The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.     

Spherical needlets for cosmic microwave background data analysis

We discuss spherical needlets and their properties. Needlets are a form of spherical wavelets which do not rely on any kind of tangent plane approximation and enjoy good localization properties in both pixel and harmonic space; moreover needlet coefficients are asymptotically uncorrelated at any fixed angular distance, which makes their use in statistical procedures very promising. In view of these properties, we believe needlets may turn out to be especially useful in the analysis of cosmic microwave background (CMB) data on the incomplete sky, as well as of other cosmological observations. As a final advantage, we stress that the implementation of needlets is computationally very convenient and may rely completely on standard data analysis packages such as healp ix.     

A speculation on the structure of the D″ layer: The growth of anti-crust at the core–mantle boundary through the subduction history of the Earth

The growth curve of the continental crust shows that large amounts of continental crust formed in the early part of the Earth history are missing. In order to test a hypothesis that the former crust was subducted to the deep mantle, we performed phase assemblage analysis in the systems of mid-oceanic ridge basalt (MORB), anorthosite, and tonalite–trondhjemite–granite (TTG) down to the core–mantle boundary (CMB) conditions. Results show that all these materials can be subducted to the CMB leading to the development of a compositional layering in the D″ layer. We speculate that there could be five layers of FeO-enriched melt from partial melting of MORB, MORB crust, anorthosite, TTG, and slab or mantle peridotite in ascending order. Although the polymorphic transformation of perovskite to post-perovskite in (Mg,Fe)SiO₃ may explain the seismic discontinuity at the top of the D″ layer (D″ discontinuity), the effects of solid solution on the sharpness of the transformation suggest that the compositional layering is more plausible for the origin of the D″ discontinuity. The D″ layer can be an “anti-crust” made up mostly of TTG + anorthosite derived from the former continental crust. Tectonic style of the anti-crust at the CMB is similar to that at the surface. At both places, chemically distinct layers are density stratified and are also characterized by the processes of accretion, magmatism, and metasomatism.     

Estimating building exposure and impact to volcanic hazards in Icod de los Vinos,Tenerife (Canary Islands)

Principal and subsidiary building structure characteristics and their distribution have been inventoried in Icod, Tenerife (Canary Islands) and used to evaluate the vulnerability of individual buildings to three volcanic hazards: tephra fallout, volcanogenic earthquakes and pyroclastic flows. The procedures described in this paper represent a methodological framework for a comprehensive survey of all the buildings at risk in the area around the Teide volcano in Tenerife. Such a methodology would need to be implemented for the completion of a comprehensive risk assessment for the populations under threat of explosive eruptions in this area. The information presented in the paper is a sample of the necessary data required for the impact estimation and risk assessment exercises that would need to be carried out by emergency managers, local authorities and those responsible for recovery and repair in the event of a volcanic eruption. The data shows there are micro variations in building stock characteristics that would influence the likely impact of an eruption in the area. As an example of the use of this methodology for vulnerability assessment, we have applied a deterministic simulation model of a volcanic eruption from Teide volcano and its associated ash fallout which, when combined with the vulnerability data collected, allows us to obtain the vulnerability map of the studied area. This map is obtained by performing spatial analysis with a Geographical Information System (GIS). This vulnerability analysis is included in the framework of an automatic information system specifically developed for hazard assessment and risk management on Tenerife, but which can be also applied to other volcanic areas. The work presented is part of the EU-funded EXPLORIS project (Explosive Eruption Risk and Decision Support for EU Populations Threatened by Volcanoes, EVR1-2001-00047).     

Partitioning between “wedge-top” river- and wave-dominated successions: an example from the late Tortonian — early Messinian Terravecchia Formation (NW Sicily)

Detailed field sedimentological and facies analyses have been performed in the Terravecchia Formation cropping out in NW Sicily, in order to differentiate and describe, for the first time, wave- and river-dominated shallow-marine (deltaic) siliciclastic successions. The latter were deposited filling syntectonic basins, developed between the late Tortonian and early Messinian time, within the wedge-top depozone of the Sicilian Foreland Basin System. It has been observed that river-dominated successions, recording the deposition of small fan-deltas are characterized by fining- to coarsening upward, transgressive-regressive sequences which were mostly deposited filling relatively narrow and often oversupplied basins. These basins were probably located in a proximal sector of the wedge-top depozone, closer to emergent sectors of the chain and probably sheltered from the main marine areas. Wavedominated successions, on the other hand, are characterized by upward fining, mostly transgressive sequences which were deposited filling wider basins open to major marine regions and located in a more distal position of the wedge-top depozone. The documented partitioning between river- and wave-dominated successions, as a function of the position of the sedimentary basin within the wedge-top depozone, is coherent with data from analyses of the deformational patterns of the Terravecchia Formation in this study area. Furthermore, the data here presented could be considered as a preliminary database for future characterization and analysis of siliciclastic reservoirs from Sicilian outcrop analogues.     

