New gravity maps of the Eastern Alps and significance for the crustal structures

The deep seismic profile Transalp crosses, from north to south, Germany, Austria and Italy. The gravity measurements for each country were made by national agencies with different reference systems and data reduction methods. Within the frame of the Transalp-project a comprehensive database of the Eastern Alps was compiled covering an area of 3.5° by 4° in longitude and latitude (275 by 445 km), respectively. To increase the data coverage in the south Alpine area two gravity surveys were carried out, resulting in 469 areally distributed new stations, of which 215 have been measured with the intent to improve the geoid in the area of the planned Brenner Basistunnel (BBT). The resulting gravity database is the best in terms of resolution and data quality presently available for the Eastern Alps. Here the free air, Bouguer and isostatic gravity fields are critically discussed. The spatial density of existing gravity stations in the three countries is discussed. On the Italian side of the Alps the spatial density is rather sparse compared to the Austrian side. The Bouguer-gravity field varies between − 190 * 10^− 5 m/s² and + 25 * 10^− 5 m/s², with the minimum located along the Alpine high topographic chain, but with a small offset (a few tens of km) to the greatest topographic elevation, showing that the Airy-type local isostatic equilibrium does not fully apply here. The maximum of the Bouguer anomaly has an elongated shape of 100 by 50 km located between the towns of Verona and Vicenza and covers the Venetian Tertiary Volcanic Province (VTVP), a feature not directly related to the plate collision in the Eastern Alps. The gravity high is only partly explainable by high-density magmatic rocks and requires also a deeper source, like a shallowing of the Moho. The isostatic residual anomalies (Airy model) are in the range ± 50 * 10^− 5 m/s², with the greatest positive anomaly corresponding to the location of the VTVP, indicating here under-compensation of masses. At last a discussion of a 2D density model based on reflection seismic data and receiver functions is made.     

Onland signatures of the Palawan microcontinental block and Philippine mobile belt collision and crustal growth process: A review

The collision of the Palawan microcontinental block with the Philippine mobile belt had significantly influenced the geological evolution of the Philippines. Multiple collisions involving several fragments, through space and time, resulted into the collage of terranes of varying origin exposed in this part of central Philippines. Cusping of the overriding plate, volcanic arc gap, ophiolite emplacement, incipient back-arc rifting, island rotation and tilting, raised coastal terraces, metamorphism, intrusion of igneous rocks and steepened subducted slab as seen in focal mechanism solutions are some of the manifestations of this collision. A late Early Miocene to early Middle Miocene age (20–16 Ma) is proposed for the major collision between the Palawan indenter and the Philippine mobile belt. The collision boundary is located from the northern part of Mindoro through the central mountain range swinging east of Sibuyan Island in the Romblon Island Group and finally threading along the Buruanga Peninsula and eastern side of the Antique Ophiolite Complex before exiting and connecting with the Negros Trench. The collision, through accretion and crustal thickening, has contributed to the crustal growth of the Philippine archipelago.     

The use of geoprocessing to assess vulnerability on the east coast aquifers of Rio de Janeiro State,Brazil

The east coast of Rio de Janeiro State, Brazil, shows a worrying overlap between areas with intrinsic groundwater vulnerability and the most significant urban expansion zones. It experienced a rapid population growth in recent years, mainly due to the tourism industry, resulting in a significant pressure on drinking groundwater resources. In this regard, development and use of techniques to control and protect areas susceptible to contamination is crucial. The elaboration of aquifer vulnerability maps is thus extremely helpful to support water resources management. The aim of the work is to present the methodological approach in the use of Geoprocessing techniques to obtain a suitable groundwater vulnerability model in Rio de Janeiro east coast. Considering the existing problems and the current land use and characteristics of the study region, it is clear that the most vulnerable areas (that is, “extreme” and “very high” vulnerability areas), coincide with the most significant zones of urban occupation, corresponding to 11% of the total study area, demanding adoption of urgent measures in the near future. Geoprocessing tools and remote sensing for characterization of Rio de Janeiro’s east coast aquifer vulnerability gave good results, representing a satisfactory method for management actions at low cost.     

