Halogen diffusion in a basaltic melt

The diffusion of the halogens fluorine, chlorine and bromine was measured in a hawaiitic melt from Mt. Etna at 500 MPa and 1.0 GPa, 1250 to 1450 °C at anhydrous conditions; the diffusion of F and Cl in the melt was also studied with about 3 wt% of dissolved water. Experiments were performed using the diffusion-couple technique in a piston cylinder. Most experiments were performed with only one halogen diffusing between the halogen-enriched and halogen-poor halves of the diffusion couple, but a few experiments with a mixture of halogens (F, Cl and Br) were also performed in order to investigate the possibility of interactions between the halogens during diffusion. Fluorine and chlorine diffusivity show a very similar behavior, slightly diverging at low temperature. Bromine diffusion is a factor of about 2-5 lower than the other halogens in this study. Diffusion coefficients for fluorine range between 2.3 × 10⁻¹¹ and 1.4 × 10⁻¹⁰ m² s⁻¹, for chlorine between 1.1 × 10⁻¹¹ and 1.3 × 10⁻¹⁰ and for bromine between 9.4 × 10⁻¹² and 6.8 × 10⁻¹¹ m² s⁻¹. No pressure effect was detected at the conditions investigated. In experiments involving mixed halogens, the diffusivities appear to decrease slightly (by a factor of ∼3), and are more uniform among the three elements. However, activation energies for diffusion do not appear to differ between experiments with individual halogens or when they are all mixed together. The effect of water increases the diffusion coefficients of F and Cl by no more than a factor of 3 compared to the anhydrous melt (D_F = 4.0 × 10⁻¹¹ to 1.6 × 10⁻¹⁰ m² s⁻¹; D_Cl = 3.0 × 10⁻¹¹ to 1.9 × 10⁻¹⁰ m² s⁻¹). Comparing our results to the diffusion coefficients of other volatiles in nominally dry basaltic melts, halogen diffusivities are about one order of magnitude lower than H₂O, similar to CO₂, and a factor of ∼5 higher than S. The contrasting volatile diffusivities may affect the variable extent of volatile degassing upon melt depressurization and vesiculation, and can help our understanding of the compositions of rapidly grown magmatic bubbles.     

CO<Subscript>2</Subscript>-driven large mafic explosive eruptions: the Pozzolane Rosse case study from the Colli Albani Volcanic District (Italy)

Generally, the intensity and magnitude of explosive volcanic activity increase in parallel with SiO₂ content. Pyroclastic-flow-forming eruptions in the Colli Albani ultrapotassic volcanic district (Italy) represent the most striking exception on a global scale, with volumes on the order of tens of cubic kilometres and K-foiditic compositions (SiO₂ even <42 wt.%). Here, we reconstruct the pre-eruptive scenario and event dynamics of the ~456 ka Pozzolane Rosse (PR) eruption, the largest mafic explosive event of the Colli Albani district. In particular, we focus on the driving mechanisms for the unusually explosive eruption of a low-viscosity, mafic magma. Geologic, petrographic and geochemical data with mass balance calculations, supported by experimental data for Colli Albani magma compositions, provide evidence for significant ingestion of carbonate wall rocks by the Pozzolane Rosse K-foiditic magma. Moreover, the scattered occurrence of cored bombs in Pozzolane Rosse pyroclastic-flow deposits records carbonate entrainment even at the eruptive time scale, as also tested quantitatively by thermal modelling of magma–carbonate interaction and carbonate assimilation experiments. We suggest that the addition of free CO₂ from decarbonation of country rocks was the major factor controlling magma explosivity. High CO₂ activity in the volatile component, coupled with magma depressurisation, produced extensive leucite crystallisation at short time scales, resulting in a dramatic increase in magma viscosity and volatile pressurisation, which was manifested a change of eruptive dynamics from early effusion to the Pozzolane Rosse's highly explosive eruption climax.     

LARAM School 2018: the doctoral school on “LAndslide Risk Assessment and Mitigation”

The international school for PhD students and young doctors on “LAndslide Risk Assessment and Mitigation” (LARAM) is presented and, specifically, information is provided about the next edition of the doctoral school that will held in Italy, at the University of Salerno, on September 3–14, 2018. The LARAM School is managed by the Geotechnical Engineering Group (GEG) of the University of Salerno, which recently became an Associate member of the International Consortium on Landslides (ICL). The 2018 edition of the LARAM School is organised as an ICL/IPL activity.     

