Design and Production of an Atlas for Diplomacy in Zimbabwe and The Southern African Development Community

Abstract

An atlas of Zimbabwe and the Southern African Development Community was designed and produced for use by American diplomats in Zimbabwe. Two copies of the bound atlas are used by the Embassy of the United States of America (U.S. Embassy) and the Mission of the U.S. Agency for International Development (USAID) in Harare, Zimbabwe, to orient visitors and discuss matters of diplomacy and development in Zimbabwe and the Southern African Development Community. The atlas contains maps derived from satellite images showing features of the physical geography of Southern Africa and Zimbabwe and plastic overlays showing rivers and lakes and manmade features, such as major roads, railroads, and cities. The atlas is an important tool that American diplomats can use to orient participants in discussions of the environment and to develop agreements for management of the environment in Zimbabwe and Southern Africa.     

Impacts of Climate-Related Drivers on the Benthic Nutrient Filter in a Shallow Photic Estuary

In shallow photic systems, the benthic filter, including microphytobenthos and denitrifiers, is important in preventing or reducing release of remineralized NH₄ ⁺ to the water column. Its effectiveness can be impacted by climate-related drivers, including temperature and storminess, which by increasing wind and freshwater delivery can resuspend sediment, reduce salinity and deliver nutrients, total suspended solids, and chromophoric dissolved organic matter (CDOM) to coastal systems. Increases in temperature and freshwater delivery may initiate a cascade of responses affecting benthic metabolism with impacts on sediment properties, which in turn regulate nitrogen cycling processes that either sequester (via microphytobenthos), remove (via denitrification), or increase sediment nitrogen (via remineralization, nitrogen fixation, and dissimilatory nitrate reduction to ammonium). We conducted a seasonal study at shallow stations to assess the effects of freshwater inflow, temperature, wind, light, and CDOM on sediment properties, benthic metabolism, nitrogen cycling processes, and the effectiveness of the benthic filter. We also conducted a depth study to constrain seasonally varying parameters such as temperature to better assess the effects of light availability and water depth on benthic processes. Based on relationships observed between climatic drivers and response variables, we predict a reduction in the effectiveness of the benthic filter over the long term with feedbacks that will increase effluxes of N to the water column with the potential to contribute to system eutrophication. This may push shallow systems past a tipping point where trophic status moves from net autotrophy toward net heterotrophy, with new baselines characterized by degraded water quality.     

The groundwater geochemistry of the Bengal Basin: Weathering, chemsorption, and trace metal flux to the oceans

Sixty-eight groundwater samples from the Ganges-Brahmaputra floodplain in the Bengal Basin were analyzed to assess the groundwater geochemistry, the subsurface hydrology, the buffering effects of sediments on trace metal concentrations and their isotopic compositions, and the magnitude of the subsurface trace element flux to the Bay of Bengal and to the global ocean. Samples obtained from depths of 10 to 350 m were measured for major and trace elements, dissolved gas, and tritium. On the basis of the ³He/³H ages, the groundwater at depth (30-150 m) appears to be continually replenished, indicating that this recharge of groundwater to depth must ultimately be balanced by a significant quantity of submarine discharge into the Bay of Bengal. Using the ³He/³H groundwater age-depth relationship to calculate a recharge rate of 60 ± 20 cm/yr, we estimate a subsurface discharge into the Bay of Bengal of 1.5 ± 0.5 × 10¹¹ m³/yr, or 15% of the surface Ganges-Brahmaputra river (GBR) flux. Several trace elements, especially Sr and Ba, display elevated concentrations averaging 7 to 9 times the surface GBR water values. The submarine groundwater fluxes of Sr and Ba to the oceans are 8.2 ± 2 × 10⁸ and 1.5 ± 0.3 × 10⁸ mol/yr, or 3.3 and 1.2%, respectively, of the world total, or equal to the surface GBR Sr and Ba estimated fluxes. Our groundwater flux for Ba agrees with the estimate of Moore (1997) (3 × 10⁸-3 × 10⁹ mol/yr), on the basis of measured Ba and Ra excesses in the Bay of Bengal. Other trace metals, such as U and Mo, are at low but measurable levels and are not major contributors to the global flux in this river system. A comparison of the Sr and Ba concentrations, plus ⁸⁷Sr/⁸⁶Sr ratios in groundwater to the oxalate extractable fractions of a coastal sediment core, suggests that weathering of carbonates and minor silicates, coupled with cation exchange plus adsorption and desorption reactions, controls the trace element concentrations and ⁸⁷Sr/⁸⁶Sr isotopic compositions in both the groundwater and river water. Our data also imply that other coastal floodplains (e.g., the Mekong and the Irrawaddy rivers) that have high precipitation rates and rapid accumulation of immature sediments are likely to make significant contributions to the global oceanic trace metal budgets and have an impact on the Sr isotopic evolution in seawater.     

