Peperite formed by lava flows over sediments: An example from the central Paraná Continental Flood Basalts,Brazil

Pahoehoe flows interbedded with sediments have been identified in the superior portion of Paraná Continental Flood Basalts (PCFB), west portion of Paraná State, southern Brazil. In the study area peperites are generated by the interaction between lava flows and wet lacustrine sediments (silt and clay). Evidence that the sediments were unconsolidated or poorly consolidated and wet when the lava flowed over them includes vesiculated sediment, sediment in vesicles and fractures in lava flow and in juvenile clasts in the peperite and soft sediment deformation. Hydrodynamic mingling of lava and wet sediments (coarse mingling) is predominant and volcanic rocks and textures related to explosive phase of Molten Fuel Coolant Interaction (MFCI) are not observed in study area. Locally centimeter-sized areas display direct contact between ash-sized juvenile clasts and sediments formed by the collapse of a vapor film. The textures of fluidal peperites in the central PCFB indicate that the relevant factors that led to a coarse mingling between lava/sediment are (1) lava properties (low viscosity); (2) fine grained, unconsolidated or poorly consolidated wet sediment; and (3) a single episode of interaction between lava flows and sediment.     

On the dynamic stiffness of circular ring footings on an elastic stratum

Circular ring footings on an elastic stratum are considered. The static and dynamic stiffnesses are calculated using an efficient numerical technique. The results indicate that the static torsional and rocking stiffnesses of a ring footing do not deviate significantly from the corresponding stiffness of the circular footing for values of the inner-radius-to-outer-radius ratio up to about 0.75. The static horizontal and vertical stiffnesses change considerably only for values of this ratio greater than about 0.60. The change in the stiffness and damping coefficients is small for values of the ratio between 0 and 0.5.     

Does the current Clean Development Mechanism (CDM) deliver its sustainable development claim? An analysis of officially registered CDM projects

This article presents an analytical framework for analyzing Clean Development Mechanism (CDM) projects in terms of their contribution to employment generation, equal distribution of CDM returns, and improvement of local air quality. It assesses 16 officially registered CDM projects with regard to whether they fulfill the two objectives required by the Kyoto Protocol: greenhouse gas emission reductions and contribution to sustainable development in the host country. While a large part (72%) of the total portfolio’s expected Certified Emission Reductions (CERs) are likely to represent real and measurable emission reductions, less than 1% are likely to contribute significantly to sustainable development in the host country. According to our analysis, there are currently no UNFCCC registered CDM projects that are likely to fulfill the Kyoto Protocol’s twofold objective of simultaneously delivering greenhouse gas (GHG) emission reduction and contributing to sustainable development.     

First-order impacts on winter and summer crops assessed with various high-resolution climate models in the Iberian Peninsula

The first-order or initial agricultural impacts of climate change in the Iberian Peninsula were evaluated by linking crop simulation models to several high-resolution climate models (RCMs). The RCMs provided the daily weather data for control, and the A2 and B2 IPCC scenarios. All RCMs used boundary conditions from the atmospheric general circulation model (AGCM) HadAM3 while two were also bounded to two other AGCMs. The analyses were standardised to control the sources of variation and uncertainties that were added in the process. Climatic impacts on wheat and maize of climate were derived from the A2 scenario generated by RCMs bounded to HadAM3. Some results derived from B2 scenarios are included for comparisons together with impacts derived from RCMs using different boundary conditions. Crop models were used as impact models and yield was used as an indicator that summarised the effects of climate to quantify initial impacts and differentiate among regions. Comparison among RCMs was made through the choice of different crop management options. All RCM-crop model combinations detected crop failures for winter wheat in the South under control and future scenarios, and projected yield increases for spring wheat in northern and high altitude areas. Although projected impacts differed among RCMs, similar trends emerged for relative yields for some regions. RCM-crop model outputs compared favourably to others using European Re-Analysis data (ERA-15), establishing the feasibility of using direct daily outputs from RCM for impact analysis. Uncertainties were quantified as the standard deviation of the mean obtained for all RCMs in each location and differed greatly between winter (wheat) and summer (maize) seasons, being smaller in the latter.     