Origin of crystal-poor, differentiated magmas: insights from thermal gradient experiments

Crystal-poor, differentiated magmas are commonly erupted from shallow, thermally zoned magma chambers. In order to constrain the origin of these magmas, we have experimentally investigated crystallization, differentiation and crystal-melt separation in presence of a thermal gradient. Experiments have been designed taking advantage of the innate temperature gradient of the piston cylinder apparatus and carried out on a phonolitic system at 0.3 GPa and temperature ranging from 1,050 to 800°C. Crystallization degree and melt composition in experimental products vary as a function of the temperature gradient. In particular, melt composition differentiates from tephri-phonolite (starting material) to phonolite moving from the hotter, glassy zone (T ≤ 1,050°C) towards the cooler, heterogeneously crystallized zone (T ≤ 900°C) of the charge. The heterogeneously crystallized zone is made up of: (1) a crystal-rich, mushy region (crystallinity >30 vol%), (2) a rigid crystal framework (crystallinity ≤80 vol%) and (3) glassy belts of phonolitic glass at the top. Thermal gradient experiments picture crystallization, differentiation and crystal-melt separation processes occurring in a thermally zoned environment and reveal that relatively large volumes of crystal-poor melt (glassy belts) can originate as a consequence of the instability and collapse of the rigid crystal framework. Analogously, in thermally zoned magma chambers, the development and collapse of a solidification front may represent the controlling mechanism originating large volumes of crystal-poor, differentiated magmas.     

Detecting Stochastic Behaviour and Scaling Laws in Time Series of Geomagnetic Daily Means

—We use advanced methods to extract quantitative time dynamics from geomagnetic signals. In particular we analyse daily geomagnetic time series measured at three stations in Norway. The dynamics of geomagnetic measurements has been investigated using autoregressive models. The procedure is based on two forecasting approaches: the global autoregressive approximation and the local autoregressive approximation. The first technique views the data as a realisation of a linear stochastic process, whereas the second considers them as a realisation of a deterministic process, supposedly non-linear. The comparison of the predictive skill of the two techniques is a strong test to discriminate between low-dimensional chaos and stochastic dynamics. Our findings suggest that the physical system governing the phenomena is characterised by a stochastic dynamics, and the process could be described by numerous degrees of freedom. We also investigated the kind of stochasticity of the geomagnetic signals, analysing the power spectrum density. We identify a power law P(?)∝?^-α, with the scaling exponent α which is a typical fingerprint of irregular processes. In this analysis we use the Higuchi method, which presents an interesting relationship between the fractal dimension D and the spectral power law scaling index α.     

Using hydro‐chemograph analyses to reveal runoff generation processes in a Mediterranean catchment

The paper deals with the hydro‐chemical analysis performed in order to reveal processes, sources, paths and timing of the runoff generation in an experimental catchment representative of the hilly, terrigenous and forested watershed in the Mediterranean humid eco‐region of southern Italy. The analysis is based on the data recorded at the outlet of the catchment during 2013–2014. A mixing law procedure was applied on discharge (Q) and electrical conductivity (EC) data, by using the Q–EC end members previously collected at selected groundwater, sub‐surficial and surficial stations. In this way, we found four bound curves delimiting fields in a Q–EC plot, each with hydro‐chemograph value ranges. At annual time scale, the analysis revealed a seasonal behaviour of the hydrological response, different for the wet period, when the aquifer is recharging, and the dry periods, when the aquifer is discharging, despite frequent summer rain showers. At event time scale, the catchment seems to show the behaviour of a typical hydro‐geomorphic threshold system. We interpreted this behaviour as due to a progressive addition of water from distinctive components (i.e. deep aquifer, riparian corridor, hillslope and hollow), each with originally different mechanisms of runoff production (i.e. groundwater, groundwater ridging, saturation excess, infiltration excess and soil pipe exfiltration) and response time. During the event, the contributing areas enlarge upward the riparian corridors and the zero‐order basins, where the aforementioned components become superposed and the mechanisms interact more and more. We hypothesize that the threshold values between different states of the system are defined by the intersections of the boundary curves on the Q–EC plot. Different patterns in the Q–EC hysteretic cycles are prevalently related to the pre‐event soil saturation and groundwater contributions to stormflow and recharge mechanisms. Copyright © 2016 John Wiley & Sons, Ltd.     

