Lu-Hf garnet geochronology of eclogites from the Balma Unit (Pennine Alps): implications for Alpine paleotectonic reconstructions

Three samples of eclogite from the Balma Unit, an ophiolite sheet on top of the Monte Rosa Nappe in the Pennine Alps, were investigated in terms of their P-T evolution, geochemistry, and Lu-Hf geochronology. The paleogeographic origin of this unit is controversial (North Penninic vs. South Penninic). It has been interpreted as a piece of Late Cretaceous oceanic crust, on the basis of ca. 93 Ma U-Pb SHRIMP ages of synmagmatic zircon cores in an eclogite. Trace element and isotope data suggest a mid ocean ridge (MOR) rather than an intraplate or OIB setting for the protoliths of the eclogites. Electron microprobe analyses of representative garnets show typical prograde zoning profiles. Estimated peak metamorphic temperatures of 550–600 Cº most likely did not exceed the closure temperature of the Lu-Hf system. Hence, Lu-Hf ages most likely reflect garnet growth in the studied samples. To minimize inclusion effects on age determinations, a selective digestion procedure for garnet was applied, in which zircon and rutile inclusions are not dissolved. The ages obtained for three samples, 42.3 ± 0.6 Ma (MSWD: 0.47), 42 ± 1 Ma (MSWD: 3.0) and 45.5 ± 0.3 Ma (MSWD: 0.33), are younger than all Lu-Hf ages reported so far for South Penninic Units. Metamorphic zircon domains of the 42.3 Ma sample (PIS1) were previously dated by U-Pb SHRIMP at 40.4 ± 0.7 Ma, indicating that the growth of metamorphic zircon post-dated the onset of garnet growth.These new data put important constraints on the paleogeographic reconstruction of the Alps. The MORB character of the rocks, together with their previously published protolith age, imply that oceanic spreading was still taking place in the Late Cretaceous. This supports a North Penninic origin for our samples because plate tectonic models predict Cretaceous spreading in the North Penninic but not in the South Penninic Ocean. If the Balma Unit is indeed North Penninic, the new Lu-Hf data, in combination with published geochronological data, require that two independent subduction zones consumed the South and North Penninic oceans.     

Extracting central places from the link structure in Wikipedia

Explicit information about places is captured in an increasing number of geospatial datasets. This article presents evidence that relationships between places can also be captured implicitly. It demonstrates that the hierarchy of central places in Germany is reflected in the link structure of the German language edition of Wikipedia. The official upper and middle centers declared, based on German spatial laws, are used as a reference dataset. The characteristics of the link structure around their Wikipedia pages, which link to each other or mention each other, and how often, are used to develop a bottom‐up method for extracting central places from Wikipedia. The method relies solely on the structure and number of links and mentions between the corresponding Wikipedia pages; no spatial information is used in the extraction process. The output of this method shows significant overlap with the official central place structure, especially for the upper centers. The results indicate that real‐world relationships are in fact reflected in the link structure on the web in the case of Wikipedia.     

Nitrate reduction potential of a fractured Middle Triassic carbonate aquifer in Southwest Germany

Hydrogeology Journal - Nitrate reduction constitutes an important natural mechanism to mitigate the widespread and persistent nitrate contamination of groundwater resources. In fractured aquifers,...     

Timing of the Last-Interglacial High Sea Level on the Seychelles Islands, Indian Ocean

Corals from the Seychelles Islands, Indian Ocean, occur mainly as small coralline algae–vermetid remnants found in cavities adhering to the rock surface, and they rarely attain more than 2 m²in area. Samples ofGoniastreaandPoritesfrom elevations between 1.7 and 6 m above present mean sea level were dated by TIMS²³⁸U–²³⁴U–²³⁰Th techniques. The ages from well-preserved corals lie between 131,000 and 122,000 yr B.P., in agreement with most other observations of the last-interglacial sea level. Field evidence and dating from high marine limestones from two sections at La Digue Island indicate a period of coral buildup until 131,000 yr B.P., followed by a drop in sea level between 131,000 and 122,000 yr B.P.     

