Enceladus: Present internal structure and differentiation by early and long-term radiogenic heating

Pre-Cassini images of Saturn's small icy moon Enceladus provided the first indication that this satellite has undergone extensive resurfacing and tectonism. Data returned by the Cassini spacecraft have proven Enceladus to be one of the most geologically dynamic bodies in the Solar System. Given that the diameter of Enceladus is only about 500 km, this is a surprising discovery and has made Enceladus an object of much interest. Determining Enceladus' interior structure is key to understanding its current activity. Here we use the mean density of Enceladus (as determined by the Cassini mission to Saturn), Cassini observations of endogenic activity on Enceladus, and numerical simulations of Enceladus' thermal evolution to infer that this satellite is most likely a differentiated body with a large rock-metal core of radius about 150 to 170 km surrounded by a liquid water-ice shell. With a silicate mass fraction of 50% or more, long-term radiogenic heating alone might melt most of the ice in a homogeneous Enceladus after about 500 Myr assuming an initial accretion temperature of about 200 K, no subsolidus convection of the ice, and either a surface temperature higher than at present or a porous, insulating surface. Short-lived radioactivity, e.g., the decay of ²⁶Al, would melt all of the ice and differentiate Enceladus within a few million years of accretion assuming formation of Enceladus at a propitious time prior to the decay of ²⁶Al. Long-lived radioactivity facilitates tidal heating as a source of energy for differentiation by warming the ice in Enceladus so that tidal deformation can become effective. This could explain the difference between Enceladus and Mimas. Mimas, with only a small rock fraction, has experienced relatively little long-term radiogenic heating; it has remained cold and stiff and less susceptible to tidal heating despite its proximity to Saturn and larger eccentricity than Enceladus. It is shown that the shape of Enceladus is not that of a body in hydrostatic equilibrium at its present orbital location and rotation rate. The present shape could be an equilibrium shape corresponding to a time when Enceladus was closer to Saturn and spinning more rapidly, or more likely, to a time when Enceladus was spinning more rapidly at its present orbital location. A liquid water layer on Enceladus is a possible source for the plume in the south polar region assuming the survivability of such a layer to the present. These results could place Enceladus in a category similar to the large satellites of Jupiter, with the core having a rock-metal composition similar to Io, and with a deep overlying ice shell similar to Europa and Ganymede. Indeed, the moment of inertia factor of a differentiated Enceladus, C/MR², could be as small as that of Ganymede, about 0.31.     

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in T_max from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '¹³C_org signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.     

Modeling fluvial response to in‐stream woody vegetation: implications for stream corridor restoration

River restoration and bank stabilization programs often use vegetation for improving stream corridor habitat, aesthetic and function. Yet no study has examined the use of managed vegetation plantings to transform a straight, degraded stream corridor into an ecologically functional meandering channel. Experimental data collected using a distorted Froude‐scaled flume analysis show that channel expansion and widening, thalweg meandering and riffle and pool development are possible using discrete plantings of rigid, emergent vegetation, and the magnitudes of these adjustments depend on the shape of the vegetation zone and the density of the vegetation. These experimental results were verified and validated using a recently developed numerical model, and model output was then used to discuss mechanistically how rivers respond to the introduction of in‐stream woody vegetation. Finally, a hybrid method of meander design is proposed herein where managed vegetation plantings are used to trigger or force the desired morphologic response, transforming a straight, degraded reach into a more functional meandering corridor. It is envisioned that such numerical models could become the primary tool for designing future stream restoration programs involving vegetation and assessing the long‐term stability of such activities. Copyright © 2007 John Wiley & Sons, Ltd.     

Tectonic significance of the present relief of the Betic Cordillera

Tortonian calcarenites of the Betic Cordillera were deposited in coastal or very shallow marine environments and represent an ideal marker for estimating vertical movements from the late Miocene to the Present. A map showing the heights at which these Tortonian marine rocks are situated has a clear correlation with the present relief, indicating that today's relief has been formed since the Tortonian. There is also a good correlation between present relief and the Bouguer anomaly distribution in the Betic Cordillera, as well as with crustal thickness. Likewise, the present relief is directly related to the geodynamic setting of a horizontal N–S to NNW–SSE compression and an almost perpendicular extension, along with isostatic readjustment, existing in the Betic Cordillera from the Tortonian. As a result of these regional stresses, faults and folds have produced notable vertical movements. The highest rates of uplift of the Betic Cordillera coincide with large antiforms, in particular those of the Sierra Nevada and the Sierra Filabres. Several subsiding sectors also exist (for example, the Granada Basin or the Guadalquivir Basin). The foreland Guadalquivir Basin has a complex history because the uplift in its eastern sector and subsidence in the western sector coexisted during the late Tortonian. Today the whole Betic Cordillera is characterized by differential regional uplift, even in the aforementioned subsiding sectors.     

Cities on edge: Smuggling and neoliberal policies at the Iguazú triangle

The vision of a borderless world, of people, ideas and products freely circulating within a self‐regulating market, is one that clashes with the emerging legal regime based on the punitive force of the state. After a period of liberalization, seen in the opening of national economies and the promotion of regional trade projects and free‐trade zones, the ambivalence of neoliberalism is manifest in a borderless capitalism that ambiguously depends on the securitization of national borders. Such a changing regime of state intervention is clearly seen at the Iguazú triangle – the tri‐border urban conglomerate that straddles Brazil, Paraguay and Argentina – where the illegality of informal cross‐border trading has been tolerated for decades. Recently stepped up police raids and controls hinder the passage of people and goods, while a new fiscal regime introduced in 2009 in Brazil attempts to regularize cross‐border trafficking by turning petty smugglers into micro entrepreneurs. Petty smugglers – dubbed sacoleiros– can hardly be defined as entrepreneurs and do not constitute an identifiable category of entrepreneurship but, as typical in the informal sector, act on opportunity and need. Drawing on ethnographic research, this paper contextualizes the programmes for border controls and regularizing smuggling inspired by neoliberal ideology in South America.     

