Characterisation of dispersed organic matter from lower Palaeozoic metasedimentary rocks by organic petrography, X-ray diffraction and micro-Raman spectroscopy analyses

Dispersed organic matter (DOM) concentrates of C-rich rocks from areas with different metamorphic characteristics were studied by organic petrography, X-ray diffraction (XRD) and micro-Raman spectroscopy analysis. The concentrates contain several types of DOM with different morphologies, reflectance, X-ray diffraction and micro-Raman characteristics.Four different morphological types were identified in the two studied areas. The different types have different distributions and their reflectance is quite variable in the four types, with a dominance of the highest reflectance values in the DOM from the area with the highest metamorphic grade.XRD analyses of samples from the areas reveal the presence of fine graphite together with non-graphitised carbons.The Raman spectral profiles show the usual bands G (1582 cm⁻¹) and D1 (1350 cm⁻¹), on the first-order Raman spectrum, and S1 (2700 cm⁻¹) on the second-order spectrum. Additional weaker bands, D2 (1620 cm⁻¹), and more rarely D3 (1500 cm⁻¹) and S2 (2900 cm⁻¹), are present. These are characteristic for disordered carbons in the different types of DOM and in both studied areas. However, the Raman parameters (D1/G intensity area ratio and the frequency and width of G band) indicate variable degrees of organisation in all DOM types.The existence of different types of DOM with different degrees of ordering in the same lithologies and metamorphic grade seems to be related to different organic precursors, as they are graphitised to different extents under the same metamorphic conditions. However, in the same lithologies and metamorphic grade, the existence of various stages of graphitisation within the same type of DOM can only be explained though the interaction of DOM with the metamorphic fluids present in the rocks. The ordering graphitisation process may be due to the existence of metamorphic fluid circulation events with a variety of compositions.     

Egg production of the copepodAcartia tonsa in Florida Bay during summer. 1. The roles of food environment and diet

The diet and egg production rate ofAcartia tonsa were measured during the thermally stable period between June and October 1995 at four locations in inner and outer Florida Bay. We sought to characterize the role ofA. tonsa in the bay’s pelagic food web, which has been changing since 1987, when the dominant submerged vegetation began shifting from benthic seagrasses to planktonic algae. At Rankin Lake, a shallow basin on the north side of the inner bay, where extensive seagrass mortality and persistent cyanobacteria blooms have occurred, microplankton biomass was relatively high and dominated by heterotrophic protists and dinoflagellates. Nanoplankton at Rankin, Lake, while numerically abundant, usually contributed only a small portion of the biomass. The ingestion rate ofA. tonsa in Florida Bay varied independently of food concentration (i.e., total microplankton biomass), but rates were higher (mean±SD =3.88 ± 0.73 μg C copepod^?1 d^?1) on the north side of the bay than on the south side (0.78 ±0.11 μg C copepod^?1 d^?1). Microzooplankton and dinoflagellates were important dietary constituents, especially in the vicinity of Rankin Lake. Egg production in this region (mean ± SD = 14.2 ± 7.7 eggs female^?1 d^?1) was considerably high than the baywide mean (5.8±0.81 eggs female^?1d^?1), and principal components analysis revealed associations between egg production and both dietary microzooplankton and dinoflagellate biomass. However, although grazing rates were relatively high in the inner bay,A. tonsa removed only 1–6% of the primary production from the water column during the summer and its egg production rates were low relative to typical rates for the species.     

Analysis of the liquefaction phenomena in the village of Vittorito (L��Aquila)

This paper describes a case-history of liquefaction occurred near the village of Vittorito after the April 6, 2009 L’Aquila earthquake (moment magnitude M_w = 6.3), approximately 45 km far from the epicentre. In the document, first, an estimation of the seismic motion in the area has been made. Thereafter, the performed geotechnical investigation is described, followed by the application of some fast assessment criteria for the occurrence of liquefaction, recently proposed by the new Italian Building Code. A careful assessment of all the parameters involved in conventional Seed and Idriss (1971) liquefaction analyses is considered. The cyclic resistance ratio CRR is evaluated by cone penetration tests CPT and by in situ seismic dilatometer tests SMDT; in the latter case CRR is evaluated by different empirical correlations with shear wave velocity V_s and horizontal stress index K_D. Analytical data confirmed the observed occurrence of the liquefaction in Vittorito, even if the acceleration field in the area, produced by the L’Aquila earthquake, was very low.     

Re-testing the JET-X Flight Module No. 2 at the PANTER facility

The Joint European X-ray Telescope (JET-X) was the core instrument of the Russian Spectrum-X- γ space observatory. It consisted of two identical soft X-ray (0.3–10 keV) telescopes with focusing optical modules having a measured angular resolution of nearly 15 arcsec. Soon after the payload completion, the mission was cancelled and the two optical flight modules (FM) were brought to the Brera Astronomical Observatory where they had been manufactured. After 16 years of storage, we have utilized the JET-X FM2 to test at the PANTER X-ray facility a prototype of a novel X-ray polarimetric telescope, using a Gas Pixel Detector (GPD) with polarimetric capabilities in the focal plane of the FM2. The GPD was developed by a collaboration between INFN-Pisa and INAF-IAPS. In the first phase of the test campaign, we have re-tested the FM2 at PANTER to have an up-to-date characterization in terms of angular resolution and effective area, while in the second part of the test the GPD has been placed in the focal plane of the FM2. In this paper we report the results of the tests of the sole FM2, using an unpolarized X-ray source, comparing the results with the calibration done in 1996.     