Sediments from Lake Cheko (Siberia), a possible impact crater for the 1908 Tunguska Event

Cheko, a small lake located in Siberia close to the epicentre of the 1908 Tunguska explosion, might fill a crater left by the impact of a fragment of a Cosmic Body. Sediment cores from the lake’s bottom were studied to support or reject this hypothesis. A 175‐cm long core, collected near the center of the lake, consists of an upper ～1 m thick sequence of lacustrine deposits overlaying coarser chaotic material. ²¹⁰Pb and ¹³⁷Cs indicate that the transition from lower to upper sequence occurred close to the time of the Tunguska Event. Pollen analysis reveals that remains of aquatic plants are abundant in the top post‐1908 sequence, but are absent in the lower pre‐1908 portion of the core. These results, including organic C, N and δ¹³C data, suggest that Lake Cheko formed at the time of the Tunguska Event.     

Middle Miocene–Pliocene siliciclastic influx across a carbonate shelf and influence of deltaic sedimentation on shelf construction,Northern Carnarvon Basin,Northwest Shelf of Australia

Middle Miocene to Pliocene siliciclastics of the Bare Formation represent a long‐lived (ca. 11 Myr) break in the otherwise carbonate‐dominated shelf of the Northern Carnarvon Basin, Northwest Shelf of Australia. The quartz‐sandstone interval is correlated with the appearance of spectacular clinoform sets mapped on 3D and dense 2D seismic data. Twenty‐seven clinoform sets are interpreted as delta lobes primarily based on their plan‐view morphology (strike‐elongate to lobate features) and their 40–100‐m‐high clinoform amplitudes. The delta lobes were deposited on outer‐shelf to shelf‐edge positions, and the older deltas show evidence of a higher degree wave reworking than the younger deltas. Measurements of the along‐strike (migration) and down‐dip (progradation) movement of these deltas are compared with relative sea‐level behaviour inferred from shelf‐edge trajectory analysis. Delta lobes exhibit greater lateral shifting during relative sea‐level rise, whereas delta lobes are more restricted to dip‐oriented fairways during sea‐level fall, although no major incised valleys have been identified. Long‐term (cumulative) progradation of this delta system and subsequent backstepping correlates with long‐term sea‐level fall and rise during the late middle and late Miocene. In addition, a long‐term northeastward migration trend for these delta lobes was likely a result of localized uplift of an inversion anticline in the Rosemary–Legendre Trend; the growth of this anticline probably steered the fluvial source for the delta system towards the northeast. The Bare Formation siliciclastic influx correlates with other middle Miocene increases in siliciclastic sediment supply worldwide. Global cooling and a shift to more arid conditions, negatively influencing vegetation cover, may have combined with more seasonally variable rainfall to generate the high sediment supply that built the deltas. Retreat of the siliciclastics could correlate with ice‐sheet growth in the Northern Hemisphere and/or increase in the Indonesian Throughflow and Leeuwin Current (ca. 1.6 Ma), which might have modified climate regionally.     

Vertical crustal motions from differential tide gauge observations and satellite altimetry in southern Italy

Our goal is to determine vertical crustal movement rates from tide gauge and satellite altimetry measurements. Tide gauges measure sea level, but as they are fixed to the crust, they sense both sea surface height variations and vertical crustal movements. The differential sea level rates of sufficiently nearby stations are a good means to determine differential crustal movement rates, when sea level height variations can be assumed to be homogeneous. Satellite altimetric measurements determine sea surface height variations directly and can be used to separate the crustal signal from the sea surface height variations in tide gauge measurements. The correction of the tide gauge sea level rates for the sea surface height contribution requires collocation of the satellite pass and the tide gauge station. We show that even if this is not the case, the satellite altimetric observations enable correction of differential tide gauge rates for the effects of sea surface rate inhomogeneities.     

