A novel method for the study and classification of shales

The electron spin resonance spectra of a range of shales, from the Upper Pennsylvanian and Lower Permian of Kansas, U.S.A., have been recorded. Cluster analysis of the spectral data produced a four-group classification of the samples. The results compare well with a classification based on X-ray diffraction results.     

Exsolution and shock microstructures of igneous pyroxene clasts in the Northwest Africa 7533 Martian meteorite

Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia.     

Chemistry of the heavily urbanized Bagmati River system in Kathmandu Valley, Nepal: export of organic matter, nutrients, major ions, silica, and metals

Water quality in less-developed countries is often subject to substantial degradation, but is rarely studied in a systematic way. The concentration and flux of major ions, carbon, nitrogen, silicon, and trace metals in the heavily urbanized Bagmati River within Kathmandu Valley, Nepal, are reported. The concentrations of all chemical species increased with distance downstream with the exceptions of protons and nitrate, and showed strong relationships with population density adjacent to the river. Total dissolved nitrogen (TDN), dominated by NH₄, was found in high concentrations along the Bagmati drainage system. The export of dissolved organic carbon (DOC) and TDN were 23 and 33 tons km^?2 year^?1, respectively, at the outlet point of the Kathmandu Valley, much higher than in relatively undeveloped watersheds. The cationic and silica fluxes were 106 and 18 tons km^?2 year^?1 at the outlet of the Bagmati within Kathmandu Valley, and 36 and 32 tons km^?2 year^?1 from the relatively pristine headwater area. The difference between headwaters and the urban site suggests that the apparent weathering flux is three times higher than the actual weathering rate in the heavily urbanized Bagmati basin. Fluxes of cations and silica are above the world average, as well as fluxes from densely populated North American and European watersheds. End-member composition of anthropogenic sources like sewage or agricultural runoff is needed to understand the drivers of this high rate of apparent weathering.     

Mineral inclusions in fibrous diamonds: constraints on cratonic mantle refertilization and diamond formation

We analyzed mineral microinclusions in fibrous diamonds from the Wawa metaconglomerate (Superior craton) and Diavik kimberlites (Slave craton) and compared them with published compositions of large mineral inclusions in non-fibrous diamonds from these localities. The comparison, together with similar datasets available for Ekati and Koffiefontein kimberlites, suggest a general pattern of metasomatic alteration imposed on the ambient mantle by formation of fibrous diamond. Calcium and Fe enrichment of peridotitic garnet and pyroxenes and Fe enrichment of olivine associated with fibrous diamond-forming fluids contributes to refertilization of the cratonic mantle. Saline—carbonatitic—silicic fluid trapped by fibrous diamonds may represent one of the elusive agents of mantle refertilization. Calcium enrichment of peridotitic garnet and pyroxenes is expected in local mantle segments during fibrous diamond production, as Ca in the carbonatitic fluids is deposited into the surrounding mantle when oxidized carbon is reduced to diamond. Harzburgitic garnet evolves towards Ca-rich compositions even when it interacts with Ca-poor saline fluids. An unusual trend of Mg enrichment to Fo_95–98 is observed in some olivine inclusions in Wawa fibrous diamonds. The trend may result from the carbonatitic composition of the fluid that promotes crystallization of magnesian olivine and preferentially oxidizes the fayalite component. We propose a generic model of fibrous and non-fibrous diamond formation from carbonatitic fluids that explains enrichment of the mantle in mafic magmaphile and incompatible elements and accounts for locally metasomatized compositions of diamond inclusions.     

Intrinsic intraday variability in the gravitational lens system B0218+357

Radio monitoring of the gravitational lens system B0218+357 reveals it to be a highly variable source with variations on time-scales of a few days correlated in both images. This shows that the variability is intrinsic to the background lensed source and suggests that similar variations in other intraday variable sources can also be intrinsic in origin.     

