Nitrous oxide emissions from gasohol, ethanol and CNG light duty vehicles

A sample of 21 light duty vehicles powered by Otto cycle engines were tested on a chassis dynamometer to measure the exhaust emissions of nitrous oxide (N₂O). The tests were performed at the Vehicle Emission Laboratory of CETESB (Environmental Company of the State of Sao Paulo) using the US-FTP-75 (Federal Test Procedure) driving cycle. The sample tested included passenger cars running on three types of fuels used in Brazil: gasohol, ethanol and CNG. The measurement of N₂O was made using two methods: Non Dispersive InfraRed (NDIR) analyzer and Fourier Transform InfraRed spectroscopy (FTIR). Measurements of regulated pollutants were also made in order to establish correlations between N₂O and NO_x. The average N₂O emission factors obtained by the NDIR method was 78?±?41?mg.km^?1 for vehicles running with gasohol, 73?±?45?mg.km^?1 for ethanol vehicles and 171?±?69?mg.km^?1 for CNG vehicles. Seventeen results using the FTIR method were also obtained. For gasohol vehicles the results showed a good agreement between the two methods, with an average emission factor of 68?±?41?mg.km^?1. The FTIR measurement results of N₂O for ethanol and CNG vehicles were much lower than those obtained by the NDIR method. The emission factors were 17?±?10?mg.km^?1 and 33?±?17?mg.km^?1, respectively, possibly because of the interference of water vapor (present at a higher concentration in the exhaust gases of these vehicles) on measurements by the NDIR method.     

Recent trends in mean maximum and minimum air temperatures over Spain (1961–2006)

This study analyzes the mean maximum and minimum temperature trends on a monthly, seasonal, and annual timescale by applying various statistical tools to data from 476 Spanish weather stations during the period between 1961 and 2006. The magnitude of the trends was derived from the slopes of the regression lines using the least squares method, and the nonparametric Mann–Kendall test was used to determine the statistical significance of the trends. Temperature significantly increased in over 60% of the country in March, June, spring, and summer in the case of maximum temperatures and in March, May, June, August, spring, and summer for minimum temperatures. At the annual resolution, temperatures significantly increased in over 90% of Spain with a rise of around 0.3°C/decade. The maximum temperature increased at a higher rate than the minimum temperature from midsummer to early winter as well as in winter, spring, and summer and also on an annual basis.     

The meteorological framework and the cultural memory of three severe winter-storms in early eighteenth-century Europe

Three violent eighteenth-century storms that ravaged the North Sea area (1703), western central Europe (1739) and Portugal (1739) are investigated from the point of view of their meteorological setting, their socio-economic impact, and whether and by what means they secured an enduring place in the cultural memory. The evidence draws on individual narrative sources such as chronicles and poems, and institutional sources such as ship’s logbooks and state-organised ‘windthrow’ inventories of tree loss. Each of the three storms had socio-economic impacts that could be described as ‘war-like’ in the damage caused to buildings and the destruction of forests. The “Great Storm” of December 1703 jeopardized English naval supremacy in the War of the Spanish Succession by sinking a number of Royal Navy ships and taking the life of more than 8000 seamen. In January 1739 two similarly destructive storms swept over mainland Europe. The cultural memory of the three events here considered was however strikingly different. The sequence of storms in January 1739 though being the most protracted of the last centuries, and well-chroniceled, did not persist in the collective memories of those in France, Switzerland and elsewhere who experienced them. Likewise, the “Great Storm” was quickly forgotten on the continent, whereas its memory remained deeply rooted in England through the writings of Defoe (1704). In Portugal the 1739 storm won a lasting place in the country’s cultural memory owing to two poems that it inspired. Furthermore, it was recorded in the Kingdom’s official newspaper, in the astronomical prognoses and in written records of the Old Regime’s cultural elite.     

