution of a complex drainage system in the French South Alpine Foreland Basin related to Western Alps exhumation. Sedimentological and structural analyses of the Eocene–Early Miocene succession were investigated in the (1) Argens/Peyresq, (2) Barrême/Blieux/Taulanne and (3) Montmaur/St‐Disdier sectors. Combined with the existing structural data set, we propose a new model that integrates the regional tectonic activity, the palaeovalley orientation and their dynamics through time. The Eocene–Miocene deposits clearly show the existence of N–S‐oriented palaeovalleys. The systematic presence of early NE–SW‐ to N–S‐oriented strike‐slip and extensional faults in the palaeovalleys suggests that these tectonic structures were responsible for the formation of the initial N–S‐oriented basin‐floor topographies. The vertical offset of the strike‐slip faults induced sufficient accommodation space for the Cenozoic sedimentation since the Middle Eocene. It implies the creation of N–S‐oriented palaeovalleys during the northward Pyrenean‐Provençal phase, pre‐dating westward Alpine compression. Later, the Oligocene Alpine tectonic phase induced drainage expansion toward the orogenic wedge and the erosion of the exhumed internal massifs by transverse streams. The establishment of new connections between the old topographic lows formed a longitudinal drainage pattern that remains the locus of deposition in a regional sedimentary routing system. In this model, former strike‐slip faults correspond to weakness zones overprinted by the westward Alpine shortening that allowed the formation of the modern piggyback basin structure of the foreland and the long‐time preservation of the palaeovalley geometry.     

Nonlinear Evolution of Thermal Structures. Numerical Approach

A numerical algorithm using a two stage, two level difference scheme has been developed to solve the heat transfer equation with nonlinear heat diffusion and bulk energy losses. The algorithm is an extension of the scheme developed by Meek and Norbury (1982). The first stage calculates an intermediate value which is used in a second stage to estimate a new value. The scheme is consistent, second-order convergent in space and almost second order in time. It has been applied to the nonlinear stability and time evolution of thermal structures constituted by optically thin plasmas with solar abundances. The configuration has been assumed to be heated at a rate T^m, cooled at a rate Tⁿ and a thermal conduction coefficient T^k. In particular, the second order analytical approximation considered in previous papers (Ibáñez and Rosenzweig, 1995; Steele and Ibáñez, 1997) has been worked out for arbitrary amplitude of the initial temperature disturbance. Particular cases of interest in Astrophysics are considered.     

New controversies on Columbus' “cosmographic” ideas

On the basis of modern works of a Spanish paleographer, a North American geographer and, a historian-sailor, also North American, respectively, we have reexamined some controversial aspects of the cosmographic ideas ascribed to the Columbus brothers (Christopher and Bartholomew), regarding the preparation of their first transoceanic voyage. First, we present a discussion of two versions of the translation and explanation of a part or phrase of one of the marginal notes or postils, written supposedly by one of them or both in Latin in their IMAGO MUNDI (d'Ailly, Pierre. Tract of Geography of century XV) copy that seriously questions the credibility of the Columbus brothers' knowledge of the cartography of that time. Secondly, we have analized three hypotheses attempting to explain the methods they could have used, to measure the length of a terrestrial degree either on the equator or on a meridian. We will show that these hypotheses are unacceptable due to the manipulation of the information by its authors and, because there is not enough historical evidence to demonstrate that Christopher Columbus or his brother made such geodesical measurements.     

Retrograde evolution of quartz segregations from the Dos Picos shear zone in the Nevado-Filabride Complex (Betic chains,Spain). Evidence from fluid inclusions and quartz c-axis fabrics

Synkinematic quartz veins are ubiquitous in the shear zone separating the Veleta unit from the Calar Alto unit in the internal part of the Betic Cordilleras. They have been studied with respect to quartz c-axis fabrics, microstructures and fluid inclusions. Veins were probably generated during syn-metamorphic stacking of the units at P = 500 – 600 MPa and T = 400 – 500°C. Quartz displays two groups of microstructures in the shear zone: (1) older coarse-grained mosaics (CGM) resulting from exaggerated grain growth; and (2) younger fine-grained mosaics (FGM) developed at the expense of the former. The fine-grained mosaics show polygonal granoblastic and elongate mosaic microstructures in general, with ribbon microstructures often found near the boundary of the units. Fluids contained in secondary inclusions vary from high salinity brines to different types of CO₂—brine mixtures and low density CO₂ fluids. Differences in composition and P-T trapping conditions are indicated for the different types of inclusions. Some fluid inclusions are older than the FGM, whereas others are younger, thus constraining the P- T conditions at which the two microstructural events took place. Fluid inclusion evidence suggests conditions of P_fluid > 170 MPa and T 370–430°C for the CGM and P_fluid 20–80 MPa and T > 340°C for the FGM.The quartz c-axis fabrics dealt with here correspond to the second recrystallization event, as little evidence of older fabrics is preserved in the shear zone. C-axis patterns vary across the shear zone from slightly asymmetrical type I crossed girdles in the hanging wall and footwall to more asymmetrical crossed girdles at the boundary of the units. This indicates a correlative increase in the magnitude of the heterogeneous shear strain in the same direction. Most of the deformation is concentrated at the top of the Veleta unit. The sense of movement is top to the west, in agreement with other kinematic markers.The quartz c-axis fabrics resulted from dynamic recrystallization during simple shear. The retrograde P-T path inferred from fluid inclusion analysis, along with other geological and geochronological evidence, indicates that this deformation is coeval with a reduction in the crustal overburden.Geochronological and stratigraphic data show that the proposed Dos Picos extensional detachment, separating the Calar Alto and Veleta units, took place during the early Miocene, synchronous with the intense thinning of the Nevado-Filábride Complex and of the whole continental crust underlying the Alborán Basin.     