A nonlinear programming analysis of unconfined steady-state seepage

A finite element, variable mesh analysis of unconfined steady-state seepage problems is presented based on a nonlinear programming algorithm. It is shown that the minimization of an objective function which merely represents a measure of the total flux leaving or entering the mesh at the free surface nodes (except those that belong also to pervious boundaries) does not permit a unique definition of the free surface geometry. This problem, which is apparently related to the numerical instabilities often met when using variable mesh approaches, can be eliminated by adding to the objective function a term representing a sort of overall ‘regularity’ condition for the shape of the free surface. The modified solution procedure turns out to be stable and able to provide meaningful results for practical problems even when rather coarse meshes are adopted.     

Monitoring Seismo-volcanic and Infrasonic Signals at Volcanoes: Mt. Etna Case Study

Volcanoes generate a broad range of seismo-volcanic and infrasonic signals, whose features and variations are often closely related to volcanic activity. The study of these signals is hence very useful in the monitoring and investigation of volcano dynamics. The analysis of seismo-volcanic and infrasonic signals requires specifically developed techniques due to their unique characteristics, which are generally quite distinct compared with tectonic and volcano-tectonic earthquakes. In this work, we describe analysis methods used to detect and locate seismo-volcanic and infrasonic signals at Mt. Etna. Volcanic tremor sources are located using a method based on spatial seismic amplitude distribution, assuming propagation in a homogeneous medium. The tremor source is found by calculating the goodness of the linear regression fit (R ²) of the log-linearized equation of the seismic amplitude decay with distance. The location method for long-period events is based on the joint computation of semblance and R ² values, and the location method of very long-period events is based on the application of radial semblance. Infrasonic events and tremor are located by semblance–brightness- and semblance-based methods, respectively. The techniques described here can also be applied to other volcanoes and do not require particular network geometries (such as arrays) but rather simple sparse networks. Using the source locations of all the considered signals, we were able to reconstruct the shallow plumbing system (above sea level) during 2011.     

The role of friction in the seismic risk mitigation of freestanding art objects

The problem of reducing the seismic risk for art objects, that are the objects generally contained within Museums, is of great interest. The first studies were performed in Japan and were successively organized in a general framework by a research program performed at Southern California University and sponsored by the Getty Museum at Malibu, California. In these papers and in the following Italian studies, the theoretical models for the problem concerning vases and statues are based on the dynamic behavior of rigid blocks and have been deeply developed. Unfortunately, because of the great lack of experimental data, determinant parameters for the problem characterization (like the friction between two superimposed blocks or between the art object and the support plane) are often assumed without reference to real values derived from laboratory tests. This paper presents the results of a research program containing the experimental determination of the friction coefficient between the art object and the support (by means of a testing apparatus on purpose realized) together with dynamic tests performed on simple-shaped objects made of different materials. The dynamic tests were performed using an unidirectional shaking table and different supporting surfaces, so that the influence of different friction coefficients has been analyzed.     

Regimes of magma recharge and their control on the eruptive behaviour during the period 2001–2005 at Mt. Etna volcano

Mount Etna volcano (Italy) during the period 2001–2005 has undergone a period of intense eruptive activity marked by three large eruptions (2001, 2002–2003 and 2004–2005). These eruptions encompassed diverse eruptive styles and regimes: from intensely explosive, during 2001 and 2002–2003 eruptions, to exclusively effusive in the 2004–2005 event. In this work, we put forward the idea that these three eruptions are the response of the progressive arrival into the uppermost segment of the open-conduit system of a new magma, which was geochemically distinct in terms of trace element and Sr–Nd–Pb isotope signature from the products previously emitted by the Etnean volcano. The magma migrated upwards mainly through a peripheral tectonic system, which can be considered as eccentric in spite of its relative proximity to the main system. The ingress of the new magma and its gradual displacement from the eccentric system into the uppermost sector of the open-conduit gave rise to different eruptive behaviours. At the beginning, the ascent of the undegassed magma, able to exsolve a gas phase at depth, and its interaction with closed-system magma reservoirs less than 10 km deep gave rise to the explosive events of 2001 and 2002–2003. Later, when the same magma entered into the open-conduit system, it took part in the steady-state degassing and partially lost its volatile load, leading to a totally effusive eruption during the 2004–2005 event. One further consideration highlighted here is that in 2001–2005, migration of the feeding axis from an eccentric and peripheral position towards the main open-conduit has led to the development of a new vent (South East Crater 2) located at the eastern base of the South East Crater through which most of the subsequent Etnean activity occurred.