Middle Miocene–Pliocene siliciclastic influx across a carbonate shelf and influence of deltaic sedimentation on shelf construction,Northern Carnarvon Basin,Northwest Shelf of Australia

Middle Miocene to Pliocene siliciclastics of the Bare Formation represent a long‐lived (ca. 11 Myr) break in the otherwise carbonate‐dominated shelf of the Northern Carnarvon Basin, Northwest Shelf of Australia. The quartz‐sandstone interval is correlated with the appearance of spectacular clinoform sets mapped on 3D and dense 2D seismic data. Twenty‐seven clinoform sets are interpreted as delta lobes primarily based on their plan‐view morphology (strike‐elongate to lobate features) and their 40–100‐m‐high clinoform amplitudes. The delta lobes were deposited on outer‐shelf to shelf‐edge positions, and the older deltas show evidence of a higher degree wave reworking than the younger deltas. Measurements of the along‐strike (migration) and down‐dip (progradation) movement of these deltas are compared with relative sea‐level behaviour inferred from shelf‐edge trajectory analysis. Delta lobes exhibit greater lateral shifting during relative sea‐level rise, whereas delta lobes are more restricted to dip‐oriented fairways during sea‐level fall, although no major incised valleys have been identified. Long‐term (cumulative) progradation of this delta system and subsequent backstepping correlates with long‐term sea‐level fall and rise during the late middle and late Miocene. In addition, a long‐term northeastward migration trend for these delta lobes was likely a result of localized uplift of an inversion anticline in the Rosemary–Legendre Trend; the growth of this anticline probably steered the fluvial source for the delta system towards the northeast. The Bare Formation siliciclastic influx correlates with other middle Miocene increases in siliciclastic sediment supply worldwide. Global cooling and a shift to more arid conditions, negatively influencing vegetation cover, may have combined with more seasonally variable rainfall to generate the high sediment supply that built the deltas. Retreat of the siliciclastics could correlate with ice‐sheet growth in the Northern Hemisphere and/or increase in the Indonesian Throughflow and Leeuwin Current (ca. 1.6 Ma), which might have modified climate regionally.     

The lithospheric density structure of the Eastern Alps

The three-dimensional (3D) lithospheric density structure of the Eastern Alps was investigated by integrating results from reflection seismics, receiver function analyses and tomography. The modelling was carried out with respect to the Bouguer gravity and the geoid undulations and emphasis were laid on the investigations of the importance of deep lithospheric features. Although the influence of inhomogeneities at the lithosphere–asthenosphere boundary on the potential field is not neglectable, they are overprinted by the response of the density contrast at the crust–mantle boundary and intra-crustal density anomalies. The uncertainties in the interpretations are in the same order of magnitude as the gravity field generated by the deep lithosphere.After including the deep lithospheric geometry from the tomographic model it is shown that full isostatic equilibrium is not achieved below the Eastern Alps. However, calculation of the isostatic lithospheric thickness shows two areas of lithospheric thickening along the central axis of the Eastern Alps with a transition zone below the area of the TRANSALP profile. This is in agreement with the tomographic model, which features a change in lithospheric subduction direction.     

An Anisotropic Attenuation Law of Macroseismic Intensity Performed on Virtual Intensity Distribution of Seismogenic Zones

An anisotropic attenuation law, based on an anisotropic characterization of intensity distribution for seismogenic zones, is proposed. This approach, that distinguishes itself for its consistency to the observed data, initially reconfigured by filtering procedures, is particularly suitable for seismic hazard evaluation.     

Indenter-tectonics in the Philippines: Example from the Palawan Microcontinental Block - Philippine Mobile Belt Collision

Abstract. The aseismic Palawan microcontinental block is an oceanic bathymetric high that has collided with the seismically-ac-tive Philippine Mobile Belt since the Early Miocene. Consequently, tectonic microblocks immediately north (Luzon) and south (Western Visayas Block) of the collision front rotated in opposite senses. The rotation led the microblocks to onramp adjacent strike-slip faults, and converted these to subduction zones, namely, the current Manila and Negros Trenches. In addition, the collision also initiated the southward propagation of a major left-lateral strike slip fault, the Philippine Fault Zone, and the Philippine Trench, which bounds the Philippine archipelago along its eastern boundary. Based on onshore and offshore data, the Philippine Fault Zone and the East Luzon Trough - Philippine Trench appears to also propagate northward. Furthermore, the opposite direction of propagation is also noted for the Manila and Negros Trenches from the locus of the collision in the Central Philippines to their northern and southern extensions, respectively. The ages of initiation of the Manila Trench (Early Miocene), Philippine Fault Zone (Middle Miocene) and Philippine Trench (Pliocene) as encountered along a west to east transect in the Central Philippines are consistent with the collision and subsequent indentation of Palawan with the rest of the Philippine Mobile Belt.     