Watermarking of digital geospatial datasets: a review of technical,legal and copyright issues

Gathering data accounts for more than 80% of the cost of any GIS project. Fast Internet connections and digital datasets threaten the investments of data producers through data piracy. Outside the GIS community this problem has been known for a long time, and possible solutions exist for digital imagery, formatted text, 3D meshes and so on, showing possible links to typical spatial data. This is largely achieved through embedding hidden information in a dataset without producing perceptible changes in the data, a process known as watermarking. The producer can recover the embedded information on request in order to produce evidence of ownership in a court, so the overall strategy relies on a legal basis rather than technical ones. This paper analyses the state-of-the-art for watermarking protection in digital geographical datasets. Digital imagery is demonstrably a more mature area than geographical information, even with multiple commercial vendors offering watermarking protection. 2D vector and point datasets have received less attention from the research community; however, 3D meshes have been considered by the CAD community and a handful of techniques are available for that case, and they are reviewed here.     

Effect of agrochemicals on macroinvertebrate assemblages in Pampasic streams,Buenos Aires,Argentina

Agricultural practices have been intensified in recent decades in Argentina. The Pampa plain is the main agricultural region of the country. The effect of increased application of agrochemicals on the invertebrate fauna of the Pampasic streams remains unreported. In the present study, we compared the abundance and composition of invertebrate assemblages in seven Pampasic streams with contrasting soil use in their basins. Two streams run through intensively cropped plots, two drain basins with livestock fields, while the other three are located within a biosphere Reserve. Higher nutrient and insecticide concentrations were measured in the streams draining cropped basins, related with pesticide applications and crop fertilization. The invertebrate assemblage composition of the cropped streams differed significantly from the others and between the two. Present evidence suggests that the impact of agrochemicals results in a change in composition with decreased abundance or absence of sensitive species such as Hyalellidae, Caenidae, Baetidae and Curculionidae and increased abundance of more tolerant taxa: Ostracoda, Glossiphoniidae (Hirudinea), Ancylidae (Gundlanchia), Ampullariidae (Pomacea canaliculata), Sphaeriidae and Dugesiidae. Available information suggests that macrophyte cover and composition also influence the invertebrate assemblages of the Pampasic streams.     

Wasserchemie und Stoffwirtschaft

For the solving of the most important main tasks of water quality economy, of the supply of drinking water, industrial water and irrigation water without damaging or otherwise detrimental substances we need the available findings and results of specialized research in water chemistry. In the logical continuation of the further development up to the level of maturity for practice, the experts of the engineering disciplines have to be consulted. The design of the sequence of water treatment processes depends on the aims of the tasks set, there being increasing by raised the question concerning the possibilities of the saving and winning of energy and raw materials. — Already in the sphere of production, however, in the interest of environment protection one endeavours to achieve a direct or indirect low-waste or non-waste process design. Finally, possibilities of materials and power economy are discussed by the examples of the treatment of the wastewaters of the chemical industry and of municipal wastewaters.     

Magnetism and thermal evolution of the terrestrial planets

Of the terrestrial planets, Earth and probably Mercury possess substantial intrinsic magnetic fields generated by core dynamos, while Venus and Mars apparently lack such fields. Thermal histories are calculated for these planets and are found to admit several possible present states, including those which suggest simple explanations for the observations; whule the cores of Earth and Mercury are continuing to freeze, the cores of Venus and Mars may still be completely liquid. The models assume whole mantle convection, which is parameterized by a simple Nusselt-Rayleigh number relation and dictates the rate at which heat escapes from the core. It is found that completely fluid cores, devoid of intrinsic heat sources, are not likely to sustain thermal convection for the age of the solar system but cool to a subadiabatic, conductive state that can not maintain a dynamo. Planets which nucleate an inner core continue to sustain a dynamo because of the gravitational energy release and chemically driven convection that accompany inner core growth. The absence of a significant inner core can arise in Venus because of its slightly higher temperature and lower central pressure relative to Earth, while a Martian core avoids the onset of freezing if the abundance of sulfur in the core is ?15% by mass. All of the models presented assume that (I) core dynamos are driven by thermal and/or chemical convection; (ii) radiogenic heat production is confined to the mantle; (iii) mantle and core cool from initially hot states which are at the solidus and superliquidus, respectively; and (iv) any inner core excludes the light alloying material (sulfur or oxygen) which then mixes uniformly upward through the outer core. The models include realistic pressure and composition-dependent freezing curves for the core, and material parameters are chosen so that the correct present-day values of heat outflow, upper mantle temperature and viscosity, and inner core radius are obtained for the earth. It is found that Venus and Mars may have once had dynamos maintained by thermal convection alone. Earth may have had a completely fluid core and a dynamo maintained by thermal convection for the first 2 to 3 by, but an inner core nucleates and the dynamo energetics are subsequently dominated by gravitational energy release. Complete freezing of the Mercurian core is prohibited if it contains even a small amount of sulfur, and a dynamo can be maintained by chemical convection in a thin, fluid shell.