Carbonate platform drowning caught in the act: The sedimentology of Saya de Malha Bank (Indian Ocean)

Mesophotic reefs, hardgrounds and current-controlled pelagic to hemipelagic carbonates are facies marking carbonate platform drowning successions, irrespective of the factors controlling this evolution. A modern analogue of a carbonate platform in a state of drowning, where these facies occur has not been properly reported on to date. In the present study, the sedimentary environments of the Saya de Malha Bank are characterized using a multi-disciplinary approach including sedimentology, hydroacoustics, seismics and oceanography. The Saya de Malha Bank edifice with a surface of 40 808 km² is located in the tropical Indian Ocean and lies in a water depth of 8 to 300 m extending from the surrounding more than 2000 m deep ocean floor, with no reef reaching the sea surface. Mesophotic coral and red algal facies co-exist with hemipelagic and bioclastic sands, together with a hardground. Ocean currents and internal waves are identified as major sedimentological controlling factors in the absence of elevated nutrient influx. Many features distributed along the present-day Saya de Malha Bank were described from studies presenting fossil examples of carbonate platform drowning. The results herein can therefore be applied to other drowning examples, in some cases allowing for more accurate interpretation of the stratigraphic record.     

Evaluation of susceptibility for terrain collapse and subsidence in karst areas,municipality of Iraquara,Chapada Diamantina (BA), Brazil

The morphological evolution of the karstic systems is associated with a set of physical and chemical processes, triggered by the dissolution of the rocks, related to percolation of groundwater and surface water, which consequently open underground voids and carve out peculiar forms of relief. Due to environmental and geotechnical aspects, this system is naturally more fragile and vulnerable than other natural systems and, therefore, has increasingly received the attention of the scientific community over the past decades. The objective of the study was to delimit zones with varying degrees of susceptibility for collapses and subsidence of sinkholes in the municipality of Iraquara, Chapada Diamantina (BA), Brazil, and to understand their geological and morphological determinant factors. Geological data, karst phenomenon map, and visual analysis in the field were used to categorize zones with different types of susceptibilities to the nucleation of new sinkholes based on a Hazard Index. This index was defined from the sum of geological hazard factors, lineament density, and sinkhole density. The areas that presented the highest susceptibility for terrain collapse and subsidence corresponded to regions where carbonate rocks outcrop, with high density of photolineaments and 2.62 sinkholes/km². Processes associated with terrain collapse and subsidence in karst areas consisted of a combination of various factors, hindering precise predictions. However, zones of different types of susceptibilities to terrain collapse and subsidence can be delimited when the relationships between these processes and their factors are understood. The Hazard Index proposed does not provide quantitative values for the probability of hazard susceptibility, but rather indicates areas that are more susceptible to terrain subsidence and collapse.     

Hydrogeochemical characterization and evolution of a regional karst aquifer in the Cuatrociénegas area,Mexico

The Cuatrociénegas area is useful for the investigation of the effect of groundwater extraction in the Chihuahuan freshwater xeric ecoregion. It has been investigated at this time using a selection of geochemical indicators (major, minor and trace elements) and δ³⁴S data, to characterize the origin of groundwater, the main geochemical processes and the mineral/groundwater interactions controlling the baseline geochemistry. The area is composed of limestones of Mesozoic age, with a composite thickness of about 500 m, overlaid by basin fill (poorly consolidated young sediments). Substantial water extraction and modification of natural discharges from the area along the last century have produced a detrimental impact on ecosystem structure and function. Water–rock interactions, mixing and evaporative processes dominate the baseline groundwater quality. Natural recharge is HCO₃–Ca type in equilibrium with calcite, low salinity (TDS?<?500 mg/L), Cl^? lower than 11 mg/L and average Li⁺ concentration of 0.005 mg/L. Along the groundwater flow systems, δ³⁴S evidence and mass transfer calculations indicate that Cretaceous gypsum dissolution and dedolomitization reactions adjust water composition to the SO₄–Ca type. The increase of water–rock interaction is reflected by Cl^? values increase (average 68 mg/L), TDS up to about 1500 mg/L and an average Li⁺ concentration of 0.063 mg/L. Calculations with chemical geothermometers indicate that temperature at depth could be at maximum of 15–20 °C higher than field-measured temperature for pozas. After groundwater is discharged to the surface, chemical evolution continues; water evaporation, CO₂ degassing and precipitation of minerals such as gypsum, calcite and kaolinite represent the final processes and reactions controlling water chemical composition.     

