Generation of CO2-rich melts during basalt magma ascent and degassing

To test mechanisms of basaltic magma degassing, continuous decompressions of volatile-bearing (2.7–3.8 wt% H₂O, 600–1,300 ppm CO₂) Stromboli melts were performed from 250–200 to 50–25 MPa at 1,180–1,140 °C. Ascent rates were varied from 0.25 to ~1.5 m/s. Glasses after decompression show a wide range of textures, from totally bubble-free to bubble-rich, the latter with bubble number densities from 10⁴ to 10⁶ cm^?3, similar to Stromboli pumices. Vesicularities range from 0 to ~20 vol%. Final melt H₂O concentrations are homogeneous and always close to solubilities. In contrast, the rate of vesiculation controls the final melt CO₂ concentration. High vesicularity charges have glass CO₂ concentrations that follow theoretical equilibrium degassing paths, whereas glasses from low vesicularity charges show marked deviations from equilibrium, with CO₂ concentrations up to one order of magnitude higher than solubilities. FTIR profiles and maps reveal glass CO₂ concentration gradients near the gas–melt interface. Our results stress the importance of bubble nucleation and growth, and of volatile diffusivities, for basaltic melt degassing. Two characteristic distances, the gas interface distance (distance either between bubbles or to gas–melt interfaces) and the volatile diffusion distance, control the degassing process. Melts containing numerous and large bubbles have gas interface distances shorter than volatile diffusion distances, and degassing proceeds by equilibrium partitioning of CO₂ and H₂O between melt and gas bubbles. For melts where either bubble nucleation is inhibited or bubble growth is limited, gas interface distances are longer than volatile diffusion distances. Degassing proceeds by diffusive volatile transfer at the gas–melt interface and is kinetically limited by the diffusivities of volatiles in the melt. Our experiments show that CO₂-oversaturated melts can be generated as a result of magma decompression. They provide a new explanation for the occurrence of CO₂-rich natural basaltic glasses and open new perspectives for understanding explosive basaltic volcanism.     

Earthquakes in Switzerland and surrounding regions during 2012

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2012. During this period, 497 earthquakes and 88 quarry blasts were detected and located in the region under consideration. With a total of only 13 events with M_L ≥ 2.5, the seismic activity in the year 2012 was far below the average over the previous 37 years. Most noteworthy were the earthquake sequence of Filisur (GR) in January with two events of M_L 3.3 and 3.5, the M_L 4.2 and M_L 3.5 earthquakes at a depth of 32 km below Zug in February and the M_L 3.6 event near Vallorcine in October. The epicentral intensity of the M_L 4.2 event close to Zug was IV, with a maximum intensity of V reached in a few areas, probably due to site amplification effects.     

Seismic input at the archaeological site of Kancheepuram in Southern India

A probabilistic seismic hazard assessment at Kancheepuram in Southern India was carried out with the scope of defining the seismic input for the vulnerability assessment of historical and monumental structures at the site, in terms of horizontal Uniform Hazard Spectra and a suite of spectrum-compatible natural accelerograms to perform time-history analysis. The standard Cornell?CMcGuire and a zone-free approach have been used for hazard computations after the compilation of a composite earthquake catalogue for Kancheepuram. Epistemic uncertainty in the seismic hazard was addressed within a logic-tree framework. Deaggregation of the seismic hazard for the peak ground acceleration shows low seismicity at Kancheepuram controlled by weak-to-moderate earthquakes with sources located at short distances from the archaeological site. Suites of natural accelerograms recorded on rock have been selected by imposing a custom-defined compatibility criterion with the probabilistic spectra. The site of Kancheepuram is characterized by a seismicity controlled by weak-to-moderate earthquakes with sources at short distances from the site, the PGA expected for 475- and 2,475-year return period are, respectively, 0.075 and 0.132?g. The Indian code-defined spectra (DBE and MCE) tend to underestimate spectral ordinates at low periods. On the other hand, the PGA are comparable and the spectral ordinates for longer periods from the probabilistic study are significantly lower.     