Adaptive POD model reduction for solute transport in heterogeneous porous media

We study the applicability of a model order reduction technique to the solution of transport of passive scalars in homogeneous and heterogeneous porous media. Transport dynamics are modeled through the advection-dispersion equation (ADE) and we employ Proper Orthogonal Decomposition (POD) as a strategy to reduce the computational burden associated with the numerical solution of the ADE. Our application of POD relies on solving the governing ADE for selected times, termed snapshots. The latter are then employed to achieve the desired model order reduction. We introduce a new technique, termed Snapshot Splitting Technique (SST), which allows enriching the dimension of the POD subspace and damping the temporal increase of the modeling error. Coupling SST with a modeling strategy based on alternating over diverse time scales the solution of the full numerical transport model to its reduced counterpart allows extending the benefit of POD over a prolonged temporal window so that the salient features of the process can be captured at a reduced computational cost. The selection of the time scales across which the solution of the full and reduced model are alternated is linked to the Péclet number (P e), representing the interplay between advective and dispersive processes taking place in the system. Thus, the method is adaptive in space and time across the heterogenous structure of the domain through the combined use of POD and SST and by way of alternating the solution of the full and reduced models. We find that the width of the time scale within which the POD-based reduced model solution provides accurate results tends to increase with decreasing P e. This suggests that the effects of local-scale dispersive processes facilitate the POD method to capture the salient features of the system dynamics embedded in the selected snapshots. Since the dimension of the reduced model is much lower than that of the full numerical model, the methodology we propose enables one to accurately simulate transport at a markedly reduced computational cost.     

Multiple wavelength observations of a solar active region

The Solar Maximum Mission Satellite, the Sacramento Peak Vacuum Tower Telescope, the Very Large Array and the Westerbork Synthesis Radio Telescope have been used to observe active region AR 2490 on two consecutive days at soft X-ray, ultraviolet, optical and radio wavelengths (2, 6, and 20 cm), with comparable angular resolution (2 to 15) and field of view (4 × 4). The radio emissions at = 6 cm and 20 cm show a double structure in which one component is associated with bright H plage, C iv and soft X-ray emission, and the other component is associated only with sunspots. No radiation at = 2 cm is detected in this latter component. Coronal temperature and emission measure derived from X-ray lines indicate that the dominant radiation mechanism of the plage-associated component is due to thermal bremsstrahlung while the gyroresonance absorption coefficient must be invoked to account for the high brightness temperature (T _b 2×10⁶K) observed in the sunspot associated component. The high magnetic field strength needed (600 G at a level where T2×10⁶K) is explained assuming a thin transition zone, in order to reach a high electron temperature close to the sunspot, where the magnetic fields are stronger. A higher temperature gradient above sunspots is also consistent with the absence of detectable C iv emission.Cooperative study of the SMY-FBS Project.On leave from the University of Napoli.On leave from the University of Torino.On sabbatical leave 1980–81 at the Arcetri Observatory.On leave from Toyokawa Observatory, Japan.     

Theoretical analysis of X-ray absorption near-edge structure in forsterite, Mg2SiO4-Pbnm, and fayalite, Fe2SiO4-Pbnm, at room temperature and extreme conditions

We calculated the forsterite Mg K-edge and the fayalite Fe K-edge X-ray absorption spectra both for the M 1 and M 2 sites and for the overall edge by using the one-electron multiple-scattering theory. The validity of the theoretical model is well illustrated by comparison of calculations with experimental data at the Mg K-edge of MgO (periclase) and at the Mg and Fe K-edges spectra of forsterite and fayalite. Starting from these results at room conditions, we calculated the Mg and Fe K-edges X-ray absorption spectra of forsterite and fayalite at low and high temperatures and at high pressures as well. Variations of fine structures occur mostly in the intermediate multiple scattering (IMS) regions and as a result of the applied pressure. In order to demonstrate the capability of XAS to lead to deeper knowledge of structure relevant to Earth's upper mantle we also attempted calcuating the high-P edge for Fe ²⁺ in low-spin using a different occupation of valence electrons. If a change in spin state really occurs in fayalite, our simple model shows that XAS would evidence it easily even with low resolution.