Global very long-baseline interferometry observations of compact radio sources in M82

Observations of the starburst galaxy, M82, have been made with a 20-station global very long-baseline interferometry (VLBI) array at λ 18 cm. Maps are presented of the brightest young supernova remnants (SNR) in M82 and the wide-field mapping techniques used in making images over a field of view of ∼1 arcmin with 3-milliarcsecond resolution are discussed. A limit has been placed on the power-law deceleration of the young supernova remnant (SNR) 43.31+592 with an index greater than 0.73±0.11 from observations with the European VLBI Network. Using the global array we have resolved compact knots of radio emission in the source which, with future global observations, will enable better constraints to be placed on the expansion parameters of this SNR.
The latest global observations have also provided high-resolution images of the most compact radio source in M82, 41.95+575. We determine an upper limit to the radial expansion rate along the major axis of 2000 km s⁻¹. However, the new images also show structure resembling that of collimated ejection which brings into question the previous explanation of the source as being a result of the confinement of a supernova by a high-density circumstellar medium.
It is apparent that we are now able to image the brightest supernova remnants in M82 with a linear scale which allows direct comparison with galactic SNR such as Cassiopeia A.     

Dark matter in dwarf spheroidals – II. Observations and modelling of Draco

We present stellar radial velocity data for the Draco dwarf spheroidal (dSph) galaxy obtained using the AF2/WYFFOS instrument combination on the William Herschel Telescope. Our data set consists of 186 member stars, 159 of which have good quality velocities, extending to a magnitude   V ≈19.5  with a mean velocity precision of ≈2 km s⁻¹. As this survey is based on a high-precision photometric target list, it contains many more Draco members at large radii. For the first time, this allows a robust determination of the radial behaviour of the velocity dispersion in a dSph.
We find statistically strong evidence of a rising velocity dispersion consistent with a dark matter halo that has a gently rising rotation curve. There is a <2 σ signature of rotation about the long axis, inconsistent with tidal disruption as the source of the rising dispersion. By comparing our data set with earlier velocities, we find that Draco probably has a binary distribution and fraction comparable to those in the solar neighbourhood.
We apply a novel maximum likelihood algorithm and fit the velocity data to a two parameter spherical model with an adjustable dark matter content and velocity anisotropy. Draco is best fit by a weakly tangentially anisotropic distribution of stellar orbits in a dark matter halo with a very slowly rising rotation law  ( v _circ∝ r ^0.17)  . We are able to rule out both a mass-follows-light distribution and an extended halo with a harmonic core at the 2.5 to 3 σ significance level, depending on the details of our assumptions about Draco's stellar binary population. Our modelling lends support to the idea that the dark matter in dwarf spheroidals is distributed in the form of massive, nearly isothermal haloes.     

Distant field blue horizontal branch stars – III. Identification of a probable outer halo stream at Galactocentric distance r= 70 kpc

We present FOcal Reducer/low dispersion Spectrograph-1 spectra (from the European Southern Observatory's Very Large Telescope) of a sample of 34 faint  20.0 < g * < 21.1  A-type stars selected from the Sloan Digital Sky Survey Early Data Release, with the goal of measuring the velocity dispersion of blue horizontal branch (BHB) stars in the remote Galactic halo,   R ∼ 80 kpc  . We show that colour selection with  1.08 < u *− g * < 1.40  and  −0.2 < g *− r * < −0.04  minimizes contamination of the sample by less luminous blue stragglers. In classifying the stars we confine our attention to the 20 stars with spectra of signal-to-noise ratio >15 Å⁻¹. Classification produces a sample of eight BHB stars at distances  65–102 kpc  from the Sun (mean 80 kpc), which represents the most distant sample of Galactic stars with measured radial velocities. The dispersion of the measured radial component of the velocity with respect to the centre of the Galaxy is  58 ± 15 km s⁻¹  . This value is anomalously low in comparison with measured values for stars at smaller distances, as well as for satellites at similar distances. Seeking an explanation for the low measured velocity dispersion, further analysis reveals that six of the eight remote BHB stars are plausibly associated with a single orbit. Three previously known outer halo carbon stars also appear to belong to this stream. The velocity dispersion of all nine stars relative to the orbit is only  15 ± 4 km s⁻¹  . Further observations along the orbit are required to trace the full extent of this structure on the sky.