Aquatic macrophyte diversity assessment: Validation of a new sampling method for circular-shaped lakes

We propose and validate a new sampling method to assess the presence, abundance and distribution of macrophytes in circular-shaped lakes according to the requirements of the Water Framework Directive (WFD2000/60/EC). The results of the macrophyte survey, and in particular of macrophyte diversity, obtained using this method are also discussed.The sampling is based on randomly selected transects homogeneously distributed around the perimeter of the lake. The number of transects is proportional to the lake's size. The method was validated on six Italian volcanic lakes using computational resampling procedures on a total of 126 transects.Using resampling procedures, we show that the proposed approach identifies more than 75% of the overall species richness through a moderate sampling effort. According to our results, Charophytes dominate aquatic vegetation in Italian volcanic lakes. Species diversity is highest at shallow depths, whereas the most abundant species, such as Chara polyacantha, are located at an intermediate depth between the shoreline and the maximum growing depth.     

Probabilistic seismic hazard assessment of Italy using kernel estimation methods

A representation of seismic hazard is proposed for Italy based on the zone-free approach developed by Woo (BSSA 86(2):353–362, 1996a), which is based on a kernel estimation method governed by concepts of fractal geometry and self-organized seismicity, not requiring the definition of seismogenic zoning. The purpose is to assess the influence of seismogenic zoning on the results obtained for the probabilistic seismic hazard analysis (PSHA) of Italy using the standard Cornell’s method. The hazard has been estimated for outcropping rock site conditions in terms of maps and uniform hazard spectra for a selected site, with 10 % probability of exceedance in 50 years. Both spectral acceleration and spectral displacement have been considered as ground motion parameters. Differences in the results of PSHA between the two methods are compared and discussed. The analysis shows that, in areas such as Italy, characterized by a reliable earthquake catalog and in which faults are generally not easily identifiable, a zone-free approach can be considered a valuable tool to address epistemic uncertainty within a logic tree framework.     

Numerical modelling of regional faults in land subsidence prediction above gas/oil reservoirs

The stress variation induced by gas/oil production may activate pre‐existing regional faults. This may enhance the expected land subsidence due to the generation of mechanically weak points close to the producing field. A class of elasto‐plastic interface elements (IE), specifically designed to address the mechanical behaviour of faults over a regional scale, is integrated into a finite element (FE) geomechanical model and used to investigate the role exerted by active faults in anthropogenic land subsidence. The importance of regional faults depends on a variety of factors including depth of the depleted reservoir, fault number, orientation and size, geomechanical properties of porous medium, pore pressure drawdown induced by fluid production, etc. With the aid of some representative examples, a useful indication is provided as to where and how fault activation may influence both magnitude and extent of the land subsidence bowl above producing gas/oil reservoirs, pointing to a generally limited impact on the ground surface. The simulation of a real faulted gas reservoir in a complex 3‐D setting shows that the proposed IE can be simply and efficiently incorporated into a FE geomechanical model, thus improving the quality of the stress and displacement prediction. Copyright © 2007 John Wiley & Sons, Ltd.     

Large-Eddy Simulations of Pollutant Removal Enhancement from Urban Canyons

Boundary-Layer Meteorology - Techniques for improving the removal of pollution from urban canyons are crucial for air quality control in cities. The removal mainly occurs at the building roof...     

Seismic hazard assessment of northern Pakistan

This article presents probabilistic seismic hazard analyses of northern Pakistan region carried out to produce macro-seismic hazard maps for the region that define new regional ground motion design parameters for 95-, 475-, 975- and 2475-year return period earthquakes as regional contour maps and horizontal uniform hazard at important cities. The Cornell–McGuire approach (Cornell in Bull Seismol Soc Am 58(05):1583–1606, 1968; McGuire in FORTRAN computer program for seismic risk analysis. US Geological Survey, Open file Report, 76-6768, 1976) is used to carry out the analyses at 0.1° rectangular grid. The seismotectonic model of the region used in analysis consists of shallow and deep area zones differentiated based on the focal depths of the earthquakes. Earthquake catalogue compiled and used in the analysis is a composite catalogue composed of 19,373 events. Ground motion prediction equations (GMPEs) used are calibrated using goodness-of-fitness measures and visual inspection with local strong motion data. Epistemic uncertainty in the GMPEs is taken into account through the logic tree approach. Comparison of ground motions due to deep earthquakes is made for the first time for the region. The comparison between ground motion due to shallow and deep earthquakes indicates that the seismic hazard would be underestimated if the deep earthquakes are excluded. Ground motion values obtained in this study considering all the earthquakes suggest ground motions are dominant towards the north east of the region. The proposed study indicates that the ground motion hazard values suggested by the current Building Code of Pakistan underestimate the seismic hazard. Final results of this study are in close agreement with the recent studies on the region.