A Ce/Nd isotope study of crustal contamination processes affecting Palaeocene magmas in Skye,Northwest Scotland

Twelve¹³⁸Ce/¹³⁶Ce isotope determinations, 31 Nd isotope analyses, and 31 REE profiles are presented for Tertiary basic to intermediate igneous rocks from the Isle of Skye, NW Scotland. The aim of this work is to precisely identify the contamination mechanisms of basic magmas emplaced through old crust, and to test the effectiveness of Ce isotope analysis as a petrogenetic tool.Combined Ce/Nd isotope analysis enables the modelling of the light REE profiles of the mantle-derived precursors to contaminated lavas, using different crustal end-members, in order to compare these with the magmatic lineage of uncontaminated Skye lavas. The geochemical data support a contamination mechanism involving a granitic melt, produced either by large degree melting of Scourian granulitefacies acid sheets, or (possibly) by melting of intermediate gneiss out of isotopic equilibrium.Basaltic lavas showing strong isotopic contamination effects yield calculated degrees of crustal contamination by large degree granitic melts of ca. 8 or 9% based on Ce and Nd isotopic data respectively. However, for lavas with liquidus temperatures of over 1250° C, the temperature dependence of the degree of contamination is weak.The combination of this evidence with new and published Pb isotope data suggests that the bulk of crustal contamination of the Skye lavas occurred in sill complexes at distinct levels in the crust, rather than during the actual ascent of magma through the crust in dykes. It is suggested on the basis of published fluid dynamic and field evidence that the assimilation of large degree melts of acid gneiss by turbulently flowing magma is more likely than assimilation of small degree disequilibrium melts from more refractory intermediate gneisses.It is concluded that Ce isotope analysis is a viable and useful adjunct to Nd isotope data in petrogenetic studies of continental igneous rocks emplaced through old basement.     

A Tripartite Conceptualisation of Urban Public Space as a Site for Play: Evidence from South Bank,London

Public space is a feature of the urban built environment that has received increasing attention in recent years. Discussion has focused on the theoretical decline of public space, as private and institutional forces take on increasing influence. At the same time, many such “in-between spaces,” even privately owned ones, are used and experienced as public on a daily basis. Few studies, however, have explored how spaces understood as public are used and practised as such. To address this gap in the literature this paper draws upon ethnographic data collected on the “South Bank” in London (United Kingdom) to argue that “play” is a recurrent trait of sociospatial practices enacted in public space. Three interrelated typologies of playful practices in public space are discussed: child's play, plays on meaning, and play as simulation.     

Changes in monthly baseflow across the U.S. Midwest

Characterizing streamflow changes in the agricultural U.S. Midwest is critical for effective planning and management of water resources throughout the region. The objective of this study is to determine if and how baseflow has responded to land alteration and climate changes across the study area during the 50‐year study period by exploring hydrologic variations based on long‐term stream gage data. This study evaluates monthly contributions to annual baseflow along with possible trends over the 1966–2016 period for 458 U.S. Geological Survey streamflow gages within 12 different Midwestern states. It also examines the influence of climate and land use factors on the observed baseflow trends. Monthly contribution breakdowns demonstrate how the majority of baseflow is discharged into streams during the spring months (March, April, and May) and is overall more substantial throughout the spring (especially in April) and summer (June, July, and August). Baseflow has not remained constant over the study period, and the results of the trend detection from the Mann–Kendall test reveal that baseflows have increased and are the strongest from May to September. This analysis is confirmed by quantile regression, which suggests that for most of the year, the largest changes are detected in the central part of the distribution. Although increasing baseflow trends are widespread throughout the region, decreasing trends are few and limited to Kansas and Nebraska. Further analysis reveals that baseflow changes are being driven by both climate and land use change across the region. Increasing trends in baseflow are linked to increases in precipitation throughout the year and are most prominent during May and June. Changes in agricultural intensity (in terms of harvested corn and soybean acreage) are linked to increasing trends in the central and western Midwest, whereas increasing temperatures may lead to decreasing baseflow trends in spring and summer in northern Wisconsin, Kansas, and Nebraska.     