Influence of olive mill waste application on the role of soil as a carbon source or sink

Organic matter (OM) is involved in the enhancement of soil quality since it acts on soil structure, nutrient storage and biological activity. Organic carbon (OC), the dominant element constituent of OM, and related soil properties are probably the most widely acknowledged indicator of soil quality. The typically Mediterranean climate of the South of Spain promotes low yields on crops and low organic carbon in soil. The present work was carried out to evaluate the effect of the application of alperujo, olive oil waste difficult to eliminate, on the fixation or emission of carbon on soil in an olive grove situated in Montoro (Córdoba, Spain). In the study three treatments were considered: 15 kg (A), 7.5 kg (B), 0 kg (C) of alperujo per tree and the implementation of the amendment has been made for three consecutive years. The results confirm the benefits of the amendment on the carbon content organic soil with a fixation with respect to control of 4.8 and 6.1 t ha^???1 for the first year and 8.7 and 6.8 t ha^???1 for the second in treatments A and B, respectively. Of the different climatic agents considered in the study, it was the temperature which had a major influence on the emissions of CO₂ into the atmosphere and the flow of gas presented the highest values in soils treated with the highest dose.     

Relationship between climate change and vegetation distribution in the Mediterranean mountains: Manzanares Head valley, Sierra De Guadarrama (Central Spain)

This work analyzes the consequences of climate change in the distribution of the Mediterranean high-mountain vegetation. A study area was chosen at the Sierra de Guadarrama, in the center of the Iberian Peninsula (1,795 to 2,374 m asl). Climate change was analyzed from the record of 18 variables regarding temperature, rainfall and snowfall over the period 1951–2000. The permanence of snow cover (1996–2004), landforms stability and vegetation distribution in 5 years (1956, 1972, 1984, 1991 and 1998) were all analyzed. The Nival Correlation Level of the different vegetation classes was determined through their spatial and/or temporal relationship with several climatologic variables, snow cover duration and landforms. In order to quantify trends and major change processes, areas and percent changes were calculated, as well as Mean Annual Transformation Indices and Transition Matrices. The findings reveal that in the first part of the study period (up to the first half of the 1970s) the temperature rise in the mid-winter months caused the reduction of some classes of nival vegetation, while others expanded, favored by high rainfall, decrease in both maximum temperatures and summer aridity, and longer snow cover duration. The second part of the study period was characterized by the consolidation of the increase in all thermal variables, along with an important reduction in rainfall volume and snow cover duration. As a result, herbaceous plants, which are highly correlated with a long snow permanence and abundance of melting water, have been replaced by leguminous shrubs which grow away from the influence of snow, and which are steadily becoming denser.     

Spatial and temporal patterns of dry spell lengths in the Iberian Peninsula for the second half of the twentieth century

Summary Daily pluviometric records of 43 meteorological stations across the Iberian Peninsula have permitted a detailed analysis of dry spell patterns for the period 1951–2000 by distinguishing daily amount thresholds of 0.1, 1.0, 5.0 and 10.0 mm/day. The analyses are based on three annual series, namely the number of dry spells, N, the average dry spell length, L, and the extreme dry spell length, L _max. First, the statistical significance of local trends for the annual series of N, L and L _max has been investigated by means of the Mann-Kendall test and significant field trends have been established by means of Monte Carlo simulations. Clear signs of negative field trends are detected for N (1.0 and 10.0 mm/day) and L (0.1 mm/day). Second, the Weibull model fits well the empirical distributions of dry spell lengths for all the rain gauges, whatever the daily amount threshold, with a well ranged spatial distribution of their parameters u and k. On the basis of the Weibull distribution, return period maps for 2, 5, 10, 25 and 50 years have been obtained for dry spell lengths with respect to the four daily threshold levels. While for 0.1 and 1.0 mm/day the longest dry spells are expected at the south of the Iberian Peninsula, for 5.0 and 10.0 mm/day they are mostly detected at the southeast. Finally, the elapsed time between consecutive dry spells has been analysed by considering the same rain amount thresholds and different dry spell lengths at increasing intervals of 10 days. This analysis makes evident a significant negative field trend of the elapsed time between consecutive dry spells of lengths ranging from 10 to 20 days for daily amount thresholds of 1.0, 5.0 and 10.0 mm/day. Authors’ addresses: X. Lana, C. Serra, Departament de Física i Enginyeria Nuclear, ETSEIB, Universitat Politècnica de Catalunya, Av. Diagonal 647 planta 11, 08028 Barcelona, Spain; M. D. Marínez, Departament de Física Aplicada, Universitat Politècnica de Catalunya, 08028 Barcelona, Spain; A. Burgue?o, Departament de Meteorologia i Astronomia, Universitat de Barcelona, 08028 Barcelona, Spain; J. Martín-Vide, L. Gómez, Grup de Climatologia, Universitat de Barcelona, 08028 Barcelona, Spain.     