Multivariate Analysis of Water Quality and Plankton Assemblages in an Urban Estuary

Raritan Bay, located between the states of New York and New Jersey, has a long history of cultural eutrophication and associated harmful algal blooms (HABs). Despite striking chemical and biological alterations occurring in Raritan Bay, publications in the early 1960s were the last to report consecutive measurements of both water quality parameters and plankton species composition in this system. The objectives of this study were to characterize water quality trends and plankton composition in a eutrophic estuary, compare current environmental conditions to those documented in Raritan Bay 50 years ago (i.e., at the same six sampling sites), and to further clarify the relationship among nutrients, secondary consumers, and algal bloom generation in this system using ordination techniques. This study (monthly data collected from April 2010–October 2012) indicates that Raritan Bay continues to exhibit numerous symptoms of eutrophication, including high algal biomass, high turbidity, violations of the dissolved oxygen standard to protect fish health, and blooms of potentially harmful phytoplankton species. Altered spatial and temporal patterns for nitrate and soluble reactive phosphorus (SRP) over the past 50 years may suggest new, changing, or expanding sources of nutrients. A total of 14 HAB species have been identified, including Heterosigma akashiwo, which formed a bloom in the upper Raritan Bay during summer 2012 in association with hypoxic conditions. Multivariate analyses indicate that abundance of this species is positively associated with high temperature, salinity, nitrate, and SRP and negatively associated with spring river discharge rates and total zooplankton abundance in Raritan Bay.     

Petroleum systems modeling in tectonically complex areas — A 2D migration study from the Neuquen Basin, Argentina

A roughly 30 km 2D section across the Faja Plegada y Corrida del Agrio in the Neuquen Basin, Argentina, is the basis for a petroleum systems study, including structural restoration through time, deposition and erosion, pressure, temperature and migration modeling. Integrating tectonic and petroleum systems modeling proved critical to properly evaluate sub-thrust plays. Multi-dimensional modeling of dynamic processes allows accurate assessment and prediction of the potential of petroleum systems in tectonically complex areas such as the Neuquen Basin.     

Grain size partitioning of metals in contaminated,coarse-grained river floodplain sediment: Clark Fork River,Montana, U.S.A.

The traditional concept of the relationship between metal content and grain size assumes that the fine fraction carries most of the metals in natural sediments. This concept is supported in many cases by strong, significant linear relationships between total-sediment metal concentrations and percentages of various fine-size fractions. Such observations have led to development of methods to correct for the effects of grain size in order to accurately document geographical and temporal variations and identify trends in metal concentrations away from a particular source. Samples from the floodplain sediment of a large, coarse-grained river system indicates that these concepts do not hold for sediments contaminated by mining and milling wastes. In this particular system, the application of methods to correct for grain-size effects would lead to erroneous conclusions about trends of metals in the drainage. This indicates that the a priori application of grain-size correction factors limits interpretation of actual metal distributions and should not be used unless data indicate that correlations exist between metals and particular size fractions.     

