Precipitate flotation of copper as the sulfide,using recyclable amphoteric surfactants

An experimental study was made to identify surfactants which are effective for removal of copper from dilute aqueous solution (100–500 ppm) by precipitate flotation as the sulfide, and which at the same time can be recovered from the CuS product for recycle. Batch flotation experiments confirmed that a cationic surfactant was necessary for flotation of CuS from such dilute suspensions; however, no satisfactory way could be found for recovering cationic surfactants from the CuS. This led to consideration of amphoteric surfactants, which are cationic at low pH and anionic at high pH. It was found that a change to negative, rather than simply neutral, charge was required for efficient surfactant recovery. It was further found, through the assistance of experiments in which the CuS suspension was agitated with solvents, that certain functional groups which interact chemically with the CuS surface should also be absent from the surfactant molecule. Following this logic, Amphoterge K-2 (Lonza Chemical Co.) was identified as a suitable surfactant, provided CuS was precipitated with S^2? in excess. Tests established that 95% of adsorbed Amphoterge K-2 could be recovered by raising the pH to 11 and boiling the suspension for one hour, followed by decanting. Surfactant thus recovered was effective in a second flotation test. Foamate solids settled rapidly; such behavior would help reduce the consumption of chemicals for the pH change.Column flotation studies were made using Amphoterge K-2 for removal of Cu²⁺ present at 100 ppm and pH = 2. High removals of CuS could be obtained at concentrations of surfactant above about 25 ppm, for which conditions a substantial fraction of the surfactant remains in solution rather than being adsorbed onto the CuS. The recovery of CuS would be improved by introducing the surfactant in a separate feed, below the feed of CuS suspension. Adding some surfactant in the CuS feed, as well as in a lower feed, gave an even better recovery of CuS (99.8%) at sufficiently high surfactant loadings.     

Optical properties of solid and liquid sulfur at visible and infrared wavelengths

Knowledge of the optical constants of elemental sulfur has potential applications to Venus, Jupiter, Io, Amalthea, and the Earth. The real part, n, of the index of refraction of liquid sulfur (at 133°C) and of solid orthorhombic sulfur (at 25°C) for the wavelength range 0.4–2.0 μm were measured ellipsometrically. The imaginary part, k, of the refractive index of liquid sulfur was obtained by transmittance measurements at the same temperature and wavelength range. The reflectance of semi-infinite slabs of solid and liquid sulfur is calculated using the measured n and k values. We confirm that sulfur melts on Io would be classified as “black” by the Voyager imaging system.     

Die Entwickelung und das Auftreten des Paläozoikums in Griechenland

Ohne Zusammenfassung     

Determination of subcatchment and watershed boundaries in a complex and highly urbanized landscape

Urban development significantly alters the landscape by introducing widespread impervious surfaces, which quickly convey surface run‐off to streams via stormwater sewer networks, resulting in “flashy” hydrological responses. Here, we present the inadequacies of using raster‐based digital elevation models and flow‐direction algorithms to delineate large and highly urbanized watersheds and propose an alternative approach that accounts for the influence of anthropogenically modified land cover. We use a semi‐automated approach that incorporates conventional drainage networks into overland flow paths and define the maximal run‐off contributing area. In this approach, stormwater pipes are clustered according to their slope attributes, which define flow direction. Land areas drained by each cluster and contributing (or exporting) flow to a topographically delineated catchment were determined. These land masses were subsequently added or removed from the catchment, modifying both the shape and the size. Our results in a highly urbanized Toronto, Canada, area watershed indicate a moderate net increase in the directly connected watershed area by 3% relative to a topographically forced method; however, differences across three smaller scale subcatchments are greater. Compared to topographic delineation, the directly connected watershed areas of both the upper and middle subcatchments decrease by 5% and 8%, respectively, whereas the lower subcatchment area increases by 15%. This is directly related to subsurface storm sewer pipes that cross topographic boundaries. When directly connected subcatchment area is plotted against total streamflow and flashiness indices using this method, the coefficients of variation are greater (0.93 to 0.97) compared to the use of digital elevation model‐derived subcatchment areas (0.78 to 0.85). The accurate identification of watershed and subcatchment boundaries should incorporate ancillary data such as stormwater sewer networks and retention basin drainage areas to reduce water budget errors in urban systems.     