Treatment of a Trifluraline Effluent by Means of Oxidation‐Coagulation with Fe(VI) and Combined Fenton Processes

The amination water (AW) effluent stream from the industrial production of the trifluraline herbicide was submitted to an oxidation‐coagulation treatment with potassium ferrate, combined with advanced oxidation processes. The experimental results obtained by analysis of variance (ANOVA) for the oxidation‐coagulation‐Fenton process, evaluating the variables pH (A), Fe(VI) concentration (B), and H₂O₂ concentration (C), demonstrated that the regression equation resulting from the Response Surface Methodology (RSM) experimental design, for the quadratic model, was η_Abs (%) = 36.9– 21.58A + 8.37A² + 1.36B + 0.92B² + 1.08C + 1.52C² + 1.27AB – 1.34AC + 1.33BC. The maximum absorptiometric color reduction occurred at pH 3, with corresponding maximum amounts of iron and hydrogen peroxide. The absorptiometric color and COD reduction were 96% and 57%, respectively. For the oxidation‐coagulation‐photo‐Fenton process, the analyzed variables were pH (A), Fe(VI) concentration (B), H₂O₂ concentration (C), and temperature (D). The regression equation resulting from the quadratic model was η_Abs (%) = 38.3 – 20.2A + 8.12A² – 0.27B + 3.73B² + 0.3C + 3.6C² + 1.67D + 3.1D² + 1.72AB + 0.51AC – 1.82AD + 0.74BC – 1.11BD + 0.03CD. The ANOVA response showed that the highest absorptiometric color reduction occurred at pH 3, with respective maximum amounts of iron and hydrogen peroxide at 60°C. The maximum efficiencies achieved by the proposed treatment process for the trifluraline effluent stream were 95% and 85%, for absorptiometric color and COD reduction, respectively.     

Quantifying bioirrigation using ecological parameters: a stochastic approach†

Irrigation by benthic macrofauna has a major influence on the biogeochemistry and microbial community structure of sediments. Existing quantitative models of bioirrigation rely primarily on chemical, rather than ecological, information and the depth-dependence of bioirrigation intensity is either imposed or constrained through a data fitting procedure. In this study, stochastic simulations of 3D burrow networks are used to calculate mean densities, volumes and wall surface areas of burrows, as well as their variabilities, as a function of sediment depth. Burrow networks of the following model organisms are considered: the polychaete worms Nereis diversicolor and Schizocardium sp., the shrimp Callianassa subterranea, the echiuran worm Maxmuelleria lankesteri, the fiddler crabs Uca minax, U. pugnax and U. pugilator, and the mud crabs Sesarma reticulatum and Eurytium limosum. Consortia of these model organisms are then used to predict burrow networks in a shallow water carbonate sediment at Dry Tortugas, FL, and in two intertidal saltmarsh sites at Sapelo Island, GA. Solute-specific nonlocal bioirrigation coefficients are calculated from the depth-dependent burrow surface areas and the radial diffusive length scale around the burrows. Bioirrigation coefficients for sulfate obtained from network simulations, with the diffusive length scales constrained by sulfate reduction rate profiles, agree with independent estimates of bioirrigation coefficients based on pore water chemistry. Bioirrigation coefficients for O₂ derived from the stochastic model, with the diffusion length scales constrained by O₂ microprofiles measured at the sediment/water interface, are larger than irrigation coefficients based on vertical pore water chemical profiles. This reflects, in part, the rapid attenuation with depth of the O₂ concentration within the burrows, which reduces the driving force for chemical transfer across the burrow walls. Correction for the depletion of O₂ in the burrows results in closer agreement between stochastically-derived and chemically-derived irrigation coefficient profiles.     