Saturn's south polar vortex compared to other large vortices in the Solar System

Observations made by the Imaging Science Subsystem (ISS), Visible and Infrared Mapping Spectrometer (VIMS) and the long-wavelength Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft reveal that the large, long-lived cyclonic vortex at Saturn's south pole has a 4200-km-diameter cloud-free nearly circular region. This region has a 4 K warm core extending from the troposphere into the stratosphere, concentric cloud walls extending 20-70 km above the internal clouds, and numerous external clouds whose anticyclonic vorticity suggests a convective origin. The rotation speeds of the vortex reach . The Saturn polar vortex has features in common with terrestrial hurricanes and with the Venus polar vortex. Neptune and other giant planets may also have strong polar vortices.     

Population studies of the unidentified EGRET sources

The third EGRET catalog contains a large number of unidentified sources. This subset of objects is expected to include known gamma-ray emitters of Galactic origin such as pulsars and supernova remnants, in addition to an extragalactic population of blazars. However, current data allows the intriguing possibility that some of these objects may represent a new class of yet undiscovered gamma-ray sources. Many theoretically motivated candidate emitters (e.g. clumps of annihilating dark matter particles) have been suggested to account for these detections. We take a new approach to determine to what extent this population is Galactic and to investigate the nature of the possible Galactic component. By assuming that galaxies similar to the Milky Way should host comparable populations of objects, we constrain the allowed Galactic abundance and distribution of various classes of gamma-ray sources using the EGRET data set. We find it is highly improbable that a large number of the unidentified sources are members of a Galactic halo population, but that a distribution of the sources entirely in the disk and bulge is plausible. Finally, we discuss the additional constraints and new insights that GLAST will provide.     

Dating very young planetary surfaces from crater statistics: A review of issues and challenges

Determining the ages of young planetary surfaces relies on using populations of small, often sub-km diameter impact craters due to the higher frequency at which they form. Smaller craters however can be less reliable for estimating ages as their size-frequency distribution is more susceptible to alteration with debate as to whether they should be used at all. With the current plethora of meter-scale resolution images acquired of the lunar and Martian surfaces, small craters have been widely used to derive model ages to establish the temporal relation of recent geologic events. In this review paper, we discuss the many factors that make smaller craters particularly challenging to use and should be taken into consideration when crater counts are confined to small crater diameters. Establishing confidence in a model age ultimately requires an understanding of the geologic context of the surface being dated as reliability can vary considerably and limitations of the dating technique should be considered in applying ages to any geologic interpretation.     

Waves in Jupiter's atmosphere observed by the Cassini ISS and CIRS instruments

The Cassini Imaging Science Subsystem (ISS) and Composite Infrared Spectrometer (CIRS) reported a North Equatorial Belt (NEB) wave in Jupiter's atmosphere from optical images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] and thermal maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135], respectively. The connection between the two waves remained uncertain because the two observations were not simultaneous. Here we report on simultaneous ISS images and CIRS thermal maps that confirm that the NEB wave shown in the ISS ultraviolet (UV1) and strong methane band (MT3) images is correlated with the thermal wave in the CIRS temperature maps, with low temperatures in the CIRS maps (upwelling) corresponding to dark regions in the UV1 images (UV-absorbing particles) and bright regions in the MT3 images (high clouds and haze). The long period of the NEB wave suggests that it is a planetary (Rossby) wave. The combined observations from the ISS and CIRS are utilized to discuss the vertical and meridional propagation of the NEB wave, which offers a possible explanation for why the NEB wave is confined to specific latitudes and altitudes. Further, the ISS UV1 images reveal a circumpolar wave centered at 48.5° S (planetocentric) and probably located in the stratosphere, as suggested by the ISS and CIRS observations. The simultaneous comparison between the ISS and CIRS also implies that the large dark oval in the polar stratosphere of Jupiter discovered in the ISS UV1 images [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547] is the same feature as the warm regions at high northern latitudes in the CIRS 1-mbar temperature maps [Flasar, F.M., and 39 colleagues, 2004. Nature 427, 132-135]. This comparison supports a previous suggestion that the dark oval in the ISS UV1 images is linked to auroral precipitation and heating [Porco, C.C., and 23 colleagues, 2003. Science 299, 1541-1547].