Fast 2.5D finite element simulations of borehole resistivity measurements

We develop a rapid 2.5-dimensional (2.5D) finite element method for simulation of borehole resistivity measurements in transversely isotropic (TI) media. The method combines arbitrary high-order \(H^{1}\)- and \(\mathbf {H}\)(curl)-conforming spatial discretizations. It solves problems where material properties remain constant along one spatial direction, over which we consider a Fourier series expansion and each Fourier mode is solved independently. We propose a novel a priori method to construct quasi-optimal discretizations in physical and Fourier space. This construction is based on examining the analytical (fundamental) solution of the 2.5D formulation over multiple homogeneous spaces and assuming that some of its properties still hold for the 2.5D problem over a spatially heterogeneous formation. In addition, a simple parallelization scheme over multiple measurement positions provides efficient scalability. Our method yields accurate borehole logging simulations for realistic synthetic examples, delivering simulations of borehole resistivity measurements at a rate faster than 0.05 s per measurement location along the well trajectory on a 96-core computer.     

Monitoring runoff coefficients and groundwater levels using data from GRACE,GLDAS, and hydrometeorological stations: analysis of a Colombian foreland basin

The determination of space–time variation in groundwater accumulation in Colombia’s Eastern Llanos foreland basin from 2003 to 2014 was done using terrestrial water storage (TWS) anomalies identified in two versions of the Gravity Recovery and Climate Experiment (GRACE) data—from the Global Data Center for Space Research (CSR) at the University of Texas at Austin (USA) and from the Institute of Geodesy at the Graz University of Technology (ITSG, Austria)—and also soil moisture storage (SMS) data from the Global Land Data Assimilation System (GLDAS). These data were compared to changes in groundwater storage obtained using the water-budget equation, calculated based on recorded data from hydrometeorological stations. This study confirmed the viability of using satellite information to understand and monitor temporal variation in groundwater recharge in the study area. Temporal variations in TWS, SMS, and groundwater level were shown to correspond to regional rain and drought periods, which are sensitive to climate phenomena such as El Niño and La Niña. Comparing changes in TWS and groundwater level to changes in infiltration and recharge revealed correlation coefficients of 0.56 and 0.98 with CSR data and 0.71 and 0.86 with ITSG data, respectively.     

Wien effect of Cd/Zn on soil clay fraction and their interaction

Background

The coexistence of Cd²⁺ and Zn²⁺ ions in nature has a significant influence on their environmental behaviors in soils and bioavailability for plants. While many studies have been done on the mutual toxicity of Cd²⁺ and Zn²⁺, few studies can be found in the literature focused on the interaction of Cd²⁺ and Zn²⁺ on soil clay fractions especially in terms of energy relationship.

Results

The binding energies of Cd²⁺ on boggy soil (Histosols) particles and Zn²⁺ on yellow brown soil (Haplic Luvisols) particles were the highest, while those of Cd²⁺ and Zn²⁺ on paddy soil (Inceptisols) particles were the lowest. These results indicated that Cd²⁺ and Zn²⁺ have a strong capacity to adsorb in the solid phase at the soil–water interface of boggy soil and yellow brown soil, respectively. However, both Cd²⁺ and Zn²⁺ adsorbed on paddy soil particles easily release into the solution of the soil suspension. Unlike the binding energy, the higher adsorption energies of ions in boggy and yellow brown soils showed a weak binding force of ions in boggy soil and yellow brown soil. A 1:1 ratio of Cd²⁺ to Zn²⁺ promotes the mutual inhibition of their retentions. Cd²⁺ and Zn²⁺ have high mobility and bioavailability in paddy soil and yellow drab soil (Ustalfs), whereas they have high potential mobility and bioavailability in boggy soil and yellow brown soil.

Conclusion

In the combined system, Zn²⁺ had preferential adsorption than Cd²⁺ on soil clay fractions. Boggy soil and yellow brown soil have a low environmental risk with lower mobility and bioavailability of Cd²⁺ and Zn²⁺ while paddy soil and yellow drab soil present a substantial environmental risk. In the combined system, Cd²⁺ and Zn²⁺ restrain each other, resulting in the weaker binding force between ions and soil particles at a 1:1 ratio of Cd²⁺–Zn²⁺.