Geochemistry of actinolitic hornblendes from tonalitic rocks,Northern Portugal

Chemical analyses are given for actinolitic hornblendes of tonalitic rocks from the Hercynian belt of Northern Portugal. The distribution of elements between amphibole and co-existing biotite is studied. The composition of the amphiboles is analysed in the light of experimental data on amphiboles and the physical conditions of crystallization inferred from the study of the biotite and rock series. The data on the biotites lead to the definition of a temperature of 800°C for the crystallization of actinolitic hornblendes with Mg/(Mg + Fe) ratios of 0·72-0·61 at pressures of about 3 Kb and fO₂ defined by FMQ.     

Sedimentary evidence of deglacial megafloods in the northern Gulf of Mexico (Pigmy Basin)

Cored sediments from the Pigmy Basin, northern Gulf of Mexico, were analyzed in order to better constrain late deglacial and early Holocene paleoenvironmental and sedimentary changes in response to North American climate evolution. Mineralogical and geochemical proxies indicate the succession of two sedimentary regimes: dominantly detrital during the deglaciation (15–12.9 cal ka BP) whereas biogenic contribution relatively increased later on during the Younger Dryas and early Holocene (12.9 and 10 cal ka BP). Geochemical data reveal that the deglacial record mainly reflects variations of terrigenous supply via the Mississippi River rather than modifications of redox conditions in the basin. Specific variations of almost all the parameters measured in this paper are synchronous with the main deglacial meltwater episode (Meltwater Spike) described or modeled in previous marine or continental studies. During this episode, most parameters display “stair-step-like” – pattern variations highlighting three successive steps within the main meltwater flow. Variations in grain-size and clay mineral assemblage recorded in the Pigmy Basin indicate that the erosional regime was very strong on land during the first part of the Meltwater Spike, and then milder, inducing more subtle modifications in the sedimentary regime in this part of the Gulf. Specific geochemical and mineralogical signatures (notably, clay minerals and trace metal geochemistry) pinpoint a dominant origin from NW North America for detrital particles reflecting meltwater outflow from the south-western Laurentide Ice Sheet (LIS) margin during the most intense freshwater discharge. The observed decrease of the sedimentation rate from about 200 to 25 cm/ka at ca 12.9 ka evidenced a drastic decrease of erosional processes during late phase of discharge, consistently with the hypotheses of major reduction of meltwater flow. The major modification at 12.9 cal ka BP is interpreted to result from both modifications of the main Mississippi fluvial regime due to eastward and northward rerouting of meltwater flow at the onset of the Younger Dryas, and the increase of sea-surface temperature linked to insolation. Finally, slight grain-size modifications suggest that some freshwater discharges may have episodically reached the Gulf of Mexico after the Younger Dryas reflecting possible small adjustments of the postglacial hydrological regime.     

Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.     

Petrographic and geochemical characterization of the granitic rocks of the Araguainha impact crater,Brazil

Petrographic and geochemical data obtained on the Araguainha impact crater (Goiás/Mato Grosso States, Brazil) indicate the existence of several molten products that originated during impact‐induced congruent melting of an alkali‐granite exposed in the inner part of the central uplift of the structure. Although previous studies have described these melts to some extent, there is no detailed discussion on the petrographic and geochemical variability in the granite and its impactogenic derivatives, and therefore, little is known about the geochemical behavior and mobility of trace elements during its fusion in the central part of the Araguainha crater. This paper demonstrates that the preserved granitoid exposed in the core of the structure is a magnesium‐rich granite, similar to postcollisional, A‐type granites, also found in terrains outside the Araguainha crater, in the Brasília orogenic belt. The molten products are texturally distinct and different from the original rock, but have very similar geochemical composition, making it difficult to separate these lithotypes based on concentrations of major and minor elements. This also applies for trace and rare earth elements (REE), thus indicating a high degree of homogenization during impact‐induced congruent melting under high pressure and postshock temperature conditions. Petrographic observations, along with geochemical data, indicate that melting occurs selectively, where some of the elements are transported with the melt. Simultaneously, there is an effective dissolution of the rock (granite), which leads to entrainment of the most resistant solid phases (intact or partially molten minerals) into the melt. Minerals more resistant to melting, such as quartz and oxides, contribute substantially to a chemical balance between the preserved granite and the fusion products generated during the meteoritic impact.     

Comparison of four meteorite penetration funnels in the Campo del Cielo crater field,Argentina

Abstract– More craters may be discovered in the future, but as it is currently known, the Campo del Cielo crater field is 18 km long by 4 km at its widest point. Such a distribution of craters suggests that the parent meteoroid entered and traversed the atmosphere at a very low angle relative to horizontal. The crater field contains at least 20 small craters produced by the larger fragments of the parent meteoroid. Four of these are explosion analog craters and the rest are penetration funnels. During four field seasons, we have constructed topographic and magnetic maps of four of the penetration funnels as found, and then dug trenches across them to learn their original structures and recover meteorites preserved within them. Structures of these penetration funnels indicate very low angles of impact, i.e., 9–16° relative to horizontal. This supports the idea that the parent meteoroid traversed the atmosphere at a low angle. Data given here for the four penetration funnels include projectile masses, lengths, widths, depths, and estimates of impact angles and azimuths. One of the penetration funnels described here (No. 6) can almost be classified as an explosion analog crater.