Regional climate change experiments over southern South America. I: present climate

We present an analysis of a regional simulation of present-day climate (1981–1990) over southern South America. The regional model MM5 was nested within time-slice global atmospheric model experiments conducted by the HadAM3H model. We evaluate the capability of the model in simulating the observed climate with emphasis on low-level circulation patterns and surface variables, such as precipitation and surface air mean, maximum and minimum temperatures. The regional model performance was evaluated in terms of seasonal means, seasonal cycles, interannual variability and extreme events. Overall, the regional model is able to capture the main features of the observed mean surface climate over South America, its seasonal evolution and the regional detail due to topographic forcing. The observed regional patterns of surface air temperatures (mean, maxima and minima) are well reproduced. Biases are mostly within 3°C, temperature being overestimated over central Argentina and underestimated in mountainous regions during all seasons. Biases in northeastern Argentina and southeastern Brazil are positive during austral spring season and negative in other seasons. In general, maximum temperatures are better represented than minimum temperatures. Warm bias is larger during austral summer for maximum temperature and during austral winter for minimum temperature, mainly over central Argentina. The broad spatial pattern of precipitation and its seasonal evolution are well captured; however, the regional model overestimates the precipitation over the Andes region in all seasons and in southern Brazil during summer. Precipitation amounts are underestimated over the La Plata basin from fall to spring. Extremes of precipitation are better reproduced by the regional model compared with the driving model. Interannual variability is well reproduced too, but strongly regulated by boundary conditions, particularly during summer months. Overall, taking into account the quality of the simulation, we can conclude that the regional model is capable in reproducing the main regional patterns and seasonal cycle of surface variables. The present reference simulation constitutes the basis to examine the climate change simulations resulting from the A2 and B2 forcing scenarios which are being reported in a separate study.     

Preface: Workshop on matter,astrophysics, gravitation,ions and cosmology—MAGIC23

We outline our experience in organizing the first edition of the Workshop on Matter, Astrophysics, Gravitation, Ions and Cosmology, held in virtual and in-person format, denominated MAGIC23, held from 6 to 10 March, 2023, in Praia do Rosa, Santa Catarina, Brazil. The event aimed to bring together leading academic scientists, professors, students, and research scholars for exchanging experiences and discuss the most recent innovations, trends, practical challenges, and experimental and theoretical solutions adopted in the investigation fields within the scope of the meeting. The workshop offered to the participants a platform for scientific and academic projects, partnerships, and presentation of high-quality research contributions describing original and unpublished results on topics related to matter, astrophysics, gravitation, ions, and cosmology.     

Spatial and temporal changes in dry-snow line altitude on the Antarctic Peninsula

Drastic changes were detected in glacial systems of the Antarctic Peninsula in the last decades. The observed phenomena comprise the disintegration of ice shelves, acceleration and thinning of glaciers, and retreat of glacier fronts. However, due to the lack of consistent systematic observations in particular of the higher parts of the glacial systems, it is difficult to predict further responses of the Antarctic Peninsula glaciers to climatic change. The present paper analyses spatial and temporal variations of changes in the dry-snow line altitude on the Antarctic Peninsula as extracted from a time series (1992–2005) of ERS-1/2 SAR and Envisat ASAR data. Upward changes in dry-snow line altitude were observed in general, and are attributed to extreme high-temperature events impacting the central plateaus of the Antarctic Peninsula and the increasing duration of warming periods. A mean decrease in dry-snow line altitude was detected on the west side of the peninsula and is identified as a response to recorded increase in precipitation and accumulation. These results validate the capability of SAR data for deriving superficial parameters of glaciers to be used as indicators of climatic changes in high-latitude regions where operational restrictions limit conventional meteorological observations.