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41.
42.
Iron-rich concretions are frequently found around plant roots in Tagus estuary (Portugal) where radial delivery of O2 takes place. Salt marsh sediments exhibit cracks that are an additional feature to introduce O2 and other solutes in the upper sediments. Metal concentrations in salt marsh sediments are clearly above the background levels reflecting the anthropogenic sources from a large city with 2.5 million inhabitants, and several industrial centres. In order to evaluate how both oxidised structures influences the redistribution of redox sensitive elements in salt marsh sediments, concretions were collected from roots of Halimione portucaloides below the oxygenated zone. These tubular cylindrical structures were analysed for Fe, Al, Mn, As, and P along 1-cm radial transect in a millimetre scale from the inner part to the adjacent anoxic sediment. In addition, oxidised cracks were analysed for the same spatial resolution, from the sediment–water interface to anoxic layers (2-cm transept). The parallelism between Fe, As, and P concentrations at this microscale is the most noticeable aspect. Iron and As presented very high concentrations in the 4-mm concretions (3.4 mmol g−1 and 3.1 μmol g−1, respectively) and decreased sharply to the host sediment. Oxygen released from roots oxidise the solid sulphides, and the reduced Fe and As are transported towards the root by both diffusion and pore water flow associated with the root water uptake. Subsequently, Fe(III) precipitates and As is retained by sorption and/or coprecipitation. These elements are also enriched in the first 2-mm of oxidised cracks, but in lower concentrations (50% and 30%, respectively). Manganese concentrations in concretions were low (11.8 μmol g−1), indicating that Fe dominates the sediment chemistry. Phosphorus and iron concentrations in the ascorbate fraction were higher in the oxidising surfaces of concretions (10.7 μmol g−1 and 1.6 mmol g−1, respectively) and of cracks (5.1 μmol g−1 and 0.47 mmol g−1). The parallelism of Fe and As distributions includes not only their similar redox chemistries, but also that to phosphate, including control by coprecipitation of the host iron phases. The mechanisms involved in the mobilisation of As and P are however different, whereas As comes from the oxidation of iron sulphides; dissolved P derives from reduction of ferri-hydroxide phases. 相似文献
43.
Iodate (IO3−) is the predominant dissolved species of iodine in the oxygenated waters of the Mediterranean Sea. Iodide (I−) is present in significant quantities (up to 65 nM) in oxygenated waters in the photic zone and near the interface above the anoxic and saline Bannock Basin. Lesser quantities of I− (< 10 nM) are found throughout the rest of the oxic water column. An additional unidentified dissolved iodine species is present immediately above the anoxic interface.Total dissolved iodine (ΣI) increases dramatically across the seawater/brine interface. Part of this increase is undoubtedly the result of the dissolution of iodine-rich evaporites during formation of the brine bodies at the Tyro and Bannock Basins. The vertical distribution of ΣI and other dissolved chemical species (particularly PO43−) in the Bannock Basin brine, however, suggests an additional, present-day, diagenetic source of dissolved iodine to the brine. Based on the increase in the concentration of the most soluble major ions across the seawater/brine interface, 5–7 μM of the 11.5-μM increase in ΣI concentration must be attributed to diagenesis. 相似文献
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45.
埕岛油田海上石油平台基础冲刷研究 总被引:6,自引:1,他引:6
海洋石油平台的建立会改变平台周围的水动力条件,其中平台的基础及与之连接的海底管缆(输油管道、注水管道、海底电缆等)附近产生冲刷现象,对平台和海底管缆的安全造成威胁。根据对研究区典型平台的4次实洲水深并结合以往资料,分析了埕岛油田海上石油平台基础冲刷的过程及其规律。 相似文献
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47.
南海北缘东部盆地油气资源研究 总被引:5,自引:0,他引:5
南海北缘东部的珠江口盆地及台西南盆地蕴藏着十分丰富的油气资源,根据区域构造背景、盆地发育分布的特点及中、新生代的油气地质条件,结合含油气构造、油气田、油气井的分布规律,利用油气资源评价的理论、方法,对区内的油气资源进行了综合研究,并按照油气资源状况划分出油气富集区、油气潜力区、油气远景区,在此基础上,再进一步划分出4条油气富集带、11条油气潜力带、8条油气远景带,充分显示了该区石油、天然气的分布规律和油气地质特点,为商业性的勘探开发和理论研究奠定了基础。 相似文献
48.
REEdistributioninwater-sedimentinterfacesystematdeepoceanfloor¥ZhangLijie;LiuJihuaandYaoDe(ReceivedFebruary1,1994;acceptedMay... 相似文献
49.
Abstract. We describe the basic ecology of two key-hole limpets, Fissurella crassa and Fissurella limbata , which are heavily harvested by coastal shellfishermen (mariscadores) at the rocky intertidal of central Chile. The ecological role of human predation on these species was assessed. Anthropic exclusion from a stretch of the rocky intertidal at Las Cruces (non-harvested area) for about two and a half years resulted in changes of the densities and size distributions of these fissurelid species as compared to populations in control zones (harvested area). Differential human predation generates, on key-hole limpets, responses of different intensities related to the accessibility of man to the mesohabitats (sheltered platforms, exposed platforms and vertical walls) and fringes of the intertidal (mid-low intertidal and Lessonia nigrescens fringe). Thus, size distributions and mean densities of both fissurelids differ widely between the harvested and non-harvested areas on both platform habitats but not on vertical walls. In the mid-low intertidal fringe, differences are greater than in the less accessible L. nigrescens intertidal fringe. Moreover, we discuss the way in which other species, directly harvested by mariscadores (i. e., the mollusc Concholepas concholepas) can affect the keyhole limpet populations of central Chile rocky shores. Finally, we highlight the ecological role of these limpets on the dynamics of intertidal ecosystems and how they can modify community landscape. 相似文献
50.
东太平洋沉积物U的地球化学 总被引:4,自引:0,他引:4
本文对地矿部“海洋四号”科学考察船1987-1989年在东赤道太平洋CC区所取得的27个深海表层沉积样品进行U的地球化学分析,探讨了U在深海沉积中的地球化学行为,结果表明,不同类型沉积的U含量不同,平均值由大至小的次序的含沸石粘土(2.16×10^-6),硅质粘土(1.95×10^-6),硅质软泥(1.65×10^-6),钙质硅质粘土(1.59×10^-6),在同类型沉积中U的分散性较大;U在区域 相似文献