Metallic Mineral Resources in the Twenty-First Century: II. Constraints on Future Supply

Supplying worldwide demand of metallic raw materials throughout the rest of this century may require 5–10 times the amount of metals contained in known ore deposits. This demand can be met only if mineral deposits containing the required masses of metals, in excess of present day ore reserves, exist in the Earth’s crust. It is, by definition, not known whether or not such mineral deposits exist. On the basis of the statistical distribution of metal tonnages contained in known ore deposits, however, it is possible to place constraints on the size distribution of the deposits that must be discovered in order to meet the expected demand. A nondimensional analysis of the distribution of metal tonnages in deposits of 20 metals shows that most of them follow distributions that, although not strictly lognormal, share important characteristics with a lognormal distribution. Chief among these is the observation that frequency falls off symmetrically and geometrically with deposit size, relative to a median deposit size that is approximately equal to the geometric mean deposit size. An immediate consequence of this behavior is that most of the metal endowment is concentrated in deposits that are several orders of magnitude larger than the median deposit size, and that are much rarer than the most common deposits that cluster around the median deposit size. The analysis reveals remarkable similarities among the statistical distributions of most of the metals included in this study, in particular, the fact that distribution of most metals can be fully described with essentially the same value (about 2–3) of the scale parameter, σ, which is the only parameter needed to describe the behavior of a normalized lognormal variable. This observation makes it possible to derive the following general conclusions, which are applicable to most metals—both scarce and abundant. First, it is unlikely that undiscovered mineral deposits of sizes comparable to those that contain most of the known metal endowment exist in sufficient quantities to supply the expected worldwide demand throughout the rest of this century. Second, if the expected demand is to be met, one must hope that very large deposits, perhaps up to one order of magnitude larger than the largest known deposits, exist in accessible portions of the Earth’s crust, and that these deposits are discovered.     

W–Au skarns in the Neo-Proterozoic Seridó Mobile Belt,Borborema Province in northeastern Brazil: an overview with emphasis on the Bonfim deposit

The Seridó Mobile Belt (SMB) is located in the Borborema Province in northeastern Brazil and consists of a gneiss basement (Archean to Paleo-Proterozoic), a metasedimentary sequence (marble, quartzites, and schists), and the Brasiliano igneous suite (both of Neo-Proterozoic age). In this region, skarns occur within marble and at the marble–schist contact in the metasedimentary sequence. Most of the skarn deposits have been discovered in the early 1940s, and since then, they have been exploited for tungsten and locally gold. Recently, the discovery of gold in the Bonfim tungsten skarn has resulted in a better understanding of the skarn mineralization in this region. The main characteristics of the SMB skarns are that they are dominantly oxidized tungsten skarns, with the exception of the Itajubatiba and Bonfim gold-bearing skarns, which are reduced based on pyrrhotite as the dominant sulfide, garnet with high almandine and spessartine component, and elevated gold contents. In the Bonfim deposit, pressure estimates indicate that the skarns formed at 10- to 15-km depth. The mineralized skarns present the prograde stage with almandine, diopside, anorthite, and actinolite-magnesio-hornblende, and titanite, apatite, allanite, zircon, and monazite as accessory minerals. The retrograde stage is characterized by alkali feldspar, clinozoisite–zoisite–sericite, calcite, and quartz. Scheelite occurs in four ore-shoots distributed within the marble and at the marble–schist contact. The main ore body is 5–120 cm wide and contains an average of 4.8-wt.% WO₃, which occurs in the basal marble–schist contact. Fold hinges appear to control the location of high-grade scheelite. The late-stage gold mineralization contains bismite (Bi₂O₃), fluorine-bearing bismite, native bismuth, bismuthinite (Bi₂S₃), and joseite [Bi₄(Te,S)₃], and also chlorite, epidote, prehnite, chalcopyrite, and sphalerite. This gold–bismuth–tellurium mineralization exhibits a typical late character and occurs as a black fine-grained mineral assemblage controlled by conjugate brittle-ductile faults (and extensional fractures) that crosscut not only the banding in prograde skarn but also the retrograde alkali feldspar and clinozoisite–zoisite–sericite assemblage. The Au–Bi–Te-bearing minerals are intergrown with retrograde epidote, prehnite, chlorite, chalcopyrite, and sphalerite, indicating that gold mineralization at Bonfim is linked to a late-stage skarn event. The polymetallic nature of the Bonfim deposit can be used as an important guide for the exploration of this type of skarn deposit in the Borborema Province, which potentially contains significant new, undiscovered gold and polymetallic deposits.     

Cut Slopes in Clayey Soils: Consolidation and Overall Stability by Finite Element Method

When a cut slope in a saturated clay is undertaken, a transient water flow occurs and stress transferences from the water to the soil skeleton take place in time (consolidation). Mainly in strongly overconsolidated clays, these stress transferences may determine swelling of soil and therefore reduction of its shear strength in time. However, the lowering of the water level associated to the cut increases effective mean stress, which may therefore counterbalance the above-mentioned effect. In the paper, the behaviour of a cut slope in an overconsolidated clay is analysed by a finite element program that incorporates the Biot consolidation theory (coupled analysis), with constitutive relations simulated by the p–q–θ critical state model. In addition, the variation in time of the overall stability is assessed with a computer program that uses the finite element results and formulations of the critical state soil mechanics. In order to achieve a more complex geotechnical interpretation of the problem, the analysis in time of the excess pore pressures, effective stresses, displacements and stress levels is also presented. Finally, comparisons of stability results are analysed by changing some parameters, namely the problem geometry (weight of excavated soil) and the over-consolidation ratio of the clay.