Preprocessing of gravity gradients at the GOCE high-level processing facility

One of the products derived from the gravity field and steady-state ocean circulation explorer (GOCE) observations are the gravity gradients. These gravity gradients are provided in the gradiometer reference frame (GRF) and are calibrated in-flight using satellite shaking and star sensor data. To use these gravity gradients for application in Earth scienes and gravity field analysis, additional preprocessing needs to be done, including corrections for temporal gravity field signals to isolate the static gravity field part, screening for outliers, calibration by comparison with existing external gravity field information and error assessment. The temporal gravity gradient corrections consist of tidal and nontidal corrections. These are all generally below the gravity gradient error level, which is predicted to show a 1/f behaviour for low frequencies. In the outlier detection, the 1/f error is compensated for by subtracting a local median from the data, while the data error is assessed using the median absolute deviation. The local median acts as a high-pass filter and it is robust as is the median absolute deviation. Three different methods have been implemented for the calibration of the gravity gradients. All three methods use a high-pass filter to compensate for the 1/f gravity gradient error. The baseline method uses state-of-the-art global gravity field models and the most accurate results are obtained if star sensor misalignments are estimated along with the calibration parameters. A second calibration method uses GOCE GPS data to estimate a low-degree gravity field model as well as gravity gradient scale factors. Both methods allow to estimate gravity gradient scale factors down to the 10⁻³ level. The third calibration method uses high accurate terrestrial gravity data in selected regions to validate the gravity gradient scale factors, focussing on the measurement band. Gravity gradient scale factors may be estimated down to the 10⁻² level with this method.     

Great Powers and Geopolitical Change

Abstract

Most traditional segregation measures, such as the index of dissimilarity D, fail to distinguish spatial patterns effectively. Previously proposed spatial measures modifying D suffer from several shortcomings. This article describes a general spatial segregation index based upon the concept of composite population counts, which are derived from grouping people in neighboring areas together to account implicitly for spatial interaction of groups across unit boundaries. The suggested spatial index can overcome the disadvantages of previous indices and can assess the spatial extent of the segregated clusters. The results offer a more comprehensive depiction of spatial segregation of a region.

     

Phase Relations and Melting of Anhydrous K-bearing Eclogite from 1200 to 1600{degrees}C and 3 to 5 GPa

To investigate eclogite melting under mantle conditions, wehave performed a series of piston-cylinder experiments usinga homogeneous synthetic starting material (GA2) that is representativeof altered mid-ocean ridge basalt. Experiments were conductedat pressures of 3·0, 4·0 and 5·0 GPa andover a temperature range of 1200–1600°C. The subsolidusmineralogy of GA2 consists of garnet and clinopyroxene withminor quartz–coesite, rutile and feldspar. Solidus temperaturesare located at 1230°C at 3·0 GPa and 1300°C at5·0 GPa, giving a steep solidus slope of 30–40°C/GPa.Melting intervals are in excess of 200°C and increase withpressure up to 5·0 GPa. At 3·0 GPa feldspar, rutileand quartz are residual phases up to 40°C above the solidus,whereas at higher pressures feldspar and rutile are rapidlymelted out above the solidus. Garnet and clinopyroxene are theonly residual phases once melt fractions exceed 20% and garnetis the sole liquidus phase over the investigated pressure range.With increasing melt fraction garnet and clinopyroxene becomeprogressively more Mg-rich, whereas coexisting melts vary fromK-rich dacites at low degrees of melting to basaltic andesitesat high melt fractions. Increasing pressure tends to increasethe jadeite and Ca-eskolaite components in clinopyroxene andenhance the modal proportion of garnet at low melt fractions,which effects a marked reduction in the Al₂O₃ and Na₂O contentof the melt with pressure. In contrast, the TiO₂ and K₂O contentsof the low-degree melts increase with increasing pressure; thusNa₂O and K₂O behave in a contrasted manner as a function ofpressure. Altered oceanic basalt is an important component ofcrust returned to the mantle via plate subduction, so GA2 maybe representative of one of many different mafic lithologiespresent in the upper mantle. During upwelling of heterogeneousmantle domains, these mafic rock-types may undergo extensivemelting at great depths, because of their low solidus temperaturescompared with mantle peridotite. Melt batches may be highlyvariable in composition depending on the composition and degreeof melting of the source, the depth of melting, and the degreeof magma mixing. Some of the eclogite-derived melts may alsoreact with and refertilize surrounding peridotite, which itselfmay partially melt with further upwelling. Such complex magma-genesisconditions may partly explain the wide spectrum of primitivemagma compositions found within oceanic basalt suites. KEY WORDS: eclogite; experimental petrology; mafic magmatism; mantle melting; oceanic basalts