Determination of Sulfamethoxazole and Trimethoprim and Their Metabolites in Hospital Effluent

In this work, an analytical methodological study was carried out to determine the antimicrobials sulfamethoxazole and trimethoprim, as well as their metabolites, in hospital effluent. The determinations were conducted by liquid chromatography tandem mass spectrometry using a hybrid triple quadrupole‐linear ion trap mass spectrometer (LC‐QqLIT‐MS). The data acquisition was made in selected reaction monitoring (SRM) mode, in which two SRM transitions were monitored to ensure that the target compounds were accurately identified by the information dependent acquisition (IDA) function. The limits of detection (LOD) and quantification (LOQ) were 0.25 and 0.80 µg L^?1 for sulfamethoxazole and 0.15 and 0.50 µg L^?1 for trimethoprim. The linear range for the SMX was 0.8–100.0 µg L^?1 and TMP was 0.5–100.0 µg L^?1 on the basis of six‐point calibration curves generated by means of linear regression analysis. The coefficients of the correlation were higher than 0.999, which ensured the linearity of the method. The average concentration of sulfamethoxazole and trimethoprim found in hospital effluent was 27.8 and 6.65 µg L^?1, respectively. The analytical methodology employed allowed two metabolites to be identified, N4‐acetyl‐sulfamethoxazole and α‐hydroxy‐trimethoprim. Fragmentation pathways were proposed.     

Assessing Cd,Co, Cu,Ni, and Pb Sorption on montmorillonite using surface complexation models

Cadmium, Co, Cu, Ni and Pb adsorption is measured on montmorillonite as a function of pH (3–11), ionic strength (0.001–0.1 M NaNO₃), and sorbate concentration (0.1–10 μM metal on 0.5 g/L solid). Sorption of all metals shows strong dependence on ionic strength and sorbate concentration, as well as a break in the slope of the edge, indicative of a 2-site interaction with montmorillonite. The resulting adsorption edges are used to parameterize diffuse layer surface complexation models (DLMs) for each metal. A 2-site DLM with a bidentate variable charge surface hydroxyl site and a bidentate permanent charge exchange site produced good fits for the individual experiments, but lacked the robustness to accurately predict adsorption across the entire experimental range. Other models, such as CCM, TLM, or CD-MUSIC may be required for more accurate predictions across broad ranges of solution conditions.     

Redox evolution in glacial drift aquifers: role of diamicton units in reduction of Fe(III)

High iron concentrations create water quality problems for municipal use in glacial drift aquifer units. The chemical evolution of oxic groundwater in shallow aquifer units to anoxic groundwater in deeper aquifer units, in which soluble Fe(II) is stable, is attributed to coupled reduction of Fe(III) on aquifer solids with oxidation of organic carbon. The objective of this study was to characterize the distribution of organic carbon in aquifer and aquitard sediments to determine the availability of potential electron donors to drive these reactions. To do this, four complete rotasonic cores in a glacial aquifer/aquitard system were sampled at close intervals for analyses of grain-size distribution and organic carbon content. The results indicate significantly higher organic carbon concentrations in diamicton (till) units that function as aquitards, relative to coarse-grained aquifer units. In addition, readily reducible iron content in the diamicton units and lower aquifer unit materials is sufficient to produce far more dissolved iron than is present in the aquifer. Groundwater evolves to the level of iron reduction as a terminal electron-accepting process as it moves downward through aquitard units along flow paths from upland recharge areas to downgradient discharge areas. Deeper aquifer units are therefore unlikely to contain groundwater with low iron concentration.     

Improving Cascadia subduction zone residents’ tsunami preparedness: quasi-experimental evaluation of an evacuation brochure

Natural Hazards - This study surveyed 227 residents in three US Pacific Coast communities that are vulnerable to a Cascadia subduction zone tsunami. In the Brochure condition, information was...