Wave-in-deck loads on exposed jetties

This paper presents results from research on the hydraulic loadings of exposed (unsheltered) jetties (open pile piers with decks and beams). The work presented here focuses on results from physical model tests on wave-induced loads on deck and beam elements of exposed jetties and similar structures. These tests investigated the physics of the loading process, and provided new guidance on wave-in-deck loads to be used in design. Wave forces and pressures were measured on a 1:25 scale model of a jetty head with projecting elements. Structure geometry and wave conditions tested were selected after an extensive literature review (summarised in the paper) and consultation with the project steering group. Different configurations were tested to separate 2-d and 3-d effects, and to identify the effects of inundation and of down-standing beams.     

Large deformation FEMLIP drained analysis of a vertical cut

Understanding and modelling the whole instability mechanisms of a slope are fundamental issues from a scientific and technical viewpoint. To date, small strain Lagrangian approaches have mostly been used in solid mechanics for modelling the failure stage, whereas Eulerian approaches are common in fluid mechanics for propagation analysis. A combination of both approaches allows the stability, failure and propagation stages of a slope to be analysed in a unique mathematical framework. To this end, this paper adopts a finite element method with Lagrangian integration points (FEMLIP), which is currently implemented in the ELLIPSIS code and has been used in geophysics and civil engineering applications. The method combines the robustness of an Eulerian mesh with the flexibility of a set of Lagrangian particles, which allows the history of the material to be taken into account. FEMLIP is first validated with reference to benchmarks with analytical solutions, and is then tested in a large deformation drained analysis of a vertical cut in coarse-grained soils. The results are compared with those provided by the standard engineering methods (1) the limit equilibrium method (LEM) and (2) standard stress–strain elasto-plastic FEM analysis. The comparison shows that FEMLIP is a reliable method for the analysis of both the stability and the instability of a vertical cut, and can be confidently used to analyse more complex problems related to natural slopes.     

Polychlorinated biphenyls and organochlorine pesticides in plastics ingested by seabirds

The occurrence of plastic objects in the digestive tract was assessed in eight species of Procellariiformes collected in southern Brazil and the occurrence of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in the ingested plastics pellets and plastic fragments was evaluated. PCBs were detected in plastic pellets (491 ng g⁻¹) and plastic fragments (243-418 ng g⁻¹). Among the OCPs, p,p′-DDE had the highest concentrations, ranging from 68.0 to 99.0 ng g⁻¹. The occurrence of organic pollutants in post-consumer plastics supports the fact that plastics are an important source carrying persistent organic pollutants in the marine environment. Although transfer through the food chain may be the main source of exposure to POPs to seabirds, plastics could be an additional source for the organisms which ingest them, like Procellariiformes which are the seabirds most affected by plastic pollution.     

The Impact of Erosion on Soil Productivity—An Experimental Design Applied in São Paulo State, Brazil

Soil erosion is the principal threat to agricultural sustainability, affecting both the characteristics of the in situ soil and its productive potential. However, soils vary in their resilience and there are very few empirical data upon which to appreciate the degree and type of impact on the soil caused by erosion. This paper describes an experiment designed to generate such data based on soil loss and runoff plots, and it reports on nearly nine years of experience with the design at the Instituto Agronômico, Campinas, Brazil on a Latosol (Oxisol). After seven years of erosion induced by four levels of artificial cover, the effective rainfall on the most eroded soil was 20 percent less than on the control full cover. Crop yields were also found to be significantly affected: in 1995 by nearly 700 kg/ha and in 1996 by over 1000 kg/ha—a 50% decline in yield, amounting to a loss of 4 kg/ha of maize per tonne of cumulative soil loss. Losses of nutrients (organic C, P, K, Ca and Mg) in the runoff and eroded soil were also significant with far higher levels of loss associated with the eroded sediment. Changes in the in situ soil were less clear, but a test of trends showed that the decreases in organic matter and increases in acidity could unambiguously be attributed to soil erosion. Average enrichment ratios of the eroded sediment were 1.3 for organic C, 2.6 for P, 0.7 for K, 1.3 for Ca and 1.2 for Mg. Erosion has also affected the maize quality—mainly N, Ca and B nutrient content. Through these various measures, we conclude that seven years of induced erosion has had a marked effect on soil productivity, and for the first time we are now in a position to begin calculating the financial impact of the erosion process on future yields and farmer livelihoods.