Large wavenumber convection in the rotating annulus

Abstract

The annulus model considers convection between concentric cylinders with sloping endwalls. It is used as a simplified model of convection in a rapidly rotating sphere. Large azimuthal wavenumbers are preferred in this problem, and this has been exploited to develop an asymptotic approach to nonlinear convection in the annulus. The problem is further reduced because the Taylor-Proudman constraint simplifies the dependence in the direction of the rotation vector, so that a nonlinear system dependent only on the radial variable and time results. As Rayleigh number is increased a sequence of bifurcations is found, from steady solutions to periodic solutions and 2-tori, typically ending in chaotic behaviour. Both the magnetic (MHD convection) and non-magnetic problem has been considered, and in the non-magnetic case our bifurcation sequence can be compared with those found by previous two-dimensional numerical simulations.     

Highly reducing conditions during core formation on Mercury: Implications for internal structure and the origin of a magnetic field

The high average density and low surface FeO content of the planet Mercury are shown to be consistent with very low oxygen fugacity during core segregation, in the range 3-6 log units below the iron-wüstite buffer. These low oxygen fugacities, and associated high metal content, are characteristic of high-iron enstatite (EH) and Bencubbinite (CB) chondrites, raising the possibility that such materials may have been important building blocks for this planet. With this idea in mind we have explored the internal structure of a Mercury sized planet of EH or CB bulk composition. Phase equilibria in the silicate mantle have been modeled using the thermodynamic calculator p-MELTS, and these simulations suggest that orthopyroxene will be the dominant mantle phase for both EH and CB compositions, with crystalline SiO₂ being an important minor phase at all pressures. Simulations for both compositions predict a plagioclase-bearing “crust” at low pressure, significant clinopyroxene also being calculated for the CB bulk composition. Concerning the core, comparison with recent high pressure and high temperature experiments relevant to the formation of enstatite meteorites, suggest that the core of Mercury may contain several wt.% silicon, in addition to sulfur. In light of the pressure of the core-mantle boundary on Mercury (∼7 GPa) and the pressure at which the immiscibility gap in the system Fe-S-Si closes (∼15 GPa) we suggest that Mercury’s core may have a complex shell structure comprising: (i) an outer layer of Fe-S liquid, poor in Si; (ii) a middle layer of Fe-Si liquid, poor in S; and (iii) an inner core of solid metal. The distribution of heat-producing elements between mantle and core, and within a layered core have been quantified. Available data for Th and K suggest that these elements will not enter the core in significant amounts. On the other hand, for the case of U both recently published metal/silicate partitioning data, as well as observations of U distribution in enstatite chondrites, suggest that this element behaves as a chalcophile element at low oxygen fugacity. Using these new data we predict that U will be concentrated in the outer layer of the mercurian core. Heat from the decay of U could thus act to maintain this part of Mercury’s core molten, potentially contributing to the origin of Mercury’s magnetic field. This result contrasts with the Earth where the radioactive decay of U represents a negligible contribution to core heating.     

Coastal pollution hazards in southern California observed by SAR imagery: stormwater plumes, wastewater plumes, and natural hydrocarbon seeps

Stormwater runoff plumes, municipal wastewater plumes, and natural hydrocarbon seeps are important pollution hazards for the heavily populated Southern California Bight (SCB). Due to their small size, dynamic and episodic nature, these hazards are difficult to sample adequately using traditional in situ oceanographic methods. Complex coastal circulation and persistent cloud cover can further complicate detection and monitoring of these hazards. We use imagery from space-borne synthetic aperture radar (SAR), complemented by field measurements, to examine these hazards in the SCB. The hazards are detectable in SAR imagery because they deposit surfactants on the sea surface, smoothing capillary and small gravity waves to produce areas of reduced backscatter compared with the surrounding ocean. We suggest that high-resolution SAR, which obtains useful data regardless of darkness or cloud cover, could be an important observational tool for assessment and monitoring of coastal marine pollution hazards in the SCB and other urbanized coastal regions.