Basin evolution model during cretaceous in the northeastern of Arabian plate in Kurdistan region

The research area concentrates in a part of the main Zagros fold and thrust belt in the Kurdistan region (Northern Iraq). From study tectono-stratigraphy we constrain the story of the basin evolution of Kurdistan during Cretaceous. However we mainly investigated the evolution of the pre-Subduction and Pre-collision periods, focusing on the relationship between tectonics and sedimentation. For this purposes we developed (1) a biostratigraphic approach using nannofossil analysis, (2) a fault tectonic analysis, and (3) a stratigraphic study. The Zagros fold belt in Kurdistan exhibits many lateral and vertical environmental and facies changes, especially during the Cretaceous times. During the Jurassic period the Kurdistan is occupied by the restricted Gotnia Basin. This basin disappeared and the Kurdistan area changed to open marine of a southwest Kermanshah Basin during the Cretaceous. During the Berriasian to Barremian the Kurdistan was covered by the carbonates of the Balambo and Sarmord formations. In the east and southeast the neritic Sarmord Formation gradationally and laterally passes to the basinal facies of the Balambo Formation. In the Aptian to Cenomanian period shallow massive reefal limestone of the Qamchuqa Formation deposited. The normal faulting that initiates during the Aptian is associated with an abrupt lateral change of the reefal Qamchuqa Formation to the Aptian-Cenomanian part of the Balambo Formation. During the Cenomanian-Early Turonian periods the graben formed in the Dokan Lake in eastern Kurdistan, where developed a deeper restricted environment (Dokan and Gulneri formations) surrounded by a shallow marine platform. During the Turonian the marine pelagic micritic cherty limestones of Kometan Formation covered northeast of Kurdistan, whereas in the Safeen, Shakrok and Harir anticlines the formation was totally, or partially, weathered during the Coniacian-Early Campanian period. The deposition during the Late Cretaceous is very heterogeneous with a gap in the Coniacian-Santonian times probably related to a non-deposition. Associated with extensive tectonics a basin developed during the Campanian with the deposition of shales, marls and marly limestones of the Shiranish Formation. The first appearance is the Kurdistan of the flysch facies of the Tanjero Formation was precisely dated of the Upper Campanian in northeastern Kurdistan. The Tanjero Formation conformably overlaying the Shiranish Formation and was deposited in the foredeep basin associated with the obduction of Tethyan ophiolites onto the Arabian Platform. The Early to Late Campanian period is a time of non-deposition in Central Kurdistan (Safeen, Shakrok and Harir anticlines). During the Late Campanian the Bekhme carbonate platform in the north disappeared when the marly limestones of the Shiranish Formation transgressed over the Bekmeh Platform. In the Aqra area the Maastrichtian Tanjero Formation laterally changed to the thick reefal sequence of the Aqra Formation that unconformably overlies by the Late Paleocene-Early Eocene lagoonal carbonate of the Khurmala Formation. The Campanian sedimentation is mainly controlled by NE- oriented normal faults forming Grabens in Dokan, Spilk and Soran areas. During the Maastrichtian in the extreme northeastern Kurdistan the NE-SW and NNW-SSE normal faults developed in the foredeep basin and originated horsts and grabens.     

Collision, subduction and accretion events in the Philippines: A synthesis

Abstract The Philippines preserves evidence of the superimposition of tectonic processes in ancient and present‐day collision and subduction zone complexes. The Baguio District in northern Luzon, the Palawan–Central Philippine region and the Mati–Pujada area in southeastern Mindanao resulted from events related to subduction polarity reversal leading to trench initiation, continent‐arc collision and autochthonous oceanic lithosphere emplacement, respectively. Geological data on the Baguio District in Northern Luzon reveal an Early Miocene trench initiation for the east‐dipping Manila Trench. This followed the Late Oligocene cessation of subduction along the west‐dipping proto‐East Luzon Trough. The Manila Trench initiation, which is modeled as a consequence of the counter‐clockwise rotation of Luzon, is attributed to the collision of the Palawan microcontinental block with the Philippine Mobile Belt. In the course of rotation, Luzon onramped the South China Sea crust, effectively converting the shear zone that bounded them into a subduction zone. Several collision‐related accretionary complexes (e.g. Romblon, Mindoro) are present in the Palawan–Central Philippine region. The easternmost collision zone boundary is located east of the Romblon group of islands. The Early Miocene southwestward shift of the collision boundary from Romblon to Mindoro started to end by the Pliocene. Continuous interaction between the Palawan microcontinental block and the Philippine Mobile Belt is presently taken up again along the collisional boundary east of the Romblon group of islands. The Mati–Pujada Peninsula area, on the other hand, is underlain by the Upper Cretaceous Pujada Ophiolite. This supra‐subduction zone ophiolite is capped by chert and pelagic limestones which suggests its derivation from a relatively deep marginal basin. The Pujada Ophiolite could be a part of a proto‐Molucca Sea plate. The re‐interpretation of the geology and tectonic settings of the three areas reaffirm the complex geodynamic evolution of the Philippine archipelago and addresses some of its perceived geological enigmas.