On equilibrium rotation of the central object of an accretion disc

The hydrodynamic interaction of an accretion disc with its central object is reanalysed within the framework of the slim-disc approximation. Arguments are presented against an interpretation of the total angular momentum flux as an eigenvalue of the system. A simple intuitive consideration is provided, which shows that the central object may be in a state of stationary rotation even if the disc imposes the constraint of a finite angular momentum flux into it. It is argued that equilibrium rotation is characterized by vanishing viscous torque rather than by zero total angular momentum flux. As a consequence, the central object can be in a state of stationary rotation below the break-up limit, although its angular momentum increases. Despite accretion, even for positive total angular momentum flux and subcritical rotation, central objects are spun down within a considerable range of their parameters. The results are illustrated by application to FU Orionis systems.     

Simultaneous quantification of epistemic and aleatory uncertainty in GMPEs using Gaussian process regression

This paper presents a Bayesian non-parametric method based on Gaussian Process (GP) regression to derive ground-motion models for peak-ground parameters and response spectral ordinates. Due to its non-parametric nature there is no need to specify any fixed functional form as in parametric regression models. A GP defines a distribution over functions, which implicitly expresses the uncertainty over the underlying data generating process. An advantage of GP regression is that it is possible to capture the whole uncertainty involved in ground-motion modeling, both in terms of aleatory variability as well as epistemic uncertainty associated with the underlying functional form and data coverage. The distribution over functions is updated in a Bayesian way by computing the posterior distribution of the GP after observing ground-motion data, which in turn can be used to make predictions. The proposed GP regression models is evaluated on a subset of the RESORCE data base for the SIGMA project. The experiments show that GP models have a better generalization error than a simple parametric regression model. A visual assessment of different scenarios demonstrates that the inferred GP models are physically plausible.     

Mass occurrence of the recent brachiopod Magellania venosa (Terebratellidae) in the fjords Comau and Reñihué, northern Patagonia,Chile

Mass occurrences of the terebratellid brachiopod Magellania venosa with more than 200 individuals·m^?2 are reported from the fjords Comau and Reñihué in the northernmost region of the Chilean fjordland, whereas more southern fjords do not show these high numbers of the largest living brachiopod. This is an exception to earlier observations that the abundance of M. venosa on the Chilean shelf is positively correlated with increasing latitude. As the sympatric scleractinian coral Desmophyllum dianthus also occurs in unusually high numbers in the fjords Comau and Reñihué, the hydrographical regime and its associated environmental conditions in these fjords may be responsible for these mass occurrences.     

Determination of Scandium, Yttrium and Rare Earth Elements in Rocks by High Resolution Inductively Coupled Plasma-Mass Spectrometry

The high sensitivity, minimal oxide formation and single internal standard capability of high resolution inductively coupled plasma-mass spectrometry (HR-ICP-MS) is demonstrated in the direct determination of Sc, Y and REE in the international reference materials: basalts (BCR-1, BHVO-1, BIR-1, DNC-1), andesite (AGV-1) andultramafics (UB-N, PCC-1 and DTS-1). Time consuming ion exchange separation or preconcentration were found to be unnecessary. Smooth chondrite normalized plots of the REE in PCC-1 and DTS-1 were obtained in the range 0.8-50 ng g-1 (0.01-0.1x chondrite). Method precision was found to be digestion dependent with an average external repeatability of 2-4% for the basalts, AGV-1 and UB-N, and 10% for PCC-1 and DTS-1. The mass peak due to ⁴⁵Sc was completely resolved from ²⁹Si¹⁶O and ²⁸Si¹⁶O¹H spectral interferences using medium resolution, which casts doubt on the accuracy of Sc determinations using quadrupole ICP-MS. Literature values for Y in rock reference materials were found to be approximately 9% high after HR-ICP-MS and XRF analysis.