Distribution of benthic flora in the lower course of the Valdivia River,Chile

The Valdivia River (Lake Region, Chile) originates in Riñihue Lake and flows into the sea at Corral Bay (39°52′S latitude), changing names several times along its course. The aquatic benthic flora (algae and aquatic plants) of the Valdivia River was characterized, based on 22 sites sampled and 124 plant species collected. Four benthic vegetation zones were established using presence-absence data: a freshwater zone and a marine zone were found at the extremes of the transect; an estuarine zone and a discontinuity zone were detected in the middle of this transect. The freshwater zone was characterized by a relatively diverse assemblage of vascular plants, the marine zone was dominated by algae and was rich in species. By contrast the estuarine zone was inhabited by only a few species but in great abundance, while the discontinuity zone was poor, in species and low in cover vegetation.     

Application of a 3D photorealistic model for the geological analysis of the Permian carbonates (Khuff Formation) in Saudi Arabia

Three dimensional (3D) photorealistic models of geological outcrops have the potential to enhance the teaching of earth sciences by providing scale models in a virtual reality environment. These models can be run on low-cost desktop computers. Photorealistic models for geological outcrops are a digital illustration of outcrop photographs with either a point cloud representation or Triangular Irregular Network (TIN) mesh of the outcrop surface. The level of detail for these models is dependent on the target resolutions (physical and optical) that were used during data acquisition. In addition, the technique in which the data is rendered as a digital model affects the level of detail that can be observed by the geologists. A colored point cloud representation is suitable for large-scale features, but fine details are lost when the geologist zooms in to view the model close up. In contrast, a photorealistic model that is constructed from photographs draped onto a triangle mesh surface derived from Light Detection and Ranging (LiDAR) point clouds provides a level of detail that is restricted only by the resolution of the photographs.     

The scope for generating bio-oils with relatively low oxygen contents via hydropyrolysis

The primary oils obtained in high yields from fast (fluidised-bed) pyrolysis of biomass generally have high oxygen contents (ca. 40% w/w). The scope for using pyrolysis under hydrogen pressure (hydropyrolysis), to give oils with much lower oxygen contents compared to normal pyrolysis has been investigated. Fixed-bed hydropyrolysis tests have been conducted on cellulose, sugar cane bagasse and eucalyptus wood using hydrogen pressures up to 10 MPa, with heating rates of 5 and 300°C min⁻¹. A colloidal FeS catalyst was used in some tests (Fe loading of 5%, w/w) to increase overall conversions. Further, the attractive option of using a two-stage reactor in which the primary oil vapors are passed though a bed of hydrotreating catalyst is also described. Raising the hydrogen pressure from atmospheric to 10 MPa reduced the oxygen content of the primary oil by over 10% to below 20% w/w. The addition of a dispersed iron sulphide catalyst gave conversions close to 100% for all three biomass samples investigated at 10 MPa under conditions in the fixed-bed reactor where significant diffusional resistances existed and reduced the oxygen content of the bio-oil by a further 10%. Although NMR indicated that the oils became increasingly aromatic as more oxygen was removed, the increase in hydrogen pressure decreased the extent of overall aromatisation that occurs primarily due to the lower char yields obtained. In two-stage tests for cellulose, using a commercial sulphided Ni/Mo γ-Al₂O₃ catalyst at 400°C, increasing the hydrogen pressure from 2.5 to 10 MPa decreased the oxygen content of the oil by over 20% to 10% w/w. The H/C ratios were higher and O/C ratios smaller for the two-stage bio-oils compared to their single stage counterparts. However, the differences in the O/C ratios between the single and two-stage bio-oils increase with pressure.     

Superposition of tectonic structures leading elongated intramontane basin: the Alhabia basin (Internal Zones,Betic Cordillera)

International Journal of Earth Sciences - The relief of the Betic Cordillera was formed since the late Serravallian inducing the development of intramontane basins. The Alhabia basin, situated in...     

Climatic vs. tectonic signals in a continental extensional basin (Teruel,NE Spain) from stable isotope (δ18O) and sequence stratigraphical evolution

Alluvial fans and shallow carbonate lakes interfered in the Teruel half‐graben during the Late Miocene–Pliocene. Tectonic influence is recorded in alluvial and lacustrine–palustrine successions, with long‐term climate changes being recorded in detail in the isotopic signatures of carbonates. Episodes of tectonic activity induced alluvial fan progradation and lake retraction in the whole basin. Three lacustrine stages have been identified, which support the idea that climate also exerted an important control on sedimentation. The transition between stages 1 and 2 occurred during a tectonically calm episode due to an increase in aridity in the Early Turolian; small fans with source areas next to the lake margin prograded, inducing lake‐shore retraction. The transition from stage 2 to 3 was caused by the superimposition of increasing tectonic activity and aridity effects. Our study demonstrates that discrimination of allogenic factors controlling sedimentation in continental closed basins is possible using sequence stratigraphy in combination with other techniques such as geochemistry of carbonates.     

The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2

Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H₂SO₄, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L⁻¹, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO₄–H⁺ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H⁺ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO₄–H⁺ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H⁺ solutions.     

Coastal Occupations in Tierra del Fuego,Southernmost South America: A Late Holocene Hunter‐Gatherer Context at Marazzi 2

This paper focuses on the late Holocene occupation of hunter‐gatherers at the Marazzi 2 site located on the northwestern steppe of Tierra del Fuego, Chile. Our aim is to understand stratigraphy, formation processes, and pedogenesis with respect to human occupation over the last 3000 years. Based on archaeological excavations on a fluvial terrace of the Torcido River, we integrate soil micromorphology, mineralogy, geochemistry, magnetic susceptibility, and geomorphology, as well as the micro‐ and macrofrequency distributions of archaeological material. A micro‐taphonomical perspective is also applied to anthropogenic components recorded in sedimentary thin sections. We discuss various events in the interplay between soil development and human occupation through time. Marazzi 2 was witness to aggradation and pedogenesis with an episode of surface stability coincident with a phase of more intense human occupation at about 860 BC. Taphonomic analysis suggests that there are multiple occupation events mixed together, probably by biomechanical processes, resulting in a palimpsest with poor temporal resolution.     

Late Pleistocene glaciation of Páramo de La Culata,north-central Venezuelan Andes

Late Pleistocene glacial features in the Páramo de La Culata region, north-central Venezuelan Andes, include: 1. depositional features: morainic till and fluvio-glacial deposits (terrace gravels); 2. sculptured features: glaciated valleys, cirques, horns, and arêtes; and 3. erosional features: striation and grooving, polished rock, roches moutonnées and whaleback forms, and erratic boulders. Two main levels of moraines were found, an older one at 2600 m elevation, and a younger one between 3000 and 3500 m. The difference in age is reflected by the higher degree of weathering, erosion, and vegetation cover of the lower level, as compared with the higher level. Radiocarbon dating, and a comparison and correlation of these glacial features with those of adjacent regions, indicates that the lower morainic level (2600 m) is probably the result of the main glacial advance of the Late Wisconsin Glaciation. The main morainic level (3000 to 3500 m) was probably formed by the latest Wisconsin glacial advance. The Late Pleistocene snow-line depression reached approximately 1200 m below the present snow-line (i. e., down to approximately 3500 m).     

Difference of Ti,Zr, Y and P content in calc-alkaline andesites from island arcs and continental margin (Central Andes)

Ti, Zr, Y and P, known to be chemically immobile elements during alteration and metamorphism, have been ploted in a set of diagrams in order to discriminative between calc-alkaline andesites from island arcs and continental margin. This method may be an appropiate procedure to help in the discrimination between ancient volcanics of both groups.